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Water, Air, and Soil Pollution

, Volume 101, Issue 1–4, pp 197–215 | Cite as

The Henry's Law Constant of Trichloroacetic Acid

  • Derek J. Bowden
  • Simon L. Clegg
  • Peter Brimblecombe
Article

Abstract

The Henry's law constant of trichloroacetic acid [K′H (mol kg-1 atm-1) for the equilibrium CCl3COOH(g) ⇌ CCl3COOH(aq)] has been determined from measured partial pressures over aqueous solutions at 298.15 K and 308.15 K. Its value is given by: ln(K′H) = (11.21 ± 0.5) – 8.66 × 103 (l/Tr – l/T) where T (K) is temperature and Tr is equal to 298.15 K, for an aqueous phase dissociation constant (Ka) of 0.55 mol kg-1 determined from literature osmotic coefficient and electromotive force data. Accuracy is estimated to be 4–30% in the product K′HKa. Trichloroacetic acid is highly soluble and will partition strongly into aqueous atmospheric aerosols, and completely into fog and cloud water. Its occurrence and transport in the environment are therefore to be associated primarily with liquid phases.

Henry's law solubility trichloroacetic acid 

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Copyright information

© Kluwer Academic Publishers 1998

Authors and Affiliations

  • Derek J. Bowden
    • 1
  • Simon L. Clegg
    • 1
  • Peter Brimblecombe
    • 1
  1. 1.School of Environmental SciencesUniversity of East AngliaNorwichU.K. E-mail

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