Clathrate and Inclusion Compounds. Part 12. Vibrational and NMR Spectroscopic Studies of Carboxylic Acid Guests in Dianin's Compound

  • J. Eric D. Davies
  • Vivienne A. Tabner
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Abstract

Infrared, Raman and solid state 13C-NMR spectra have been recorded for a range of clathrates of Dianin's compound containing straight chain aliphatic carboxylic acids (formic - octanoic) as guests. The IR, Raman and NMR spectra can be satisfactorily interpreted in terms of dimer (formic and acetic) and monomer (propionic - octanoic) occupation of the cavities. The clathrates containing straight chain alcohol guests (methanol - octanol) have also been prepared to aid in the interpretation of the NMR data.

IR spectroscopy Raman spectroscopy 13C-MAS NMR spectroscopy Dianin's compound clathrates carboxylic acids alcohols 

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References

  1. 1.
    Part 11. J.E.D. Davies and V.A. Tabner: J. Incl. Phenom. 11, 389 (1991).Google Scholar
  2. 2.
    D. D. MacNicol: in Inclusion Compounds, J.L. Atwood, J.E.D. Davies and D. D. MacNicol (Eds.), Academic Press, London, Vol. 2, pp. 1'45 (1984).Google Scholar
  3. 3.
    W. Baker, A.J. Floyd, J.F.W. McOmie, G. Pope, A.S. Weaving and J.H. Wild: J. Chem. Soc.2010 (1956).Google Scholar
  4. 4.
    M. Davies and W.C. Child: Spectrochim. Acta 21, 1195 (1965).Google Scholar
  5. 5.
    J.E.D. Davies, R.W.H. Small and V.A. Tabner: in preparation.Google Scholar
  6. 6.
    J.E.D. Davies: Comp. Enhanced Spectrosc. 3, 73 (1986).Google Scholar
  7. 7.
    K.J. Harrington: J. Therm. Anal. 28, 121 (1983).Google Scholar
  8. 8.
    J.E.D. Davies: J. Incl. Phenom. 3, 269 (1985).Google Scholar
  9. 9.
    J.A. Ripmeester and C.I. Ratcliffe: in Spectroscopic and Computational Studies of Supramolecular Systems,J.E.D. Davies (Ed.), Kluwer Academic, Dordrecht, pp. 1–27 (1992).Google Scholar
  10. 10.
    J.E.D. Davies and V.A. Knott: J. Mol. Struct. 174, 229 (1988).Google Scholar
  11. 11.
    F. Lee, E. Gabe, J.S. Tse and J.A. Ripmeester: J. Am. Chem. Soc. 110, 6014 (1988); F. Imashiro: J. Am. Chem. Soc. 115, 2231 (1993).Google Scholar
  12. 12.
    J.A. Ripmeester: J. Incl. Phenom. 1, 87 (1983/84).Google Scholar
  13. 13.
    J.L. Flippen, J. Karle and I.L. Karle: J. Am. Chem. Soc. 92, 3749 (1970).Google Scholar
  14. 14.
    J.L. Flippen and J. Karle: J. Phys. Chem. 75, 3566 (1971).Google Scholar
  15. 15.
    J.D. Roberts, F.J. Weigert, J.I. Kroschwitz and H.J. Reich: J. Am. Chem. Soc. 92, 1338 (1970).Google Scholar
  16. 16.
    P.C. Goswami, P. de Mayo, N. Ramnath, G. Bernard, N. Omkaram, J.R. Scheffer and Y.-F. Wong: Can. J. Chem. 63, 2719 (1985).Google Scholar

Copyright information

© Kluwer Academic Publishers 1997

Authors and Affiliations

  • J. Eric D. Davies
    • 1
  • Vivienne A. Tabner
    • 1
  1. 1.Environmental Science DivisionLancaster University, LancasterLancs.U.K

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