Russian Chemical Bulletin

, Volume 50, Issue 5, pp 901–906 | Cite as

The preparation and reactivity of metal-containing monomers. 54. Thermolysis of the acrylamide monomer [Co(CH2=CHCONH2)4(H2O)2](NO3)2

  • A. S. Rozenberg
  • A. V. Raevskii
  • E. I. Aleksandrova
  • O. I. Kolesova
  • G. I. Dzhardimalieva
  • A. D. Pomogailo
Article

Abstract

The kinetics and pathways of thermolysis of the Co(II) complex with acrylamide, [Co(CH2=CHCONH2)4(H2O)2](NO3)2 (1) were studied. The rate of gas evolution is satisfactorily approximated by a first-order equation of autocatalysis. The composition of gaseous and solid products of thermolysis of 1 was studied by IR spectroscopy, mass spectrometry, and electronic microscopy. Thermal transformations of acrylamide complex 1 include three macro stages: dehydration, polymerization of the dehydrated monomer, and thermooxidative destruction of the resulting polymer.

acrylamide complexes of cobalt nitrate thermal transformations dehydration solid-phase polymerization thermooxidative destruction cobalt nano-sized particles 

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Copyright information

© Plenum Publishing Corporation 2001

Authors and Affiliations

  • A. S. Rozenberg
    • 1
  • A. V. Raevskii
    • 1
  • E. I. Aleksandrova
    • 1
  • O. I. Kolesova
    • 1
  • G. I. Dzhardimalieva
    • 1
  • A. D. Pomogailo
    • 1
  1. 1.Institute of Problems of Chemical PhysicsRussian Academy of SciencesChernogolovkaRussian Federation

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