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Efficiency of Jarosite in Pavement Quality Concrete

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Abstract

In recent years, zinc industry waste jarosite as a partial replacement of cement for high-strength concrete manufacturing has gained importance. Hence, the current study attempts to better understand the jarosite's efficiency in pavement quality concrete. Two different approaches based on compressive strength-to-water cementitious ratio relation and flexural strength-to-water cementitious ratio relation at different replacement levels of jarosite were considered to evaluate jarosite's efficiency in pavement quality concrete. It was observed that both the water-to-cementitious ratio and the dose of jarosite significantly affect the strength characteristics of the concrete. The results showed that the optimum quantity of water for the jarosite blended concrete could be achieved well by the difference in water-to-cementitious ratio (Δw) based efficiency factor concept considered in the study. Further, based on the achieved efficiency factors, it was found that the jarosite is more efficient in terms of flexural strength when compared to compressive strength.

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References

  1. Moura, W. A., Gonçalves, J. P., & Lima, M. B. L. (2007). Copper slag waste as a supplementary cementing material to concrete. Journal of Materials Science, 42, 2226–2230. https://doi.org/10.1007/s10853-006-0997-4

    Article  Google Scholar 

  2. Spence, R., & Mulligan, H. (1995). Sustainable development and the construction industry. Habitat International, 19, 279–292. https://doi.org/10.1016/0197-3975(94)00071-9

    Article  Google Scholar 

  3. Sakir, S., Raman, S. N., Safiuddin, M., Amrul Kaish, A. B. M., & Mutalib, A. A. (2020). Utilization of by-products and wastes as supplementary cementitious materials in structural mortar for sustainable construction. Sustain. https://doi.org/10.3390/su12093888

    Article  Google Scholar 

  4. Ray, S., Daudi, L., Yadav, H., & Ransinchung, G. D. (2020). Utilization of Jarosite waste for the development of sustainable concrete by reducing the cement content. Journal of Cleaner Production, 272, 122546. https://doi.org/10.1016/j.jclepro.2020.122546

    Article  Google Scholar 

  5. Bolden, J., Abu-Lebdeh, T., & Fini, E. (2013). Utilization of recycled and waste materials in various construction applications. American Journal of Environmental Science, 9, 14–24. https://doi.org/10.3844/ajessp.2013.14.24

    Article  Google Scholar 

  6. Johnson, O. A., Napiah, M., & Kamaruddin, I. (2014). Potential uses of waste sludge in construction industry: a review. Research Journal of Applied Sciences, Engineering and Technology, 8, 565–570. https://doi.org/10.19026/rjaset.8.1006

    Article  Google Scholar 

  7. Brunner, P. H., & Rechberger, H. (2015). Waste to energy—key element for sustainable waste management. Waste Management, 37, 3–12. https://doi.org/10.1016/j.wasman.2014.02.003

    Article  Google Scholar 

  8. website Hindustan Zinc Limited India, Hindustan Zinc Limited India, (2021) 6. https://www.hzlindia.com/ask_for_zinc/the-8th-known-metal-to-the-mankind-and-4th-most-widely-consumed-metal-in-the-world-zinc/ (accessed Mar. 3, 2021).

  9. Asokan, P., Saxena, M., & Asolekar, S. R. (2006). Jarosite characteristics and its utilisation potentials. Science of the Total Environment, 359, 232–243. https://doi.org/10.1016/j.scitotenv.2005.04.024

    Article  Google Scholar 

  10. N.D. CRRI, Annual Report 2009–10, 2010.

  11. A.K. Sinha, Feasibility Study of Jarofix Waste Material for Road Construction, (2011).

  12. González-Ibarra, A. A., Nava-Alonso, F., Fuentes-Aceituno, J. C., & Uribe-Salas, A. (2016). Hydrothermal decomposition of industrial jarosite in alkaline media: the rate determining step of the process kinetics. Journal of Mining and Metallurgy, Section B: Metallurgy, 52, 135–142. https://doi.org/10.2298/JMMB150430016G

    Article  Google Scholar 

  13. A. Shukla, Best Practices in Utilization of Alternate Raw Materials : Utilization of wastes Jarosite and Lead Zinc Slag, Limited, Hindustan Zinc. (2017) 1–23.

  14. Arslan, C., & Arslan, F. (2003). Thermochemical review of jarosite and goethite stability regions at 25 and 95°C, Turkish. Journal Engineering Environmental Sciences, 27, 45–52. https://doi.org/10.3906/sag-1202-77

    Article  Google Scholar 

  15. Chen, T. T., & Dutrizac, J. E. (2000). A mineralogical study of jarofix products for the stabilization of jarosite residues for disposal. Lead-Zinc, 2013, 917–934. https://doi.org/10.1002/9781118805558.ch63

    Article  Google Scholar 

  16. Seyer, S., Chen, T. T., & Dutrizac, J. E. (2001). Jarofix: addressing iron disposal in the zinc industry. Journal of the Minerals, 53, 32–35. https://doi.org/10.1007/s11837-001-0010-2

    Article  Google Scholar 

  17. Pappu, A., Saxena, M., & Asolekar, S. R. (2011). Waste to wealth -cross sector waste recycling opportunity and challenges. Indiaenvironmentportal. Org. In., 2, 13–23.

