Abstract
Three different devices that-can be used for surface-induced dissociation (SID) m tandem quadrupole instruments are compared here. The designs were compared by examining the fragmentation of several compounds including benzene, W(CO)6, and (CH3)4N+. These studies show that SID can be readily implemented on a variety of tandem quadrupoIe instruments and that the spectra obtained with the in-line and 90° instruments are similar. Evidence is presented that confirms that high average internal energies and narrow distributions of internal energy are available by this technique. Efficiencies for fragmentation of odd-electron ions are on the order of those previously reported by others. The overall SID efficiency for even-electron ions is higher than that for odd-electron ions of similar structure.
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Wysocki, V.H., Ding, JM., Jones, J.L. et al. Surface-induced dissociation in tandem quadrupole mass spectrometers: A comparison of three designs. J Am Soc Mass Spectrom 3, 27–32 (1992). https://doi.org/10.1016/1044-0305(92)85015-C
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DOI: https://doi.org/10.1016/1044-0305(92)85015-C