Russian Chemical Bulletin

, Volume 50, Issue 11, pp 2144–2148 | Cite as

Reactions of methoxycarbonylcarbene with 3-ethyl-2-phenyl- and 2,3-diphenyloxazolidines

  • A. P. Molchanov
  • A. V. Stepakov
  • J. Kopf
  • I. G. Zenkevich
  • R. R. Kostikov
Article

Abstract

The reactions of methoxycarbonylcarbene, which was generated by catalytic thermal decomposition of methyl diazoacetate, with 3-ethyl-2-phenyl- or 2,3-diphenyloxazolidines resulted in the insertion of the former predominantly at the C—N bond of the oxazolidine ring to produce substituted esters of morpholine-3-carboxylic acid.

carbenes diazo compounds oxazolidines insertion reactions 

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Copyright information

© Plenum Publishing Corporation 2001

Authors and Affiliations

  • A. P. Molchanov
    • 1
  • A. V. Stepakov
    • 1
  • J. Kopf
    • 2
  • I. G. Zenkevich
    • 1
  • R. R. Kostikov
    • 1
  1. 1.St. Petersburg State UniversitySt. PetersburgRussian Federation
  2. 2.Institute of Inorganic ChemistryHamburgGermany

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