    Google Scholar 

  18. Sharma, P. (2016). Feasibility study of industrial jarosite waste as vital material for construction: positive and negative aspects. Malaysian Journal of Civil Engineering, 28, 139–154. https://doi.org/10.11113/mjce.v28.160

    Article  Google Scholar 

  19. Sinha, A. K., Havanagi, V. G., Arora, V. K., Ranjan, A., & Mathur, S. (2012). Recycling Jarofix waste as a construction material for embankment and sub grade. Journal of Solid Waste Technology and Management, 38, 169–181. https://doi.org/10.5276/JSWTM.2012.169

    Article  Google Scholar 

  20. S.T. Benavides, Mineralogical and Chemical Characteristics of Some Soils, (1973) 216. http://pdf.usaid.gov/pdf_docs/pnaaa957.pdf.

  21. Arora, V., Sachdeva, S., & Aggarwal, P. (2015). Effect of use of jarosite on workability and early age strength of concrete. International Journal of Computing Science and Mathematics, 4, 136–144.

    Google Scholar 

  22. Rathore, N., Patilb, M.P., & Dohare, D. (2014). Utilization of jarosite generated from lead-zinc smelter for various applications: A review. International Journal of Civil Engineering and Technology, 5(11), 192–200.

    Google Scholar 

  23. Kerolli-Mustafa, M., Ćurković, L., Fajković, H., & Rončević, S. (2015). Ecological risk assessment of jarosite waste disposal. Croatica Chemica Acta, 88, 189–196. https://doi.org/10.5562/cca2554

    Article  Google Scholar 

  24. Sinha, A. K., Havanagi, V. G., & Shahu, J. T. (2021). Stabilised jarofix waste material for road construction. International Journal of Pavement Engineering, 22, 882–893. https://doi.org/10.1080/10298436.2019.1652299

    Article  Google Scholar 

  25. Investigations, M., & Csic, C. (1999). New constructionm a TERI a LS from Spanish. Jarosite, 12, 1399–1402.

    Google Scholar 

  26. Mymrin, V. A., Ponte, H. A., & Impinnisi, P. R. (2005). Potential application of acid jarosite wastes as the main component of construction materials. Construction and Building Materials, 19, 141–146. https://doi.org/10.1016/j.conbuildmat.2004.05.009

    Article  Google Scholar 

  27. Katsioti, M., Boura, P., Agatzini, S., Tsakiridis, P. E., & Oustadakis, P. (2005). Use of jarosite/alunite precipitate as a substitute for gypsum in Portland cement. Cement and Concrete Composites, 27, 3–9. https://doi.org/10.1016/j.cemconcomp.2003.10.002

    Article  Google Scholar 

  28. Asokan, P., Saxena, M., & Asolekar, S. R. (2006). Hazardous jarosite use in developing non-hazardous product for engineering application. Journal of Hazardous Materials, 137, 1589–1599. https://doi.org/10.1016/j.jhazmat.2006.04.054

    Article  Google Scholar 

  29. Asokan, P., Saxena, M., & Asolekar, S. R. (2010). Recycling hazardous jarosite waste using coal combustion residues. Materials Characterization, 61, 1342–1355. https://doi.org/10.1016/j.matchar.2010.09.005

    Article  Google Scholar 

  30. Patrick Mubiayi, M., Elizabeth Makhatha, M., & Titilayo Akinlabi, E. (2018). Characterization, leachate characteristics and compressive strength of Jarosite/clay/fly ash bricks. Materials Today: Proceedings, 5, 17802–17811. https://doi.org/10.1016/j.matpr.2018.06.105

    Article  Google Scholar 

  31. M.P. Mubiayi, O.S.I. Fayomi, Characteristics and utilization of Jarosite and fly ash wastesin the construction industry: an overview, (n.d.) 1–8.

