Abstract
Wear and high–low temperature resistance composites with enhanced mechanical and thermal properties were preparation by carbon fiber (CF) reinforced silicone rubber (MVQ)/fluorine rubber (FKM), the coupling agent was used as a compatibilizer. The effect of coupling agent type and content on mechanical properties of CF/MVQ/FKM composites was investigated, the interaction between coupling agent and composites was studied by infrared spectrum and X-ray photo electron spectroscopy, the surface morphology and phase composition of composites were observed by atomic force microscope and infrared imaging technology, the thermal properties of composites were studied by dynamic thermomechanical analysis and thermogravimetric analysis. The results showed that the coupling agents crosslinked with CF and matrix, the best coupling agent was (3-mercaptopropyl) trimethoxysilane (KH590), and the content was 2 phr (parts per hundred rubber), the wear of KH590/CF/MVQ/FKM composites decreased from 0.0314 to 0.0283 cm3 km−1, the Tg reduced from – 20 to − 34 °C, the initial decomposition temperature increased from 231 to 304 °C compared with FKM.
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References
Zhao XY, Wang SF (2018) Thermal, mechanical properties and morphology of epoxy resins modified with light pyrolysis natural rubber. Adv Polym Tech 37:2541–2551. https://doi.org/10.1002/adv.21929
Yangthong H, Pichaiyut S, Jumrat S, Wisunthorn S, Nakason C (2018) Novel natural rubber composites with geopolymer filler. Adv Polym Tech 37:2651–2662. https://doi.org/10.1002/adv.21940
Moghaddamzadeh S, Rodrigue D (2018) The effect of polyester recycled tire fibers mixed with ground tire rubber on polyethylene composites. Part I: morphological analysis. Prog Rubber Plast Re 34:200–220. https://doi.org/10.1177/1477760618798267
Gunwant D, Sah PL, Zaidi MGH (2018) Morphology and micromechanics of liquid rubber toughened epoxies. E-Polymers 18:511–527. https://doi.org/10.1515/epoly-2018-0141
Mishra RM, Rai JSP (2018) Preparation and properties of nanocomposites based on polyetherimide (PEI)/silicone rubber reinforced with halloysite nanotubes. Indian J Pure Ap Phy 56:787–791
Chen YK, Gong Z, Cao LM, Wang YH, Yuan DS, Xu CH (2018) Novel fluorosilicone thermoplastic vulcanizates prepared via core-shell dynamic vulcanization: effect of fluororubber/silicone rubber ratio on morphology, crystallization behavior, and mechanical properties. Polym Adv Technol 29:1456–1468. https://doi.org/10.1002/pat.4257
Wang CY, Wen L, Ming WW, An QL, Chen M (2018) Experimental study on effects of fiber cutting angle in milling of high-strength unidirectional carbon fiber-reinforced polymer laminates. P I Mech Eng B-J Eng 232:1813–1824. https://doi.org/10.1177/0954405416679868
Ye CS, Zhang RB, An ZM, Wang BL (2018) A machinable carbon aerogel composite with a low thermal conductivity and enhanced mechanical properties. Adv Appl Ceram 117:468–475. https://doi.org/10.1080/17436753.2018.1495897
Wu WL, Wang J (2018) Effect of KH550 on the preparation and compatibility of carbon fibers reinforced silicone rubber composites. Silicon 10:1903–1910. https://doi.org/10.1007/s12633-017-9700-4
Choi WK, Park GY, Kim BS, Se MK (2018) Effect of silane coupling agent on the creep behavior and mechanical properties of carbon fibers/acrylonitrile butadiene rubber composites. J Nanosci Nanotechnol 18:6220–6227. https://doi.org/10.1166/jnn.2018.15627
Bulatovic VO, Mihaljevic A, Bajsic EG (2018) Mechanical and interfacial properties of compatibilized polyurethane blends. Polym Eng Sci 58:1911–1922. https://doi.org/10.1002/pen.24800
George S, Sushama CM, Nair AB (2017) Efficiencies of dipolymer rubber blends (EPDM\FKM) using common weight data envelopment analysis. Mater Res-Ibero-Am J 20:1722–1728. https://doi.org/10.1590/1980-5373-MR-2016-1127
Moezzi MD, Karrabi M, Jahani Y (2017) Thermal tensile, and dynamic mechanical properties of PVDF/FKM blends in different curing systems. Polym-Korea 41:250–259. https://doi.org/10.7317/pk.2017.41.2.250
Wu L, Qu P, Zhou R, Wang B, Liao S (2017) Green synthesis of reduced graphene oxide and its reinforcing effect on natural rubber composites. High Perform Polym 27:486–496. https://doi.org/10.1177/0954008314555530
Yang Y, Zhao XJ, Peng GR, Liu WP (2018) Effects of nitrile rubber and multi-walled carbon nanotubes on damage recovery and physical mechanical properties of carbon fiber–reinforced epoxy composites. High Perform Polym 30:856–863. https://doi.org/10.1177/0954008317733527
Tavakkoli H, Meibod MP, Frounchi M, Dadbin S (2011) Study and production of silicone rubber and polyethylene alloy. J Compos Mater 24:669–677. https://doi.org/10.1177/0892705711401558
Wang CC, Zhang YF, Wang ZB (2017) Mechanical properties, morphology, and mullins effect of thermoplastic vulcanizates based on ethylene-vinyl acetatecopolymer/ethylene -vinyl acetate rubber. J Compos Mater 30:827–839. https://doi.org/10.1177/0892705715614062
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This work was financially supported by Fundamental Research Funds in Heilongjiang Provincial Universities, China (No: YSTSXK201864).
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Wu, W., Li, X. Wear and thermal properties of carbon fiber reinforced silicone rubber/fluorine rubber composites. J Rubber Res 22, 119–126 (2019). https://doi.org/10.1007/s42464-019-00020-z
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DOI: https://doi.org/10.1007/s42464-019-00020-z