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Tourmaline as versatile additive to improve the performance of thin-film composite forward osmosis membrane

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Abstract

Modified tourmaline (TM) minerals were prepared using hydrothermal method, followed by surface coating with sorbitan monostearate (SPAN-60), as well as characterization of FTIR, XRD, zeta potential, and antibacterial property analysis. The as-synthesized TM particles were incorporated with polyethersulfone (PES) substrate of thin-film composite forward osmosis (TFC-FO) membrane for alleviated structural resistance and biofouling tendency based on two different approaches, polymer blending into and polymer coating onto the inorganic deposited layer, respectively. To investigate the micromorphology of the prepared membranes, SEM was used to obtain the surface and cross-section images, and elemental mapping with EDS was applied to analyze the dispersion state of TM particles in PES matrix. In comparison to the control membrane, the water flux in FO mode of the nanocomposite membranes significantly increased with TM loading content, which is attributed to the optimization of microstructure and enhancement of inner osmotic pressure resulted from the ions released by TM. More importantly, the results showed TM endowed antibacterial activity in the membrane when TM deposited layer combined with the bottom surface of substrate. It is confirmed by our work that TM is a versatile additive for FO membrane with high performance.

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References

  1. A.M. Awad, R. Jalab, J. Minier-Matar, S. Adham, M.S. Nasser, S. Judd, The status of forward osmosis technology implementation. Desalination 461, 10–21 (2019)

    Article  CAS  Google Scholar 

  2. Z. Alihemati, S.A. Hashemifard, T. Matsuura, A.F. Ismail, N. Hilal, Current status and challenges of fabricating thin film composite forward osmosis membrane: A comprehensive roadmap. Desalination 491, 114557 (2020)

    Article  CAS  Google Scholar 

  3. J.J. Beh, E.P. Ng, J.Y. Sum, B.S. Ooi, Thermodynamics and kinetics control of support layer synthesis for enhanced thin film composite membrane performance. J. Appl. Polym. Sci. 135, 45802 (2018)

    Article  Google Scholar 

  4. Q. Zhang, Z. Zhang, L. Dai, H. Wang, S. Li, S. Zhang, Novel insights into the interplay between support and active layer in the thin film composite polyamide membranes. J. Membr. Sci. 537, 372–383 (2017)

    Article  CAS  Google Scholar 

  5. W. Zhao, H. Liu, Y. Liu, M. Jian, L. Gao, H. Wang, X. Zhang, Thin-film nanocomposite forward-osmosis membranes on hydrophilic microfiltration support with an intermediate layer of graphene oxide and multiwall carbon nanotube. ACS Appl. Mater. Interfaces. 10, 34464–34474 (2018)

    Article  CAS  Google Scholar 

  6. S. Phuntsho, J.E. Kim, V.H. Tran, S. Tahara, N. Uehara, N. Maruko, H. Matsuno, S. Lim, H.K. Shon, Free-standing, thin-film, symmetric membranes: Next-generation membranes for engineered osmosis. J. Membr. Sci. 607, 10 (2020)

    Article  Google Scholar 

  7. M. He, L. Wang, Y. Lv, X. Wang, Z. Zhang, Q. Cui, J. Zhu, Effect of a novel hydrophilic double-skinned support layer on improving anti-fouling performance of thin-film composite forward osmosis membrane. Colloids Surf. A: Physicochem. Eng. Aspects 602, 125081 (2020)

    Article  CAS  Google Scholar 

  8. L. Qi, Y. Hu, Z. Liu, X. An, E. Bar-Zeev, Improved anti-biofouling performance of thin-film composite forward-osmosis membranes containing passive and active moieties. Environ. Sci. Technol. 52, 9684–9693 (2018)

    Article  CAS  Google Scholar 

  9. Y.-H. Chiao, A. Sengupta, S.-T. Chen, S.-H. Huang, C.-C. Hu, W.-S. Hung, Y. Chang, X. Qian, S.R. Wickramasinghe, K.-R. Lee, J.-Y. Lai, Zwitterion augmented polyamide membrane for improved forward osmosis performance with significant antifouling characteristics. Sep. Purif. Technol. 212, 316–325 (2019)

    Article  CAS  Google Scholar 

  10. Q. She, R. Wang, A.G. Fane, C.Y. Tang, Membrane fouling in osmotically driven membrane processes: A review. J. Membr. Sci. 499, 201–233 (2016)

    Article  CAS  Google Scholar 

  11. I. Ibrar, O. Naji, A. Sharif, A. Malekizadeh, A. Alhawari, A.A. Alanezi, A. Altaee, A review of fouling mechanisms, control strategies and real-time fouling monitoring techniques in forward osmosis. Water 11, 695 (2019)

