Skip to main content
SpringerLink
Log in

Green Approach to Corrosion Inhibition of Mild Steel by Lignin Sulfonate in Acidic Media

  • Material
  • Published:
Journal of Iron and Steel Research International Aims and scope Submit manuscript

Abstract

The inhibition effect of lignin sulfonate against corrosion for mild steel in acidic solution has been examined by means of FTIR (fourier transform infrared spectroscopy), FAA (flame atomic absorption) spectroscopy, SEM (scanning electron microscope), EDS (energy dispersive X-ray spectroscopy), and mass loss techniques. The results revealed that lignin is a beneficial inhibitor for mild steel corrosion in acidic medium. It has been further found that Langmuir adsorption isotherm is obeyed by the tested lignin s adsorption over the surface of mild steel. The range of inhibition efficiency (IE) in 2 mol • L−1 HCl was found to be 75.88%–87.88% for Reax 88A, 40.72%–60.32% for Reax 88B, and 54.32% –63.03% for Reax 100M, after immersed at 298 K for 24 h time.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. A. S. Fouda, H. A. Mostafa, F. El-Taib Haekel, G. Y. Elewady, Corros. Sci. 47 (2005) 1988–2004.

    Article  Google Scholar 

  2. H. L. Wang, R. B. Liu, J. Xin, Corros. Sci. 46 (2004) 2455–2466.

    Article  Google Scholar 

  3. M. A. Amin, S. S. Abd El-Rehim, E. E. F. El-Sherbini, R. S. Bayoumi, Electrochim. Acta 52 (2007) 3588–3600.

    Article  Google Scholar 

  4. F. Bentiss, M. Traisnel, M. Lagrenee, Corros. Sci. 42 (2000) 127–146.

    Article  Google Scholar 

  5. S. K. Shukla, M. A. Quraishi, Corros. Sci. 52 (2010) 314–321.

    Article  Google Scholar 

  6. A. K. Maayta, N. A. Al-Rawashdeh, Corros. Sci. 46 (2004) 1129–1140.

    Article  Google Scholar 

  7. A. N. Ababneh, M. A. Sheban, M. A. Abu-Dalo, J. Mater. Civil Eng. 24 (2012) 141–151.

    Article  Google Scholar 

  8. A. Ababneh, M. Sheban, M. Abu-Dalo, S. Andreescu, Jordan J. Civil Eng. 3 (2009) 91–102.

    Google Scholar 

  9. M. Sheban, M. Abu-Dalo, A. Ababneh, S. Andreescu, Anti-Corros. Methods Mater. 54 (2007) 135–147.

    Article  Google Scholar 

  10. M. M. Al-Abdallah, A. K. Maayta, M. A. Al-Qudah, N. A. F. Al-Rawashdeh, The Open Corros. J. 2 (2009) 71–76.

    Article  Google Scholar 

  11. M. A. Abu-Dalo, A. A. Othman, N. A. F. Al-Rawashdeh, Int. J. Electrochem. Sci. 7 (2012) 9303–9324.

    Google Scholar 

  12. T. T. Bataineh, M. A. Al-Qudah, E. M. Nawafleh, N. A. F. Al-Rawashdeh, Int. J. Electrochem. Sci. 9 (2014) 3543–3557.

    Google Scholar 

  13. I. Radojcic, K. Berkovic, S. Kovac, J. Vorkapic-Furac, Corros. Sci. 50 (2008) 1498–1504.

    Article  Google Scholar 

  14. P. B. Raja, A. K. Qureshi, A. A. Rahim, H. Osman, K. Awang, Corros. Sci. 69 (2013) 292–301.

    Article  Google Scholar 

  15. M. A. Migahed, A. M. Abdul-Raheim, A. M. Atta, A. W. Brostow, Mater. Chem. Phys. 121 (2010) 208–214.

    Article  Google Scholar 

  16. A. K. Maayta, N. A. F. Al-Rawashdeh, Jordan J. Chem. 5 (2010) 175–189.

    Google Scholar 

  17. A. Ruosan, N. A. F. Al-Rawashdeh, Corros. Eng. Sci. Tech. 41 (2006) 235–239.

    Article  Google Scholar 

  18. N. A. F. Al-Rawashdeh, A. K. Maayta, Anti-Corros. Methods Mater. 52 (2005) 160–166.

    Article  Google Scholar 

  19. C. P. Vance, T. K. Kilrk, R. T. Sherwood, Annu. Rev. Phytopathol. 18 (1980) 259–288.

