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Journal of Materials Science

, Volume 33, Issue 1, pp 229–234 | Cite as

Glass formation and glass structure of the BiO1.5—PbO—CuO system

  • YI Hu
  • N.-H Liu
  • U.-L Lin
Article

Abstract

The glass-forming region of the BiO1.5—PbO—CuO system has been determined by the melt-quenching technique. The glass transition temperatures, Tg, and the first crystallization peak temperatures, Tx1, are around 240°C and 285°C, respectively. The glass structure consists of [BiO3] and [BiO6] units, and the conversion between these polyhedra mainly depends on the CuO and PbO content. The covalent characteristic in the infrared absorption spectra of the [PbOn] pyramidal units becomes significant when the glass contains more PbO.

Keywords

Polymer Crystallization Absorption Spectrum Transition Temperature Glass Transition 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Chapman and Hall 1998

Authors and Affiliations

  • YI Hu
    • 1
  • N.-H Liu
    • 1
  • U.-L Lin
    • 1
  1. 1.Department of Materials EngineeringTatung Institute of TechnologyTaipeiTaiwan

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