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Russian Chemical Bulletin

, Volume 51, Issue 3, pp 476–480 | Cite as

Formation of coordination polymeric structures on the basis of 4,4"-dipyridylethylene and Ag+ in solutions

  • V. F. Razumov
  • S. B. Brichkin
  • O. M. Pilugina
  • T. P. Karpova
  • S. Z. Vatsadze
  • D. A. Lemenovskii
  • M. Schröder
  • N. R. Champness
  • M. V. Alfimov
Article

Abstract

The formation of coordination polymeric chain structures in which silver ions alternate with dipyridylethylene (DPyEt) ligands was studied. In a homogeneous ethanol solution, complex formation of DPyEt with silver cations takes place. The outcome of this reaction depends on the ligand/cation molar ratio, the initial ligand concentration, and the counter-ion type. Conditions were identified under which the coordination polymer is formed as a microdispersed solid precipitating from the solution. The precipitates formed in the DPyEt—AgNO3 and DPyEt—AgClO4 systems were investigated by various experimental techniques. The counter-ion was found to be incorporated in the polymer and to influence the structure of the precipitate particles.

complex formation coordination polymers dipyridylethylene ligands silver cations 

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References

  1. 1.
    L. R. MacGillivray, I. S. Subramanian, and M. J. Zaworotko, J. Chem. Soc., Chem. Commun., 1994, 1325.Google Scholar
  2. 2.
    G. B. Gardner, D. Venkataraman, J. S. Moore, and S. Lee, Nature, 1995, 347, 792.Google Scholar
  3. 3.
    G. R. Desiraju, Angew. Chem., Int. Ed. Engl., 1995, 34, 2311.Google Scholar
  4. 4.
    M. Fujata and K. Ogura, Coord. Chem. Rev., 1996, 148, 249.Google Scholar
  5. 5.
    R. Robson, in Comprehensive Supramolecular Chemistry, Eds. J. L. Atwood, J. E. D. Davies, D. D MacNicol, F. Vortle, and J. M. Lehn, Pergamon, Oxford, 1997, 6, Ch. 22, 733.Google Scholar
  6. 6.
    A. J. Blake, N. R. Champness, S. S. M. Chung, W.-S. Li, and M. Schröder, Chem. Commun., 1997, 1675.Google Scholar
  7. 7.
    A. J. Blake, N. R. Champness, A. N. Khlobystov, D. A. Lemenovskii, W.-S. Li, and M. Schröder, J. Chem. Soc., Chem. Commun., 1997, 1339.Google Scholar
  8. 8.
    A. J. Blake, N. R. Champness, A. N. Khlobystov, D. A. Lemenovskii, W.-S. Li, and M. Schröder, J. Chem. Soc., Chem. Commun., 1997, 2027.Google Scholar
  9. 9.
    S. R. Batten and R. Robson, Angew. Chem., Int. Ed., 1998, 37, 1460.Google Scholar
  10. 10.
    N. R. Champness and M. Schröder, Curr. Opin. Solid. State Mater. Sci., 1998, 3, 419.Google Scholar
  11. 11.
    M. Munakata, L. P. Wu, and T. Kuroda-Sowa, Adv. Inorg. Chem., 1998, 46, 173.Google Scholar
  12. 12.
    P. J. Hagrman, D. Hagrman, and J. Zubieta, Angew. Chem., Int. Ed., 1999, 38, 2638.Google Scholar
  13. 13.
    B. Olcnyuk, A. Fechtenkotter, and P. J. Stang, J. Chem. Soc., Dalton Trans Google Scholar
  14. 14.
    P. J. Stang, Chem. Eur. J., 1998, 4, 19.Google Scholar
  15. 15.
    M. Fujita, O. Sasaki, K. Watanabe, K. Ogura, and K. Yamaguchi, New J. Chem., 1998, 189.Google Scholar
  16. 16.
    L. Garlucci, G. Ciani, P. Macchi, D. M. Proserpoo, and S. Rizzato, Chem. Eur. J., 1999, 5, 237.Google Scholar
  17. 17.
    A. J. Blake, N. R. Champness, P. Hubberstey, W.-S. Li, M. A. Withersby, and M. Schröder, Coord. Chem. Rev., 1999, 183, 117.Google Scholar
  18. 18.
    A. F. Dodonov, V. I. Kozlovski, I. V. Soulimenkov, and V. V. Raznikov, Eur. J. Mass Spectrometry, 2000, 6, 481.Google Scholar
  19. 19.
    A. N. Khlobystov, A. J. Blake, N. R. Champness, D. A. Lemenovskii, A. G. Majouga, N. V. Zyk, and M. Schröder, Coord. Chem. Rev., 2001, 222, 137.Google Scholar

Copyright information

© Plenum Publishing Corporation 2002

Authors and Affiliations

  • V. F. Razumov
    • 1
  • S. B. Brichkin
    • 1
  • O. M. Pilugina
    • 1
  • T. P. Karpova
    • 1
  • S. Z. Vatsadze
    • 2
  • D. A. Lemenovskii
    • 2
  • M. Schröder
    • 3
  • N. R. Champness
    • 3
  • M. V. Alfimov
    • 1
    • 4
  1. 1.Russian Academy of SciencesInstitute of Problems of Chemical PhysicsChernogolovkaRussian Federaton
  2. 2.Chemical DepartmentMoscow State UniversityMoscowRussian Federation
  3. 3.Department of ChemistryThe University of NottinghamNottinghamUK
  4. 4.Center of PhotochemistryRussian Academy of SciencesMoscowRussian Federation

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