A new flowing afterglow-guided ion beam tandem mass spectrometer. Applications to the thermochemistry of polyiodide ions

  • Khanh Do
  • Timothy P. Klein
  • Cynthia Ann Pommerening
  • Lee S. Sunderlin
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Abstract

A new flowing afterglow-guided ion beam tandem mass spectrometer has been constructed. The tandem mass spectrometer has a linear quadrupole-octopole-quadrupole geometry. The apparatus has been successfully tested for the measurement of reaction rates and endothermic reaction thresholds. The new instrument has been used to determine 0 K bond strengths in two polyiodide ions: D(I2−I−)=126±6 kJ/mol and D(I2−I 3 − )=49±6 kJ/mol. These values compare well to recent computational results. Electron affinity (EA)(I3)=4.15±0.12 eV can be derived from this work and values in the literature.

Keywords

Bond Strength Electron Affinity Flow Tube Tandem Mass Spectrometer Couple Cluster Theory 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.
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Copyright information

© American Society for Mass Spectrometry 1997

Authors and Affiliations

  • Khanh Do
    • 1
  • Timothy P. Klein
    • 1
  • Cynthia Ann Pommerening
    • 1
  • Lee S. Sunderlin
    • 1
  1. 1.Department of ChemistryNorthern Illinois UniversityDeKalbUSA

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