Abstract
Studies on the magnetic and electrical behavior of the perovskite complex EuMn0.5Fe0.5O3, which crystallizes in the orthorhombic structure and belongs to the symmetry group (Pbnm), have been conducted based on this study using numerical techniques More specifically, we investigated the magnetic and electrical properties of the EuMn0.5Fe0.5O3 material using approximations created within the framework of density functional theory, such as a full potential linearized augmented plane wave and the generalized gradient approximation. The magnetization, the transition temperature, as well as the fluctuation of the magnetic entropy, the specific heat, and the variation of the adiabatic temperature and relative cooling power. were analyzed using the Monte Carlo simulations when it was discovered via research that this compound exhibit spin-reorientation phenomena as it behaves like a conducting metal.
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S. Cao, H. Zhao, B. Kang, J. Zhang, W. Ren, Temperature induced spin switching in SmFeO3 single crystal. Sci Rep. 4, 5960 (2014)
S.J. Yuan, W. Ren, F. Hong, Y.B. Wang, J.C. Zhang, L. Bellaiche, S.X. Cao, G. Cao, Spin switching and magnetization reversal in single-crystal NdFeO. Phys. Rev. B. 87, 184405 (2013)
F. Pomiro, R.D. Sánchez, G. Cuello, A. Maignan, C. Martin, R.E. Carbonio, Spin reorientation, magnetization reversal, and negative thermal expansion observed in RFe0.5Cr0.5O3 perovskites (R=Lu, Yb, Tm). Phys. Rev. B. 94, 134402 (2016)
P. Mandal, C.R. Serrao, E. Suard, V. Caignant, B. Raveau, A. Sundaresan, C.N.R. Rao, Spin reorientation and magnetization reversal in perovskite oxides, YFe1-xMnxO3: A neutron diffraction study. J. Solid. State. Chem. 197, 408 (2013)
H. Shen, Z. Cheng, F. Hong, J. Xu, S. Yuan, S. Cao, X. Wang, Magnetic field induced discontinuous spin reorientation in ErFeO3 single crystal. Appl. Phys. Lett. 103, 192404 (2013)
W. Sławiński, R. Przeniosło, I. Sosnowska, E. Suard, Spin reorientation and structural changes in NdFeO3. J. Phys.: Condens. Matter 17, 29 (2005)
A. Stroppa, M. Marsman, G. Kresse, S. Picozzi, The multiferroic phase of DyFeO3: an ab initio study. New. J. Physics. 12, 093026 (2010)
S. Dong, J.M. Liu, Recent Progress of Multiferroic Perovskite Manganites. Mod. Phys. Lett. B. 26(9), 1230004 (2012)
M. Fiebig, T. Lottermoser, D. Frohlich, A.V. Goltsev, R. Pisarev, Observation of coupled magnetic and electric domains. Nature 419, 818–820 (2002)
B. Raveau, A. Maignan, C. Martin, M. Hervieu, Colossal Magnetoresistance Manganite Perovskites: Relations between Crystal Chemistry and Properties. Chem. Mater 10, 2641–2652 (1998)
R. von Helmolt, J. Wecker, B. Holzapfel, L. Schultz, K. Samwer, Giant negative magnetoresistance in perovskitelike La2/3Ba1/3MnOx ferromagnetic films. Phys. Rev. Lett. 71, 2331 (1993)
K. Chahara, T. Ohno, M. Kasai, Y. Kozono, Magnetoresistance in magnetic manganese oxide with intrinsic antiferromagnetic spin structure. Appl. Phys. Lett. 1993, 63 (1990)
E. Dagotto, T. Hotta, A. Moreo, Colossal magnetoresistant materials: the key role of phase separation. Phys. Rep. 344, 1–153 (2001)
J.C. Debnath, R. Zeng, J.H. Kim, S.X. Dou, Large magnetic entropy changes near room temperature in La0.7(Ca0.27Ag0.03) MnO3 perovskite. J. Alloys. Comp. 509, 3699–3704 (2011)
T. Yamaguchi, Theory of spin reorientation in rare-earth orthochromites and Orthoferrites. J. Phys. Chem. Solids. 35, 479–500 (1974)
Moriya, T. Magnetism. Academic Press, New York, 85 (1963).
