Abstract
The reactions of the atomic oxygen radical anion O− with CH3-S-CH2-CN m the gas phase have been examined with Fourier transform ion cyclotron resonance in combination with tandem mass spectrometric experiments performed with a double-focusing quadrupole hybrid instrument. Deuterium labeling has revealed that the O− ion reacts with CH3-S-CH2-CN by proton abstraction from the methylene group as well as by competing 1,1- and 1,3-H +2 abstractions to afford isomeric radical anions. High kinetic energy (8 keV) collision-induced charge reversal experiments indicate that the 1,1-H +.2 -abstraction leads to a \(CH_3 - S - \bar C - CN\) carbene ion, whereas the 1,3-H +2 abstraction yields a novel sulfur-containing distonic radical anion, which is formulated as \(CH_2 - S - \bar CH - CN\).
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Born, M., Ingemann, S. & Nibbering, N.M.M. Formation and characterization of the sulfur-containing distonic radical anion, \(CH_2 - S - \bar CH - CN\), in the gas phase, in the gas phase. J Am Soc Mass Spectrom 6, 71–75 (1995). https://doi.org/10.1016/1044-0305(94)00089-I
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DOI: https://doi.org/10.1016/1044-0305(94)00089-I