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Russian Chemical Bulletin

, Volume 50, Issue 8, pp 1382–1389 | Cite as

Reaction of the acrylic acid and 1-vinylimidazole copolymer with CuCl2 in aqueous solution

  • V. V. Annenkov
  • E. N. Danilovtseva
  • V. V. Saraev
  • I. A. Alsarsur
  • O. V. Lunionok
Article

Abstract

The reaction of acrylic acid—1-vinylimidazole copolymer with CuCl2 in an aqueous medium was investigated by potentiometric titration and UV and ESR spectroscopy. The complex formation involves both the azole units and the carboxy groups. The Cl ions are also incorporated in the inner sphere of the complexes, their removal by dialysis resulting in an increase in the coordination capacity of the carboxylate groups.

copolymer acrylic acid 1-vinylimidazole copper chloride comple 

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Copyright information

© Plenum Publishing Corporation 2001

Authors and Affiliations

  • V. V. Annenkov
    • 1
  • E. N. Danilovtseva
    • 1
  • V. V. Saraev
    • 2
  • I. A. Alsarsur
    • 2
  • O. V. Lunionok
    • 2
  1. 1.Irkutsk Institute of ChemistrySiberian Branch of the Russian Academy of SciencesIrkutskRussian Federation
  2. 2.Chemical DepartmentIrkutsk State UniversityIrkutskRussian Federation

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