Abstract
Geopolymer concrete was prepared using stone chips of various sizes, sand and fly ash, without using any cement. Na2SiO3 and NaOH solutions with three different ratios were used as the alkaline activator for the geopolymer system, and the compositions were studied for density, strength and phase evaluation after ageing and heat treatment at different temperatures up to 90 °C. Sodium aluminium silicate hydrate phase was found to be formed in the compositions as the reaction product of geopolymerization process and is responsible for the strength and density development. The reduction in the hydrated phase content at higher temperatures results in the reduction of density and strength values.
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Pacheco-Torgal, F., Castro-Gomes, J., Jalali, S.: Alkali-activated binders: A review? Part 1. Historical background, terminology, reaction mechanisms and hydration products. Constr. and Build. Mater. 22 (2008) 1305–1314
Roy, D.M.: Alkali-activated cements: Opportunities and challenges. Cem. Concr. Res. 29 (1999) 249–254
Palomo, A., Grutzeck, M.W., Blanco, M.T.: Alkali activated fly ashes: A cement for the future. Cem. Concr. Res. 29 (1999) 1323–1329
Duxon, P., Fernández-Jiménez, A., Provis, J.L., Luckey, G.C., Palomo, A., van Deventer, J.S.J.: Geopolymer technology: The current state of the art. J. Mater. Sci. 42 (2007) 2917–2933
Nataraja, M.C., Rajamane, N.P., Lakshmanan, N.: Geopolymer concrete — A new eco-friendly material of construction. J. Eng. Technol. Res. 3 (2011) [1] 1–4
Hardjito, D.: Studies on flyash based geopolymer concrete. Ph.D. Thesis, Dept. of Civil Engineering, Curtin University of Technology, Perth, Australia (2005)
Rangan, B.V.: lyash based geopolymer concrete. Curtin University of Technology, Perth, Australia Research Report GC 4 Engineering Faculty (2008)
Potharaju, M., Ramujee, K.: Development of mix design for low calcium based geopolymer concrete in low, medium and higher grades Indian Scenario. J. Civil Eng. & Technol. 1 (2013) [1] 15–25
Kurhade, S.D., Kawade, U.R., Salunkhe, P.A.: Flyash based geopolymer concrete. Int. J. Innovative Res. in Sci. Eng. and Technol. 3 (2014) 4
Fernández-Jiménez, A., Palomo, A.: Composition and microstructure of alkali activated fly ash binder: Effect of the activator. Cem. Concr. Res. 35 (2005) 1984–1992
Rangan B.V.: Fly ash-based geopolymer concrete. Res. Report GC 4, Faculty of Engineering, Curtin University of Technology, Perth, Australia (2008)
Rattanasak, U., Chindaprasirt, P.: Influence of NaOH solution on the synthesis of fly ash geopolymer. Min. Eng. 22 (2009) 1073–1078
Duchesne, J., Duong, L., Bostrom, T., Frost, R.: Microstructure study of early in situ reaction of fly ash geopolymer observed by environmental scanning electron microscopy (ESEM). Waste Biomass Valor. 1 (2010) 367–377
Palomo, A., Grutzeck, M.W., Blanco, M.T.: Alkali-activated fly ashes: A cement for the future. Cem. Concr. Res. 29 (1999) 1323–1329
Xu, H., van Deventer, J.S.J.: Ab initio calculations on the five-membered aluminosilicate framework rings model: Implications for dissolution in alkaline solutions. Comp. and Chem. 24 (2000) 391–404
Tempest, B., Sanusi, O., Gergely, J., Ogunro, V., Weggel, D.: Compressive strength and embodied energy optimization of fly ash based geopolymer concrete. World of Coal Ash Conf., Lexington, KY, USA. Ed., (2009) 1–17
Chindaprasirt, P., Chareerat, T., Sirivivatnanon, V.: Workability and strength of coarse high calcium fly ash geopolymer. Cem. Concr. Compos. 29 (2007) 224–229
Fernández-Jiménez, A., Palomo, A.: Characterization of fly ashes. Potential reactivity as alkaline cements. Fuel 82 (2003) 2259–2265
Temuujin, J., van Riessen, A.: Effect of fly ash preliminary calcination on the properties of geopolymer. J. Hazard. Mater. 164 (2009) 634–639
Jones, M.R., McCarthy, A., Booth, A.P.P.G.: Characteristics of the ultrafine component of fly ash. Fuel 85 (2006) 2250–2259
Ward, C.R., French, D.: Determination of glass content and estimation of glass composition in fly ash using quantitative X-ray diffractometry. Fuel 85 (2006) 2268–2277
Kovalchuk, G Fernández-Jiménez, A., Palomo, A.: Alkali-activated fly ash: Effect of thermal curing conditions on mechanical and microstructural development 3—Part II. Fuel 86 (2007) 315–322
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Sarkar, R., Routray, S. Fly Ash Containing Alkali Activated Geopolymer Concrete: Effect of the Na2SiO3:NaOH Ratio and Temperature. Interceram. - Int. Ceram. Rev. 67, 24–29 (2018). https://doi.org/10.1007/s42411-018-0014-3
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DOI: https://doi.org/10.1007/s42411-018-0014-3