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Interceram - International Ceramic Review

, Volume 68, Issue 3, pp 40–49 | Cite as

Porous Beads of in-situ Calcium Hexaluminate Prepared by Extrusion-Dripping

  • R. Salomão
  • A.J.B. Poiani
  • L.M.M. Costa
Research and Development
  • 21 Downloads

Abstract: Structures comprised of mixtures of corindon (α-Al2O3) and calcium hexaluminate (CaAl12O19 or CA6) show high refractoriness and chemical resistance. This article addresses the in situ formation of porous alumina-CA6 beads (approximately 2-3 mm) prepared by an extrusion-dripping process with sodium alginate (SA) as a coagulation agent. The best conditions for a simultaneous dispersion of aqueous mixtures of the precursor raw materials, fine alumina, and calcium carbonate (β-CaCO3 or calcite), in an SA solution were investigated by Zeta potential and apparent viscosity measurements and turbidity tests. Extrusion-dripped beads of different compositions were consolidated by the ionotropic gelation of SA in a Ca2+ solution. A net of thin coagulated-SA filaments restraining solid particles was registered by scanning electron microscopy. Different pore generation mechanisms were observed during heating up to 1500 °C. Variations in the initial Al2O3-CaCO3 ratio yielded a wide range of compositions, microstructures, and physical properties (total porosity, crystalline phase content, and pore size distribution).

Copyright information

© Springer Fachmedien Wiesbaden GmbH 2019

Authors and Affiliations

  • R. Salomão
    • 1
  • A.J.B. Poiani
    • 1
  • L.M.M. Costa
    • 1
  1. 1.Materials Engineering Department, São Carlos School of Engineering, University of São PauloSão PauloBrazil

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