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Lithium-cation and proton affinities of sulfoxides and sulfones: A fourier transform ion cyclotron resonance study

  • Erwin Buncel
  • Michèle Decouzon
  • Alessandra Formento
  • Jean-François GalEmail author
  • Marta Herreros
  • Lewyn Li
  • Pierre-Charles Maria
  • Ilmar Koppel
  • Riho Kurg
Articles

Abstract

The kinetic method was used for the quantitative determination of lithium-cation affinities by Fourier transform ion cyclotron resonance. This method was applied to a series of XYSO and XYSO2 compounds. Proton basicities of the SO and SO2 compounds were also determined. When comparison is made between Li+ basicities and proton basicities, a linear regression encompassing XYSO and XYSO2 families suggests that Li+ may be bonded in a similar way to the SO and SO2 moieties, that is, to only one oxygen on the latter. PM3 calculations support this hypothesis.

Keywords

Proton Affinity Kinetic Method PhNO2 Proton Basicity HCO2Et 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© American Society for Mass Spectrometry 1997

Authors and Affiliations

  • Erwin Buncel
    • 1
  • Michèle Decouzon
    • 2
  • Alessandra Formento
    • 2
  • Jean-François Gal
    • 2
    Email author
  • Marta Herreros
    • 2
  • Lewyn Li
    • 2
  • Pierre-Charles Maria
    • 2
  • Ilmar Koppel
    • 3
  • Riho Kurg
    • 3
  1. 1.Department of ChemistryQueen’s UniversityKingstonCanada
  2. 2.Groupe FT-ICR, Laboratoire de Chimie Physique OrganiqueUniversité de Nice-Sophia AntipolisNice Cedex 2France
  3. 3.Institute of Chemical PhysicsTartu UniversityTartuEstonia

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