Transition Metal Chemistry

, Volume 27, Issue 5, pp 473–480 | Cite as

Homo- and hetero-nuclear chromium(III) complexes with natural ligands. Part 1. Spectroscopic and mass spectra studies on ternary [M–L1–L2] systems

  • Gabriela Maciejewska
  • Maria Cieślak-Golonka
  • Zbigniew Staszak
  • Adam Szeląg
Article

Abstract

Seven new ternary mono- and poly-nuclear CrIII complexes with natural ligands: glycine, glutaminic, nicotinic and asparginic acids, cysteine and glutathione, have been isolated and physicochemically characterized. Four of them have been tested and appear to be non-toxic. The complexes have been analysed using spectroscopic (diffuse reflectance U.v–vis., i.r., f.i.r.), magnetic methods, and (some) by FAB mass spectra. Spectral analyses with the digital filter and band deconvolution methods have been also presented.

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References

  1. 1.
    J.B. Vincent, Polyhedron, 20, 1 (2001).Google Scholar
  2. 2.
    D. Sterns, BioFactors, 11, 149 (2000).Google Scholar
  3. 3.
    R.A. Anderson, M.M. Polanski, N.A. Bryden and J.J. Canary, Am. J. Clin. Nutr., 54, 909 (1991).Google Scholar
  4. 4.
    M. Beran, R. Stahal and M. Beran, Analyst, 120, 979 (1995).Google Scholar
  5. 5.
    J.J.R.F. Da Silva and R.J.P. Williams, The Biological Chemistry of the Elements, Clarendon Press, Oxford, 1991.Google Scholar
  6. 6.
    W. Mertz and K. Schwarz, Am. J. Physiol., 196(3), 614 (1959).Google Scholar
  7. 7.
    S. Yashimoto, K. Sakamoto, I. Wakabayashi and H. Masui, Metabolism, 41, 636 (1992).Google Scholar
  8. 8.
    M. Simono., D. Shapcott, S. Alameddine, M.T. Sutter-Dub and G. Simonoff, Biol. Trace Elem.Res., 32, 25 (1992).Google Scholar
  9. 9.
    J. Barrett, P.O 'Brien and J.Pedrosa de Jesus, Polyhedron Report, 9, 1 (1985).Google Scholar
  10. 10.
    C.M. Davis, A.C. Royer and J.B. Vincent, Inorg. Chem., 36, 5316 (1997).Google Scholar
  11. 11.
    T. Ellis, M. Glass, A. Harton, K. Folting, J.C. Huffman and J.B. Vincent, Inorg. Chem., 33, 5522 (1994).Google Scholar
  12. 12.
    A. Yamamoto, O. Wada and T. Ono, Eur.J.Biochem., 165, 627 (1987).Google Scholar
  13. 13.
    C.M. Davis and J.B. Vincent, Arch. Biochem. Biophys., 339, 335 (1997).Google Scholar
  14. 14.
    K.H. Sumrall and J.B. Vincent, Polyhedron, 16, 4171 (1997).Google Scholar
  15. 15.
    J.B. Vincent, Acc.Chem.Res., 33, 503 (2000).Google Scholar
  16. 16.
    G. Gałuszka, M. Cieślak-Golonka, A. Szelag, J. Starosta and A. Wojciechowska, Polyhedron, 17, 3785 (1998).Google Scholar
  17. 17.
    M. Vicens, J.J. Fiol, A. Terron, V. Moreno and D.M.L. Goodgame, Inorg. Chim. Acta, 157, 127 (1989).Google Scholar
  18. 18.
    A.M. Calafat, J.J. Fiola, A. Terron, V. Moreno, D.M.L. Goodgame and I. Hussain, Inorg. Chim. Acta, 169, 133 (1990).Google Scholar
  19. 19.
    M. Vicens, M. Prats, J.J. Fiol, A. Terron and A. Moreno, Inorg. Chim.Acta, 158, 59 (1989).Google Scholar
  20. 20.
    N. Sakagami, E. Kita, P. Kita, J. Wisniewska and S. Kaizaki, Polyhedron, 18, 2001 (1999).Google Scholar
  21. 21.
    T.H. Nufert, C.T. Goetschel, C.A. Yountville and C.B. Allan, Abstracts of the International Symposium Health Effects of Dietary Chromium, 1-2V, 1998, US Patent 5, 266, 560.Google Scholar
  22. 22.