    Article  CAS  Google Scholar 

  12. J. Zhu, J. Hou, Y. Zhang, M. Tian, T. He, J. Liu, V. Chen, Polymeric antimicrobial membranes enabled by nanomaterials for water treatment. J. Membr. Sci. 550, 173–197 (2018)

    Article  CAS  Google Scholar 

  13. W. Sun, J. Shi, C. Chen, N. Li, Z. Xu, J. Li, H. Lv, X. Qian, L. Zhao, A review on organic–inorganic hybrid nanocomposite membranes: a versatile tool to overcome the barriers of forward osmosis. RSC Adv. 8, 10040–10056 (2018)

    Article  CAS  Google Scholar 

  14. K.Y. Lee, D.B. Mahadik, V.G. Parale, H.H. Park, Composites of silica aerogels with organics: a review of synthesis and mechanical properties. J. Korean Ceram. Soc 57(1), 1–23 (2020)

    Article  Google Scholar 

  15. S. Yadav, H. Saleem, I. Ibrar, O. Naji, A.A. Hawari, A.A. Alanezi, S.J. Zaidi, A. Altaee, J. Zhou, Recent developments in forward osmosis membranes using carbon-based nanomaterials. Desalination 482, 114375 (2020)

    Article  CAS  Google Scholar 

  16. W. Suwaileh, N. Pathak, H. Shon, N. Hilal, Forward osmosis membranes and processes: A comprehensive review of research trends and future outlook. Desalination 485, 114455 (2020)

    Article  CAS  Google Scholar 

  17. Y. Wang, T. Xu, Anchoring hydrophilic polymer in substrate: An easy approach for improving the performance of TFC FO membrane. J. Membr. Sci. 476, 330–339 (2015)

    Article  CAS  Google Scholar 

  18. Y. Wang, R. Ou, H. Wang, T. Xu, Graphene oxide modified graphitic carbon nitride as a modifier for thin film composite forward osmosis membrane. J. Membr. Sci. 475, 281–289 (2015)

    Article  CAS  Google Scholar 

  19. Y.H. Teow, A.W. Mohammad, New generation nanomaterials for water desalination: A review. Desalination 451, 2–17 (2019)

    Article  CAS  Google Scholar 

  20. Y. Hao, M. Tian, H. Zhao, L. Qu, S. Zhu, X. Zhang, S. Chen, K. Wang, J. Ran, High efficiency electrothermal graphene/tourmaline composite fabric joule heater with durable abrasion resistance via a spray coating route. Ind. Eng. Chem. Res. 57, 13437–13448 (2018)

    Article  CAS  Google Scholar 

  21. J. Li, S. Tabassum, Synergism of uncoupler dicoumarin and nonmetallic mineral tourmaline for the sewage sludge treatment process: Reducing sludge generation. Clean. Eng. Technol. 1, 100013 (2020)

    Article  Google Scholar 

  22. F. Bosi, Tourmaline crystal chemistry. Am. Miner.: J. Earth Planet. Mater. 103, 298–306 (2018)

    Article  Google Scholar 

  23. F. Bosi, H. Skogby, U. Hålenius, M.E. Ciriotti, Experimental cation redistribution in the tourmaline lucchesiite, CaFe 2+ 3 Al 6 (Si 6 O 18)(BO 3) 3 (OH) 3 O. Phys. Chem. Miner. 45, 621–632 (2018)

    Article  CAS  Google Scholar 

  24. S. Qiu, F. Ma, Y. Wo, S. Xu, Study on the biological effect of Tourmaline on the cell membrane of E. coli. Surf. Interface Anal. 43, 1069–1073 (2011)

    Article  CAS  Google Scholar 

  25. D. Wang, H. Xu, J. Ma, X. Lu, J. Qi, S. Song, Strong promoted catalytic ozonation of atrazine at low temperature using tourmaline as catalyst: Influencing factors, reaction mechanisms and pathways. Chem. Eng. J. 354, 113–125 (2018)

    Article  CAS  Google Scholar 

  26. J. Li, C. Wang, D. Wang, Z. Zhou, H. Sun, S. Zhai, A novel technology for remediation of PBDEs contaminated soils using tourmaline-catalyzed Fenton-like oxidation combined with P. chrysosporium. Chem. Eng. J. 296, 319–328 (2016)

    Article  CAS  Google Scholar 

  27. G. Li, D. Chen, W. Zhao, X. Zhang, Efficient adsorption behavior of phosphate on La-modified tourmaline. J. Environ. Chem. Eng. 3, 515–522 (2015)

