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Experimental Studies of Bimetallic Zinc-Cadmium Admixed L-Threonine Single Crystal

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Abstract

A bimetallic compound Zn2+ [Cd (C2H3O2) (C4H8NO3) (H2O)], fabrication and its analysis is the major focus of this article. The bimetallic single crystal namely Zinc L-threonine Cadmium Acetate, has been crystallized by the simple method of slow evaporation technique. X-ray diffraction technique identified that, the prepared bimetallic single crystal with asymmetric units of a polymeric structure belongs to the class of monoclinic crystal system with a = 5.87 Å, b = 8.87 Å, c = 10.81 Å, α = γ = 90°, β = 91.84°, space group P21 and. volume 563Å3. The optical nature of the crystal specifically its transparency has sufficiently increased nearly cent percentage due the presence of organic ligand’s present in the L-threonine amino acids. The impacts of zinc on the thermal stability and different stages of chemical degradations are studied with the aid of Thermo gravimetric and differential thermal analysis. Thermal stability increases nearly 5% with the addition of zinc concentration. The dielectric studies support the finding that the zinc doping increases dielectric constant by five times compared to the L-threonine cadmium acetate crystal. Second harmonic generations efficiency increases almost 20% in each 0.2 mol% of the zinc addition. Magnetic properties are also elucidated and the effect of zinc has been analysed and the materials are identified as a paramagnetic nature due to the partially filled electron in the d-shell of Zn2+ion.

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Data Availability

The datasets generated during and/or analysed during the current study are available from the corresponding author on reasonable request.

References

  1. G.D. Batema, C.A. van Walree, G.P.M. van Klink, C. de Mello Doneg, A. Meijerink, J. Perez-Moreno, K. Clays, G. van Koten, Octupolar organometallic Pt(II) NCN-pincer complexes; synthesis, electronic, photophysical, and NLO properties. J. Organomet. Chem. 867, 246–252 (2018)

    Article  CAS  Google Scholar 

  2. C.P. Raptopoulou, Metal organic frameworks synthetic methods and potential applications. Materials (Basel) 14, 310 (2021)

    Article  CAS  PubMed  Google Scholar 

  3. S.K. Tilley, R.C. Fry, Systems biology in toxicology and environmental health (Elsevier, Academic Press, 2015)

    Google Scholar 

  4. A. Roy Chowdhury, R. Datta and D. Sarkar, Heavy Metal Pollution and Remediation, ed. by B. Torok, T. Dransfield (Elsevier, Academic Press, 2018)

  5. E.W.P. Wong, C.Y. Cheng, Comprehensive toxicology (Elsevier, USA, 2010)

    Google Scholar 

  6. Pathaik and Pradyot, Handbook of inorganic chemical compounds (Mcgraw Hill Professional, New York, 2003)

    Google Scholar 

  7. H.C. You, Transistor characteristics of zinc oxide active layers at various zinc acetate dihydrate solution concentrations of zinc oxide thin-film. J. Appl. Res. Technol. 13, 291–296 (2015)

    Article  Google Scholar 

  8. R.L. Madan, Organic chemistry (Tata McGrew Hill Education private Limited, New Delhi, 2013)

    Google Scholar 

  9. M. Abila Jeba Queen, K.C. Bright, S. Mary Delphine, catena-Poly [[[(acetato-κ2O, O′)aquacadmium(II)]-μ-L-threoninato-κ3N, O:O′]monohydrate]. IUCr Data 3, x181770 (2018). https://doi.org/10.1107/S2414314618017704

    Article  CAS  Google Scholar 

  10. M. Abila Jeba Queen, K.C. Bright, S. Mary Delphine, P. Aji Udhaya, Spectroscopic investigation of supramolecular organometallic compound L-threonine cadmium acetate monohydrate. Spectrochim. Acta A Mol. Biomol. Spectrosc. 228, 117802 (2019). https://doi.org/10.1016/j.saa.2019.117802

    Article  CAS  Google Scholar 

  11. M.A.J. Queen, K.C. Bright, S.M. Delphine, P.A. Udhaya, Enhanced linear and non-linear optical activity of lead onto L threonine cadmium acetate crystal. J. Mater. Sci. Mater. Electron. 32(10), 13261–13268 (2021). https://doi.org/10.1007/s10854-021-05881-y

    Article  CAS  Google Scholar 

  12. M.A.J. Queen, K.C. Bright, P.A. Udhaya, Investigation on the effect of Potassium on the structural, optical and thermal properties of the L threonine cadmium acetate: elucidation of organo cadmium compound for dielectric filters. J. Mater. Sci. Mater. Electron. 34, 181 (2023). https://doi.org/10.1007/s10854-022-09620-9

    Article  CAS  Google Scholar 

  13. T. Vu, O.Y. Khyzhun, A.A. Lavrentyev, B.V. Gabrelian, K.F. Kalmykova, L.I. Isaenko, A.A. Goloshumova, P.G. Krinitsyn, G.L. Myronchuk, M. Piasecki, Electronic band structure and optical properties of Li2In2GeSe6 crystal. Mater. Today Commun. 35, 105798 (2023). https://doi.org/10.1016/j.mtcomm.2023.105798