  32. Gupta, C., & Prasad, A. (2018). Strength and durability of lime-treated jarosite waste exposed to freeze and thaw. Journal of Cold Regions Engineering, 32, 04017025. https://doi.org/10.1061/(asce)cr.1943-5495.0000154

    Article  MathSciNet  Google Scholar 

  33. Mehra, P., Thomas, B. S., Kumar, S., & Gupta, R. C. (2016). Jarosite added concrete along with fly ash: properties and characteristics in fresh state. Perspectives on Science, 8, 69–71. https://doi.org/10.1016/j.pisc.2016.03.012

    Article  Google Scholar 

  34. Mehra, P., Gupta, R. C., & Thomas, B. S. (2016). Assessment of durability characteristics of cement concrete containing jarosite. Journal of Cleaner Production, 119, 59–65. https://doi.org/10.1016/j.jclepro.2016.01.055

    Article  Google Scholar 

  35. Debbarma, S., Ransinchung, G., & Singh, S. (2020). Zinc waste as a substitute for portland cement in roller-compacted concrete pavement mixes containing RAP aggregates. Journal of Materials in Civil Engineering, 32, 04020207. https://doi.org/10.1061/(asce)mt.1943-5533.0003278

    Article  Google Scholar 

  36. Gupta, T., & Sachdeva, S. N. (2019). Investigations on jarosite mixed cement concrete pavements. Arabian Journal for Science and Engineering, 44, 8787–8797. https://doi.org/10.1007/s13369-019-03801-1

    Article  Google Scholar 

  37. Gupta, T., & Sachdeva, S. N. (2019). Prediction of compressive and flexural strengths of jarosite mixed cement concrete pavements using artificial neural networks. Road Materials and Pavement Design. https://doi.org/10.1080/14680629.2019.1702583

    Article  Google Scholar 

  38. Gupta, T., & Sachdeva, S. N. (2020). Study of mechanical, micro-structural and environmental properties of concrete containing zinc industry waste for pavements. Construction and Building Materials, 245, 118331. https://doi.org/10.1016/j.conbuildmat.2020.118331

    Article  Google Scholar 

  39. Saini, S. K., Ransinchung, G. D., Kumar, P., & Ray, S. (2022). Investigation of jarosite-cement blends for hydration process and mechanical behavior in PQC mixes. Innovative Infrastructure Solutions. https://doi.org/10.1007/s41062-021-00707-6

    Article  Google Scholar 

  40. IS 383, “Indian Standard Specification for Coarse and Fine Aggregates From Natural Sources for Concrete (Second Revision),” Bureau of Indian Standards, India, 2002.

  41. IRC 44, “Guidelines for Cement Concrete Mix Design for Pavements (Third Revision),” Indian Roads Congress, India, 2017.

  42. IS 8112, “Ordinary Portland Cement, 43 Grade — Specification (Second Revision),” Bureau of Indian Standards, India, 2013.

  43. Indian Roads Congress, IRC-15: Standard Specifications and Code of Practice for Construction of Concrete Roads, (2002).

  44. IS 516, “Indian Standard Methods of Tests for Strength of Concrete,” Bureau of Indian Standards, India, 2004.

  45. ASTM C618, “Standard Specification for Coal Fly Ash and Raw or Calcined Natural Pozzolan for Use in Concrete.,” American society for testing and materials, United States, 2019. https://doi.org/10.1520/C0618.

  46. Paris, J. M., Roessler, J. G., Ferraro, C. C., Deford, H. D., & Townsend, T. G. (2016). A review of waste products utilized as supplements to Portland cement in concrete. Journal of Cleaner Production, 121, 1–18. https://doi.org/10.1016/j.jclepro.2016.02.013

    Article  Google Scholar 

  47. Nochaiya, T., Wongkeo, W., & Chaipanich, A. (2010). Utilization of fly ash with silica fume and properties of Portland cement-fly ash-silica fume concrete. Fuel, 89, 768–774. https://doi.org/10.1016/j.fuel.2009.10.003

    Article  Google Scholar 

  48. Ganesh Babu, K., & Surya Prakash, P. V. (1995). Efficiency of silica fume in concrete. Cement and Concrete Research, 25, 1273–1283. https://doi.org/10.1016/0008-8846(95)00120-2

    Article  Google Scholar 

  49. I.R.C. 58:2015, Guidelines for the design of plain jointed rigid pavements for highways (Fourth Revision), Indian Roads Congress, India, 2015.

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Acknowledgements

Authors sincerely acknowledge their sincere thanks to Vishal Kumar Singh, Debashish Sahoo, and Nidhi Srivastav from Zinc Smelter Debari Plant, Udaipur, Rajasthan, India, for helping us out while procuring jarosite waste and taking us to the site plant to understand the generation process. The authors also sincerely acknowledge their sincere thanks to the quality improvement program of the All India Council for Technical Education (AICTE), Government of India, for providing the scholarship to one of the authors for pursuing this research at the Indian Institute of Technology Roorkee.

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SKS: conceptualization, methodology, investigation, and writing original draft. GDRRN, PK: supervision.

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Correspondence to G. D. Ransinchung.

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Saini, S.K., Ransinchung, G.D. & Kumar, P. Efficiency of Jarosite in Pavement Quality Concrete. Int. J. Pavement Res. Technol. 16, 1364–1374 (2023). https://doi.org/10.1007/s42947-022-00202-w

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