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Preparation of a Novel Clay/Dye Composite and its Application in Contaminant Detection

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Clays and Clay Minerals

Abstract

Although fluorescence detection is a sensitive method in the field of pollutant analysis, its application is restricted due to the fluorescence shown by organic material being quenched after aggregation and to low photo-thermal stability. To address these issues, a novel mineral/dye composite material was prepared by intercalating a fluorescence molecule, Rhodamine (R6G), into the interlayer space of montmorillonite (Mnt). This composite material greatly enhanced the light stability and efficiency of R6G. After enhancement, the fluorescence lifetime of R6G-Mnt was eight times longer than originally and the luminous intensity was 20 times greater. Chromium at the mmol/L (mM) level can be detected by the naked eye when its enhanced fluorescent property is fabricated into a solid test paper, even though a fluorescence spectrophotometer should be used for detection at the 0.01 μmol/L level in the sensing range 0.01 μmol/L to 100 mmol/L. These results can provide new avenues as well as a theoretical and experimental foundation for the development of novel supramolecular luminescent material.

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Acknowledgments

This research was funded jointly funded by the China Postdoctoral Science Foundation funded project (2018M631818) and the Doctoral Startup Foundation of Liaoning (20170520315).

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Authors and Affiliations

  1. School of Materials Science and Engineering, Shenyang Jianzhu University, Shenyang, 110168, China

    Limei Wu, Haoyu Zhong & Yuwei Pan

  2. The Beijing Municipal Key Laboratory of New Energy Materials and Technologies, School of Materials Sciences and Engineering, University of Science and Technology Beijing, Beijing, 100083, China

    Xuyuan Bao

  3. Beijing Key Laboratory of Materials Utilization of Nonmetallic Minerals and Solid Wastes, National Laboratory of Mineral Materials, School of Materials Science and Technology, China University of Geosciences, Beijing, 100083, China

    Guocheng Lv & Libing Liao

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  1. Limei Wu
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  2. Xuyuan Bao
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  3. Haoyu Zhong
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  4. Yuwei Pan
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  5. Guocheng Lv
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Correspondence to Guocheng Lv.

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Wu, L., Bao, X., Zhong, H. et al. Preparation of a Novel Clay/Dye Composite and its Application in Contaminant Detection. Clays Clay Miner. 67, 244–251 (2019). https://doi.org/10.1007/s42860-019-00022-3

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