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Hyperfine Interactions

, Volume 106, Issue 1–4, pp 51–56 | Cite as

Reorientation dynamics of cyclohexadienyl radicals in zeolites

  • M. Stolmár
  • E. Roduner
  • H. Dilger
  • U. Himmer
  • M. Shelley
  • I.D. Reid
Article

Abstract

The dynamics of the muonium substituted cyclohexadienyl radical adsorbed on silicalite and NaZSM‐5 is investigated by means of avoided level crossing muon spin resonance. The influence of benzene loading on the mobility of the radical is studied. At low loadings the radicals were found to be located on a single adsorption site where they undergo a wobbling type of motion. With increasing loading an additional species adsorbed on a different site is observed.

Keywords

Zeolite Silicalite Paul Scherrer Institute Reorientation Dynamic Cyclohexadienyl Radical 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Kluwer Academic Publishers 1997

Authors and Affiliations

  • M. Stolmár
    • 1
  • E. Roduner
    • 1
  • H. Dilger
    • 1
  • U. Himmer
    • 1
  • M. Shelley
    • 2
  • I.D. Reid
    • 3
  1. 1.Institut für Physikalische ChemieUniversität StuttgartStuttgartGermany
  2. 2.TRIUMFVancouverCanada
  3. 3.Paul Scherrer InstituteVilligen PSISwitzerland

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