T.C. Gibb.: (1981). Europium-151 Mössbauer spectra of some orthorhombic perovskites. J. Chem. Soc. Dalton Trans. 2245–2249
K. Sultan, R. Samad, S.A.U. Islam, M.Z. Habib, M. Ikram, Effect of Rare Earth Ions (R = Pr, Eu and Ho) on the Structural and Electrical Properties of Orthoferrites. J. Electron. Mater. 48, 6003–6007 (2019)
R.L. White, Review of Recent Work on the Magnetic and Spectroscopic Properties of the Rare-Earth Orthoferrites. J. Appl. Phys. 40, 1061 (1969)
H.A. Jahn, E. Teller, Stability of Polyatomic Molecules in Degenerate Electronic States. I. Orbital Degeneracy. Proc. Roy. Soc. A. 161(905), 220–235 (1937)
A. Tripathy, S. Bhuyan, S.N. Das, R.N.P. Choudhary, J. Korean Ceram. Soc. 60, 373–380 (2023)
S. Priyadarshinee, J. Pati, R. Mahapatra, P. Mohanty, D.K. Mishra, Jy. Mohapatra. J. Korean Ceram. Soc. 60, 203–214 (2023)
B. Chan Kim, C. Cheon, J. Korean Ceram. Soc. 57, 578–584 (2020)
H. Bae, Y. Shin, L. Mathur, D. Lee, S.-J. Song, J. Korean Ceram. Soc. 59, 876–888 (2022)
P.J. Perdew, K. Burke, Y. Wang, Generalized gradient approximation for the exchange-correlation hole of a many-electron system. Phys. Rev. B. 54, 16533 (1996)
P. Blaha, K. Schwartz, G. K. H. Madsen, D. Kvasnicka, J. Luitz.: (2001). WIEN2K: An Augmented Plane Wave Plus Local Orbitals Program for Calculating Crystal Properties. Vienna University of Technology, Austria.
M.C. Silva-Santana, C.A. DaSilva, J.M. Santos, J.A. DaSilva-Santos, P. Barrozo, L. De Los Santos, N.O.M. Valladares, J Phys. Chem. Sol. 147, 109668 (2020)
N. Metropolis, A.W. Rosenbluth, M.N. Rosenbluth, A.H. Teller, Equation of state calculations by fast computing machines. J. Chem. Phys. 21, 6 (1953)
K.M. Wong, M. Irfan, A. Mahmood, G. Murtaza, First principles study of the structuraland optoelectronic properties of the AGInSbO6 (A= Ca, Sr, Ba) compounds. Optik 130, 517–524 (2017)
G. Murtaza, I. Ahmad, First principle study of the structural and optoelectronic properties of cubic perovskites CsPbM3 (M= Cl, Br, I). Phys. B Cond. Matter. 406, 3222–3229 (2011)
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M.I: conceptualization, methodology, software, investigation, validation, formal analysis, formal analysis, no funding acquisition, writing—original draft preparation, writing—reviewing and editing, supervision, project administration. R.M: conceptualization, methodology, software, investigation, validation, formal analysis, formal analysis, no funding acquisition, writing—original draft preparation, writing—reviewing and editing, supervision, project administration.
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Imami, M., Masrour, R. Magnetic, electric and magnetocaloric properties of EuFe0.5Mn0.5O3 perovskite: Monte Carlo study and ab-initio calculations. J. Korean Ceram. Soc. 61, 83–90 (2024). https://doi.org/10.1007/s43207-023-00329-x
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DOI: https://doi.org/10.1007/s43207-023-00329-x