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Novel chemically cross-linked self-molding particulate sorbents as solid-phase extraction media

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  • Novel Analytical Approaches towards SDGs
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Abstract

Here, we describe novel, chemically cross-linked, self-molding particulate polymer sorbents that are utilized as a molding-type solid-phase extraction medium (M-SPEM), which exhibits high permeability and rigidness. To fabricate such M-SPEM, first, polyethyleneimine (PEI)-modified reversed-phase (RP)-type particulate sorbents were synthesized, thereafter, they were chemically cross-linked by a polymer having many epoxy groups together with additional PEI. By optimizing the binding conditions of the particulate sorbents, the resultant M-SPEM has almost the same adsorption properties as the corresponding unmolded particulate sorbent for some polar (e.g., uracil and adenine) compounds. The binding technique proposed here is expected to facilitate the fabrication of molding-type sorbents and improve the performance of the SPE procedure.

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Acknowledgements

This study was partly supported by JSPS KAKENHI Grant Number 20K05571 (Grant-in-Aid for Scientific Research (C) for H.M.), 19H02751 (Grant-in-Aid for Scientific Research (B) for N.T.), and the Hibi Science Foundation. The authors would like to thank Enago (www.enago.jp) for the English language review.

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Correspondence to Hiroya Murakami.

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Miki, Y., Murakami, H., Gotoh, M. et al. Novel chemically cross-linked self-molding particulate sorbents as solid-phase extraction media. ANAL. SCI. 39, 749–754 (2023). https://doi.org/10.1007/s44211-022-00179-3

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  • DOI: https://doi.org/10.1007/s44211-022-00179-3

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