    P.R. Shepherd, C. Elwood, P.D. Buckley and L.F. Blackwell, Biol. Trace Elem. Res., 32, 109 (1992).Google Scholar
  23. 23.
    J. Myrczek, Spectrosc. Lett., 23, 1027 (1990).Google Scholar
  24. 24.
    J. Stawińka, M. Cieślak-Golonka, Z. Staszak, R. Gancarz, Trans. Met.Chem., 26, 153 (2001).Google Scholar
  25. 25.
    A. Baruya and W. Maddams, Appl. Spec., 32, 563 (1978).Google Scholar
  26. 26.
    J.R. Perumareddi, J.Phys. Chem., 76, 3401 (1972).Google Scholar
  27. 27.
    A. Drljaca and L. Spiccia, Polyhedron, 15, 4373 (1996).Google Scholar
  28. 28.
    A. Harton, K. Terrell, J.C. Huffman, Ch. MacDonald, A. Beatty, S. Li, Ch.J. O'Connor and J.B. Vincent, Inorg. Chim. Acta, 36, 4875 (1997).Google Scholar
  29. 29.
    A.E. Ceniceros-Gomez, N. Barba-Behrens, M.E. Quiroz-Castro, S. Bernes, H. Nothand S.E. Castillo-Blum, Polyhedron, 19, 1821(2000).Google Scholar
  30. 30.
    A.C. Covington, G.S. Lampard, O. Menderes, A.V. Chadwick, G. Rafeletos, P. O'Brien, Polyhedron, 20, 461 (2001).Google Scholar
  31. 31.
    A. Harton, M.K. Nagi, M.M. Glass, M.P.C. Junk, J.L. Atwoodand J.B. Vincent, Inorg. Chim. Acta, 217, 171 (1994).Google Scholar
  32. 32.
    A. Parand, A.C. Royer, T.L. Cantrell, M. Weitzel, N. Memon, J.B. Vincent and M.W. Crowder, Inorg. Chim. Acta, 268, 211(1998).Google Scholar
  33. 33.
    C.G. Agoston, K. Varnagy, A. Benyei, D. Sanna, G. Micera and I. Sovago, Polyhedron, 19, 1849 (2000).Google Scholar
  34. 34.
    M. Abdullah, J. Barrett and P. O'Brien, J. Chem. Soc., Dalton Trans., 2085 (1985).Google Scholar
  35. 35.
    K. Nakamoto, Infrared and Raman Spectra of Inorganic and Coordination Compounds, 5th edit., A Wiley-Interscience Publication, New York-Chichester-Brisbane-Toronto, 1997Google Scholar
  36. 36.
    D.P. Singhand V.B. Rana, Polyhedron, 14, 2901 (1995).Google Scholar
  37. 37.
    H. Heaster and P.E. Hoggard, Polyhedron, 13, 333 (1994).Google Scholar
  38. 38.
    K.-W. Lee, K.-Il. Eom and S.-J. Park, Inorg. Chim. Acta, 254, 131 (1997).Google Scholar
  39. 39.
    W. Radecka-Paryzek, M.T. Kaczmarek and E. Luks, Polish. J. Chem., 75, 35 (2001).Google Scholar
  40. 40.
    G. Kortüm, Reflexionsspektroskopie, Springer-Verlag Berlin Heidelberg, New York, 1969Google Scholar
  41. 41.
    M. Cieślak-Golonka, M. Raczko and Z. Staszak, Polyhedron, 11, 2549 (1992).Google Scholar
  42. 42.
    S.P. Kaiwar, A. Sreedhara, M.S.S. Raghavan, Ch.P. Rao, V. Jadhav and K.N. Ganesh, Polyhedron, 15, 756 (1996).Google Scholar
  43. 43.
    A.B.P. Lever, Inorganic Electronic Spectroscopy, 2nd edit., Elsevier, Amsterdam-Oxford-New York-Tokyo, 1984, and the references therein.Google Scholar
  44. 44.
    W.B. Saunders, Handbook of Toxicology, 1956, vol. 1., Comp. Philadelphia-London.Google Scholar

Copyright information

© Kluwer Academic Publishers 2002

Authors and Affiliations

  • Gabriela Maciejewska
    • 1
  • Maria Cieślak-Golonka
    • 1
  • Zbigniew Staszak
    • 2
  • Adam Szeląg
    • 3
  1. 1.Institute of Inorganic Chemistry and Metallurgy of Rare ElementsUniversity of TechnologyWrocławPoland
  2. 2.Faculty of Computer Science and Management, Department of Computer ScienceUniversity of TechnologyWrocławPoland
  3. 3.Department of PharmacologyMedical AcademyWrocławPoland

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