Theoretical and Experimental Chemistry

, Volume 37, Issue 1, pp 36–41 | Cite as

Catalysis of the Sodium Sulfide Reduction of Methylviologene by CuS Nanoparticles

  • S. Ya. Kuchmii
  • A. V. Korzhak
  • A. E. Raevskaya
  • A. I. Kryukov


Feasibility was demonstrated for the catalysis of the sodium sulfide reduction of methylviologene (MV2+) in aqueous solution using cupric sulfide nanoparticles. The catalytic activity of the nanoparticles depends on their size. The basic features were found for the formation of the MV radical–cation in the reduction of MV2+ by HS anions in the presence of CuS nanoparticles as the catalyst. This is an equilibrium reaction.


Sodium Aqueous Solution Sulfide Catalysis Catalytic Activity 
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  1. 1.
    P. V. Kamat, Chem. Rev., 93, No. 1, 267-300 (1993).Google Scholar
  2. 2.
    A. Hagfeldt and M. M. Grätzel, Chem. Rev., 95, No. 1, 49-68 (1995).Google Scholar
  3. 3.
    A. I. Kryukov, S. Ya. Kuchmii, and V. D. Pokhodenko, Teor. Éksp. Khim., 33, No. 5, 306-321 (1997).Google Scholar
  4. 4.
    R. F. Khairutdinov, Usp. Khim., 67, No. 2, 125-139 (1998).Google Scholar
  5. 5.
    A. I. Kryukov, S. Ya. Kuchmii, A. V. Korzhak, et al., Teor. Éksp. Khim., 35, No. 2, 92-98 (1999).Google Scholar
  6. 6.
    S. N. Ushakov, Polyvinyl Alcohol and its Derivatives [in Russian], Vol. 1, Izd. Akad. Nauk SSSR, Moscow-Leningrad (1960).Google Scholar
  7. 7.
    T. Watanabe and K. Honda, J. Phys. Chem., 86, No. 14, 2617-2619 (1982).Google Scholar
  8. 8.
    P. Resh, R. J. Field, and F. W. Scheider, J. Phys. Chem., 93, No. 7, 2783-2791 (1989).Google Scholar
  9. 9.
    M. Kanemoto, T. Shiragami, C. Pac, and S. Yanegida, J. Phys. Chem., 96, No. 8, 3521-3526 (1992).Google Scholar
  10. 10.
    M. Gratzel (ed.), Energy Resources Through the Prism of Photochemistry and Catalysis [Russian translation], Mir, Moscow (1986).Google Scholar

Copyright information

© Plenum Publishing Corporation 2001

Authors and Affiliations

  • S. Ya. Kuchmii
    • 1
  • A. V. Korzhak
    • 1
  • A. E. Raevskaya
    • 1
  • A. I. Kryukov
    • 1
  1. 1.L. V. Pisarzhevskii Institute of Physical Chemistry, National Academy of Sciences of UkraineKyivUkraine

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