Fragmentations and reactions of the organophosphate insecticide Diazinon and its oxygen analog Diazoxon studied by electrospray ionization ion trap mass spectrometry

  • J. D. Barr
  • A. J. Bell
  • M. Bird
  • J. L. Mundy
  • J. Murrell
  • C. M. Timperley
  • P. Watts
  • F. Ferrante
Articles

Abstract

The fragmentations and reactions of Diazinon and related compounds have been studied by electrospray ionization ion trap mass spectrometry. Several novel fragmentation and rearrangements have been observed, including an intramolecular thiono-thiolo rearrangement. The stability, in the gas-phase, of the protomers of 2-isopropyl-4-methyl-6-pyrimidinol has been demonstrated. The complexity of the gas phase ion processes observed suggest that, at present, caution should be exercised in using this approach for the analysis of environmental and other samples until our understanding of these processes increases considerably.

Copyright information

© American Society for Mass Spectrometry 2005

Authors and Affiliations

  • J. D. Barr
    • 1
  • A. J. Bell
    • 3
  • M. Bird
    • 3
  • J. L. Mundy
    • 3
  • J. Murrell
    • 3
  • C. M. Timperley
    • 3
  • P. Watts
    • 3
  • F. Ferrante
    • 4
  1. 1.Department of ChemistrySouthampton UniversitySouthamptonUnited Kingdom
  2. 2.Institut Català d’Investigació Química (ICIQ)TarragonaSpain
  3. 3.Detection DepartmentProton DownSalisburyUnited Kingdom
  4. 4.Dipartmento di Chimica Fisica F. AccascinaUniversità degli Studi di PalermoPalermoItaly

Personalised recommendations