Russian Journal of General Chemistry

, Volume 71, Issue 9, pp 1487–1490

Conformational Composition of 5-Alkyl-1,3-Oxathianes

  • A. M. Turyanskaya
  • A. N. Novikov
  • G. M. Verkhivker
  • V. V. Kuznetsov
Article

DOI: 10.1023/A:1013930725137

Cite this article as:
Turyanskaya, A.M., Novikov, A.N., Verkhivker, G.M. et al. Russian Journal of General Chemistry (2001) 71: 1487. doi:10.1023/A:1013930725137

Abstract

Conformational equilibrium of 5-isopropyl-1,3-oxathiane occurs mainly between the forms of chair with equatorial and axial orientation of the substituent at the C5 atom, and in the case of 2,2,5-trimethyl- and, apparently, in the case of 5-tert-butyl-1,3-oxathianes is characterized by a more noticeable contribution of flexible forms.

Copyright information

© MAIK “Nauka/Interperiodica” 2001

Authors and Affiliations

  • A. M. Turyanskaya
    • 1
    • 2
    • 3
  • A. N. Novikov
    • 1
    • 2
    • 3
  • G. M. Verkhivker
    • 1
    • 2
    • 3
  • V. V. Kuznetsov
    • 1
    • 2
    • 3
  1. 1.Mechnikov Odessa State UniversityOdessaUkraine
  2. 2.Bogatskii Physico-chemical InstituteUkrainian National Academy of SciencesOdessaUkraine
  3. 3.Ufa State Petroleum Technical University, UfaBashkortostanRussia

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