    Article  CAS  Google Scholar 

  28. S.-M. Huang, C.-H. Weng, J.-H. Tzeng, Y.-Z. Huang, J. Anotai, L.-T. Yen, C.-J. Chang, Y.-T. Lin, Photocatalytic inactivation of Klebsiella pneumoniae by visible-light-responsive N/C-doped and N-tourmaline/palladium-C-codoped TiO2. Chem. Eng. J. 379, 122345 (2020)

    Article  CAS  Google Scholar 

  29. L.D. Tijing, M.T.G. Ruelo, A. Amarjargal, H.R. Pant, C.-H. Park, D.W. Kim, C.S. Kim, Antibacterial and superhydrophilic electrospun polyurethane nanocomposite fibers containing tourmaline nanoparticles. Chem. Eng. J. 197, 41–48 (2012)

    Article  CAS  Google Scholar 

  30. Y. Hu, X. Yang, The surface organic modification of tourmaline powder by span-60 and its composite. Appl. Surf. Sci. 258, 7540–7545 (2012)

    Article  CAS  Google Scholar 

  31. A. Tiraferri, N.Y. Yip, A.P. Straub, S.R.V. Castrillon, M. Elimelech, A method for the simultaneous determination of transport and structural parameters of forward osmosis membranes. J. Membr. Sci. 444, 523–538 (2013)

    Article  CAS  Google Scholar 

  32. J. Meng, W. Jin, J. Liang, Y. Ding, K. Gan, Y. Yuan, Effects of particle size on far infrared emission properties of tourmaline superfine powders. J. Nanosci. Nanotechnol. 10, 2083–2087 (2010)

    Article  CAS  Google Scholar 

  33. J.R. McCutcheon, M. Elimelech, Influence of concentrative and dilutive internal concentration polarization on flux behavior in forward osmosis. J. Membr. Sci. 284, 237–247 (2006)

    Article  CAS  Google Scholar 

  34. X. Liu, H.Y. Ng, Fabrication of layered silica–polysulfone mixed matrix substrate membrane for enhancing performance of thin-film composite forward osmosis membrane. J. Membr. Sci. 481, 148–163 (2015)

    Article  CAS  Google Scholar 

  35. T. García-Sánchez, A. Muscat, I. Leray, L.M. Mir, Pyroelectricity as a possible mechanism for cell membrane permeabilization. Bioelectrochemistry 119, 227–233 (2018)

    Article  Google Scholar 

  36. Z. Ji, Z. Jin, J. Liang, J. Wang, X. Yan, Influence of tourmaline on pH value of water. China Environ. Sci. 22(6), 5 (2002)

    CAS  Google Scholar 

  37. A. Subramani, E.M.V. Hoek, Direct observation of initial microbial deposition onto reverse osmosis and nanofiltration membranes. J. Membr. Sci. 319, 111–125 (2008)

    Article  CAS  Google Scholar 

  38. D.M. Seong, J. Chang, H, Antimicrobial ceramic hybrid films for keep-freshness packaging with fluorinated illite particles. J. Korean Ceram. Soc. 58(4), 430–436 (2021)

    Article  CAS  Google Scholar 

Download references

Acknowledgements

Project was supported by the National Science Foundation for Post-doctoral Scientist of China (Grant No. 2017M612091) and PhD research startup foundation of Anhui Jianzhu University (Grant No. 2020QDZ23).

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Authors and Affiliations

  1. Anhui Key Laboratory of Advanced Building Materials and Key Laboratory of Functional Molecule Design and Interface Process, Anhui Jianzhu University, 856 South Jinzhai Road, Hefei, 230022, Anhui, China

    Feng Zhang, Yaqin Wang & Wenfei Miao

  2. Shandong Tianwei Membrane Technology Co., LTD, Binhai Economic and Technological Development Area, Weifang, 262737, Shandong, China

    Yaqin Wang & Zhaoming Liu

  3. Department of Advanced Materials Science and Engineering, Hanseo University, Seosan, 31962, South Korea

    Won-Chun Oh

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  1. Feng Zhang
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  2. Yaqin Wang
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  3. Wenfei Miao
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Correspondence to Yaqin Wang or Won-Chun Oh.

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Zhang, F., Wang, Y., Miao, W. et al. Tourmaline as versatile additive to improve the performance of thin-film composite forward osmosis membrane. J. Korean Ceram. Soc. 59, 604–613 (2022). https://doi.org/10.1007/s43207-022-00191-3

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  • DOI: https://doi.org/10.1007/s43207-022-00191-3

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