    Article  CAS  Google Scholar 

  14. E.P. Wagner, Investigating bandgap energies, materials, and design of light emitting diodes. J. Chem. Educ. 93, 1289–1298 (2016). https://doi.org/10.1021/acs.jchemed.6b00165

    Article  CAS  Google Scholar 

  15. N. Mir, M. Salavati-Niasari, Preparation of TiO2 nanoparticles by using tripodal tetraamine ligands as complexing agent via two-step sol–gel method and their application in dye-sensitized solar cells. Mater. Res. Bull. 48(4), 1660–1667 (2013). https://doi.org/10.1016/j.materresbull.2013.01.006

    Article  CAS  Google Scholar 

  16. M.H. Khorasanizadeh, R. Monsef, M. Salavati-Niasari, H.S. Majdi, W.K. Al-Azzawi, F.S. Hashim, Schiff-base ligand assisted synthesis of DyVO4/ AgBr nanocomposites, characterization, and investigation of photocatalytic activity over organic dye contaminants. Arab. J. Chem. 16(8), 105020 (2023)

    Article  Google Scholar 

  17. A. Panahi, R. Monsef, E.A. Dawi, A.S. Hussein, M. Salavati-Niasari, Green auto-combustion synthesis and characterization of TmVO4 nanostructures in the presence carbohydrate sugars and their application as visible-light photocatalyst. Sol. Energy 258, 372–382 (2023). https://doi.org/10.1016/j.solener.2023.04.030

    Article  CAS  Google Scholar 

  18. S. Zinatloo-Ajabshir, M. Baladi, M. Salavati-Niasari, Enhanced visible-light-driven photocatalytic performance for degradation of organic contaminants using PbWO4 nanostructure fabricated by a new, simple and green sonochemical approach. Ultrason. Sonochem. 72, 105420 (2021)

    Article  CAS  PubMed  Google Scholar 

  19. M.S. Javed, A.J. Khan, A. Ahmad, S.H. Siyal, S. Akram, G. Zhao, A.A.A. Bahajjaj, M. Ouladsmane, M. Alfakeer, Design and fabrication of bimetallic oxide nanonest-like structure/carbon cloth composite electrode for supercapacitors. Ceram. Int. 47(21), 30747–30755 (2021). https://doi.org/10.1016/j.ceramint.2021.07.254

    Article  CAS  Google Scholar 

  20. T.R. Kumar, M.A.J. Queen, K.C. Bright, R. Ilangovan, K. Sankaranarayanan, Investigation on the physico-chemical properties of Sodium L-alanine cadmium chloride crystal and assessment for their non linear optical response. Eur. Chem. Bull. 12(3), 1633–1649 (2023)

    CAS  Google Scholar 

  21. SK Kurtz, TT Perry, A Powder technique for the evaluation of nonlinear optical materials. J. Appl. Phys. 39, 3798–38l3 (1968)

  22. J.D. Lee, Concise of organic chemistry (Wellwish Science, Germany, 2004)

    Google Scholar 

  23. A.K. Panigrahi, T. Ghosh, S.R.K. Vanjari, S.G. Singh, Oxidation resistive, CMOS compatible copper-based alloy ultrathin films as a superior passivation mechanism for achieving 150 °C Cu–Cu wafer on wafer thermocompression bonding. IEEE Trans. Electron Devices 64, 1239–1245 (2017)

    Article  Google Scholar 

  24. T.R. Kumar, M.A.J. Queen, K.C. Bright, R. Ilangovan, K. Sankaranarayanan, Comparative study on structural, mechanical, optical and Dielectric properties of L alanine cadmium chloride and manganese L alanine cadmium chloride crystal. Chem. Afr. 6, 3229–3236 (2023). https://doi.org/10.1007/s42250-023-00697-1

    Article  CAS  Google Scholar 

  25. P. Nisha Santha Kumari, S. Kalainathan, G. Bhagavannarayana, Study of crystalline perfection and thermal analysis of zinc cadmium thiocyanate single crystals grown in silica gel. Cryst. Res. Technol. 43, 276–281 (2008)

    Article  Google Scholar 

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Authors and Affiliations

  1. Department of Physics, Holy Cross College (Autonomous), Nagercoil, Tamil Nadu, 629004, India

    M. Abila Jeba Queen & P. Aji Udhaya

  2. Department of Physics, Mar Ivanio’s College (Autonomous), Thiruvananthapuram, Kerala, 695015, India

    K. C. Bright

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All the authors contributed equally to the study, conception, design and all the authors commented on the previous versions of the manuscript. All the authors read and approved the final manuscript.

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Correspondence to M. Abila Jeba Queen.

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Queen, M.A.J., Bright, K.C. & Udhaya, P.A. Experimental Studies of Bimetallic Zinc-Cadmium Admixed L-Threonine Single Crystal. Trans. Electr. Electron. Mater. (2024). https://doi.org/10.1007/s42341-024-00525-4

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