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Transition Metal Chemistry

, Volume 26, Issue 3, pp 339–344 | Cite as

Dimorphism in a 2,2′,2″-terpyridyl compound

  • Robert D. Gillard
  • Abdurrahman Sengül
  • Anthony Oldroyd
Article

Abstract

Chloro-(2,2′,2″-terpyridine)platinum(II) chloride dihydrate, [Pt(terpy)Cl]Cl · 2H2O, crystallizes from aqueous EtOH (1:1) as a yellow dimorph, but from dilute (1 M) HCl as its less stable red dimorph. X-ray powder photography shows that, above 100 °C, the red form converts into the yellow form.

Keywords

Chloride Physical Chemistry 2H2O Platinum Inorganic Chemistry 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Kluwer Academic Publishers 2001

Authors and Affiliations

  • Robert D. Gillard
    • 1
  • Abdurrahman Sengül
    • 1
  • Anthony Oldroyd
    • 2
  1. 1.Department of ChemistryUniversity of Wales CardiffPark Place, CardiffUK
  2. 2.Department of Earth SciencesUniversity of Wales CardiffPark Place, CardiffUK

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