Mechanisms of swelling of iron ore oxidized pellets in high reduction potential atmosphere

Abstract

The influences of the time, temperature and atmosphere on the reduction swelling of oxidized pellets were investigated by single factor experiments. The mechanisms of reduction swelling of oxidized pellets were analyzed and investigated by SEM (scanning electron microscopy) and XRD (X-ray diffractometer) analysis. The results show that the change rules of reduction swelling index of oxidized pellets in different reduction atmospheres are very similar. With the increase of reduction time, the reduction swelling index moves up firstly and then down. When the reduction temperature is above 900 °C, α-quartz turns into α-tridymite, and the transition generates additional volume expansion effect. The reduction swelling index changes faster in H₂ atmosphere than in CO atmosphere. Increasing H₂ content in the reduction atmosphere is useful to decrease the reduction swelling index, but it is also easy to cause oxidized pellets cracking.