Advertisement

Chemistry of Natural Compounds

, Volume 36, Issue 5, pp 501–505 | Cite as

Triterpenoid Glycosides of Fatsia japonica. II. Isolation and Structure of Glycosides from the Leaves

  • V. I. Grishkovets
  • E. A. Sobolev
  • A. S. Shashkov
  • V. Ya. Chirva
Article

Abstract

The previously known triterpenoid 3-O-α-L-arabinopyranosides of oleanolic and echinocystic acids and hederagenin, 3-O-β-D-glucopyranosyl-(1→2)-O-α-L-arabinopyranosides of oleanolic acid and hederagenin, in addition to 28-O-α-L-rhamnopyranosyl-(1→4)-O-β-D-glucopyranosyl-(1→6)-O-β-D-glucopyranosyl ethers of the 3-O-α-L-arabinopyranoside of hederagenin, and 3-O-β-D-glucopyranosyl-(1→2)-O-α-L-arabinopyranosides of oleanolic acid and hederagenin, respectively, are isolated from leaves ofFatsia japonica(Araliaceae). The structures of the glycosides are confirmed by chemical methods and13C NMR spectroscopy

Fatsia japonica triterpenoid glycosides NMR (13C, COSY, ROESY) 

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

REFERENCES

  1. 1.
    K. Ohta, Keio Igaku, 31111 (1924); K. Ohta, Keio Igaku, 4, 157 (1924); M. Kotake, K. Taguchi, and T. Okamoto, Rikagaku Kenkyusho Hokoku, 12, 590 (1933)Google Scholar
  2. 2.
    T. Aoki, Y. Tanio, and T. Suga, Phytochemistry, 15, 781 (1976).Google Scholar
  3. 3.
    T. Tomimori and H. Kizu, Yakugaku Zasshi, 99, 92 (1979).Google Scholar
  4. 4.
    Z. S. Kemoklidze, G. E. Dekanosidze, O. D. Dzhikiya, M. M. Vugal´ter, and E. P. Kemertelidze, Khim. Prir. Soedin., 788 (1982).Google Scholar
  5. 5.
    Z. S. Kemoklidze, G. E. Dekanosidze, O. D. Dzhikiya, M. M. Vugal´ter, and E. P. Kemertelidze, Khim. Prir. Soedin., 252 (1984).Google Scholar
  6. 6.
    Z. S. Kemoklidze, G. E. Dekanosidze, O. D. Dzhikiya, M. M. Vugal´ter, and E. P. Kemertelidze, Soobshch. Akad. Nauk Gruz., 125, 569 (1987).Google Scholar
  7. 7.
    V. I. Grishkovets, N. V. Tolkacheva, A. S. Shashkov, and V. Ya. Chirva, Khim. Prir. Soedin., 686 (1991).Google Scholar
  8. 8.
    V. I. Grishkovets, D. Yu. Sidorov, L. A. Yakovishin, N. N. Arnautov, A. S. Shashkov, and V. Ya. Chirva, Khim. Prir. Soedin., 377 (1996).Google Scholar
  9. 9.
    A. A. Loloiko, V. I. Grishkovets, A. S. Shashkov, and V. Ya. Chirva, Khim. Prir. Soedin., 228 (1990).Google Scholar
  10. 10.
    V. I. Grishkovets, S. V. Godin, O. Ya. Tsvetkov, A. S. Shashkov, and V. Ya. Chirva, Khim. Prir. Soedin., 411 (1997).Google Scholar
  11. 11.
    H. Kohda, S. Tanaka, and Y. Yamaoka, Chem. Pharm. Bull., 39, 3380 (1990).Google Scholar
  12. 12.
    C. J. Shao, R. Kasai, J. D. Xu, and O. Tanaka, Chem. Pharm. Bull., 37, 42 (1989).Google Scholar
  13. 13.
    C. J. Shao, R. Kasai, J. D. Xu, and O. Tanaka, Chem. Pharm. Bull., 36, 601 (1988).Google Scholar
  14. 14.
    V. I. Grishkovets, O. Ya. Tsvetkov, A. S. Shashkov, and V. Ya. Chirva, Bioorg. Khim., 21, 468 (1995).Google Scholar
  15. 15.
    V. I. Grishkovets, N. V. Tolkacheva, A. S. Shashkov, and V. Ya. Chirva, Khim. Prir. Soedin., 522 (1992).Google Scholar
  16. 16.
    K. Hostettmann and A. Marston, Saponins, Cambridge University Press, Cambridge (1995).Google Scholar
  17. 17.
    N. Gopalsamy, J. Gueho, H. R. Julien, A. W. Owadally, and K. Hostettmann, Phytochemistry, 29, 793 (1990).Google Scholar
  18. 18.
    R. Elias, A. M. Diaz Lanza, E. Vidal-Ollivier, G. Balansard, R. Faure, and A. Babadjamian, J. Nat. Prod., 54, 98 (1991).Google Scholar
  19. 19.
    A. S. Shashkov and E. P. Kermertelidze, Khim. Prir. Soedin., 229 (1988).Google Scholar

Copyright information

© Plenum Publishing Corporation 2000

Authors and Affiliations

  • V. I. Grishkovets
    • 1
  • E. A. Sobolev
    • 1
  • A. S. Shashkov
    • 2
  • V. Ya. Chirva
    • 1
  1. 1.V. I. Vernadskii Tavricheskii National UniversitySimferopol'
  2. 2.N. D. Zelinskii Institute of Organic ChemistryRussian Academy of SciencesMoscow

Personalised recommendations