Abstract
The 1-D complex with high-nuclearity [{La6Cu26gly18(μ 3-OH)30(H2O)24(ClO4)} (ClO4)21·26H2O] n was synthesized and characterized by X-ray diffraction analysis. The inner core of the basic unit is an octahedron with La3+ ions at its vertexes and Cu2+ ions at the meddles of the twelve edges. Two additional Cu2+ ions are connected to each La3+ vertex to form a [La6Cu24] unit, and adjacent units are interconnected by a pair [Cu(gly)2] bridges to give a polymeric chain structure.
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Hu, S., Dai, J., Wu, X. et al. A Copper(II)-Lanthanoid(III)-Glycine Complex with High-Nuclearity, [{La6Cu26gly18(μ 3-OH)30(H2O)24 (ClO4)}(ClO4)21·26H2O] n . Journal of Cluster Science 13, 33–41 (2002). https://doi.org/10.1023/A:1015182827959
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DOI: https://doi.org/10.1023/A:1015182827959