    Article  Google Scholar 

  20. W. Boerjan, J. Ralph, M. Baucher, Ann. Rev. Plant Biol. 54 (2003) 519–549.

    Article  Google Scholar 

  21. E. Akbarzadeh, M. N. Mohamad Ibrahim, A. A. Rahim, Int. J. Electrochem. Sci. 6 (2011) 5396–5416.

    Google Scholar 

  22. P. Merdy, E. Guillon, M. Aplincourt, New J. Chem. 26 (2002) 1638–1645.

    Article  Google Scholar 

  23. M. A. Abu-Dalo, N. A. F. Al-Rawashdeh, A. Ababneh, Desalination 313 (2013) 105–114.

    Article  Google Scholar 

  24. A. Rucinskiene, G. Bikulcius, L. Gudaviciute, E. Juzeliunas, Electrochem. Comm. 4 (2002) 86–91.

    Article  Google Scholar 

  25. P. C. Okafor, U. J. Ekpe, E. E. Ebenso, E. M. Umoren, K. E. Leizou, Bull. Electrochem. 21 (2005) 347–352.

    Google Scholar 

  26. A. Y. El-Etre, Corros. Sci. 45 (2003) 2485–2495.

    Article  Google Scholar 

  27. M. Lebrini, F. Bentiss, H. Vezin, M. Lagrenee, Corros. Sci. 48 (2006) 1279–1291.

    Article  Google Scholar 

  28. X. Guo, S. Zhang, X. Q. Shan, J. Hazard Mater. 151 (2008) 134–142.

    Article  Google Scholar 

  29. E. A. Noor, Int. J. Electrochem. Sci. 2 (2007) 996–1017.

    Google Scholar 

  30. A. Altwaiq, S. J. Khouri , S. Al-luaibi , R. Lehmann, H. Drücker, C. Vogt, J. Mater. Environ. Sci. 2 (2011) 259–270.

    Google Scholar 

  31. G. Moretti, F. Guidi, G. Grion, Corros. Sci. 46 (2004) 387–403.

    Article  Google Scholar 

  32. Y. Abboud, A. Abourriche, T. Saffaj, M. Berrada, M. Charrouf, A. Bennamara, H. Hannache, Desalination 237 (2009) 175–189.

    Article  Google Scholar 

  33. E. E. Ebenso, I. B. Obot, Int. J. Electrochem. Sci. 5 (2010) 2012–2035.

    Google Scholar 

  34. T. Szauer, A. Brandt, Electrochim. Acta 26 (1981) 1253–1256.

    Article  Google Scholar 

  35. E. A. Noor, A. H. Al-Moubaraki, Mater. Chem. Phys. 110 (2008) 145–154.

    Article  Google Scholar 

  36. Z. Li, Y. Ge, J. Braz. Chem. Soc. 22 (2011) 1866–1871.

    Article  Google Scholar 

  37. A. L. Smith, Applied Infrared Spectroscopy: Fundamentals, Techniques, and Analytical Problem-Solving, Wiley, New York, USA, 1979.

    Google Scholar 

  38. K. V. Sarkanen, C. H. Ludwig, Lignins Occurrence, Formation, Structure and Reactions, Wiley-Interscience, New York, USA, 1971.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Applied Chemical Sciences, Jordan University of Science and Technology, 22110, Irbid, Jordan

    Muna A. Abu-Dalo (Doctor, Associate Professor), Nathir A. F. Al-Rawashdeh & Ahmed A. Mutlaq

Authors
  1. Muna A. Abu-Dalo
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Nathir A. F. Al-Rawashdeh
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Ahmed A. Mutlaq
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Muna A. Abu-Dalo.

Additional information

Foundation Item: Item Sponsored by Research Fund of Jordan University of Science and Technology (161/2012)

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Abu-Dalo, M.A., Al-Rawashdeh, N.A.F. & Mutlaq, A.A. Green Approach to Corrosion Inhibition of Mild Steel by Lignin Sulfonate in Acidic Media. J. Iron Steel Res. Int. 23, 722–732 (2016). https://doi.org/10.1016/S1006-706X(16)30112-1

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1016/S1006-706X(16)30112-1

Key words

Search

Navigation