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Investigation on Photocatalytic Activity of Copper (II) Oxide Nanoparticles for the Bio Fabrication and Industrial Applications

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Abstract

Photocatalysis uses photonic energy to start the chemical reaction. Some of the most frequent uses of photocatalytic oxidation reactions are pollution reduction, self-cleaning, and self-disinfecting products. Therefore, the present study aimed to synthesize the copper (II) oxide nanoparticles utilizing citric acid with co-precipitation techniques. The physicochemical properties of synthesized copper(II) oxide nanoparticles were characterized by UV–Vis spec, SEM, HRTEM, XRD, and FTIR analysis. According to XRD technique and direct HRTEM measurements, the average particle size of copper (II) oxide nanoparticles was around 30–50 nm. The agglomerated spheres were depicted in surface morphological analyses using SEM and TEM. The presence of copper (II) oxide stretching mode was determined by strong peaks in the FTIR spectrum, and the absorbance peak of the UV–Vis spectrum revealed bandgap energy of 1.75 eV. In addition, the antibacterial activity against S. aureus and E. coli is also enhanced and inhibit growth of these bacteria. Also, the photocatalytic degradation of MB dye is completely achieved in 100 min. Based on this result, it can be indicated that copper (II) oxide nanoparticle is an effective photocatalytic materials and can be use in wastewater treatment in future prospective.

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References

  1. Ahmed SF, Mofijur M, Nuzhat S, Chowdhury AT, Rafa N, Uddin MA, Show PL (2021) Recent developments in physical, biological, chemical, and hybrid treatment techniques for removing emerging contaminants from wastewater. J Hazard Mater 416:125912

    Article  CAS  PubMed  Google Scholar 

  2. Akintelu SA, Folorunso AS, Folorunso FA, Oyebamiji AK (2020) Green synthesis of copper oxide nanoparticles for biomedical application and environmental remediation. Heliyon 6(7):e04508

    Article  PubMed  PubMed Central  Google Scholar 

  3. Ali EM, Rasool KH, Abad WK, Abd AN (2021) Green synthesis, characterization and antimicrobial activity of CuO nanoparticles (NPs) derived from Hibiscus sabdariffa a plant and CuCl. J Phys Conf Series 1963(1):012092

    Article  CAS  Google Scholar 

  4. Amaro-Gahete J, Benítez A, Otero R, Esquivel D, Jiménez-Sanchidrián C, Morales J, Romero-Salguero FJ (2019) A comparative study of particle size distribution of graphene nanosheets synthesized by an ultrasound-assisted method. Nanomaterials 9(2):152

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  5. Athanasekou CP, Likodimos V, Falaras P (2018) Recent developments of TiO2 photocatalysis involving advanced oxidation and reduction reactions in water. J Environ Chem Eng 6(6):7386–7394

    Article  CAS  Google Scholar 

  6. Behera M, Nayak J, Banerjee S, Chakrabortty S, Tripathy SK (2021) A review on the treatment of textile industry waste effluents towards the development of efficient mitigation strategy: an integrated system design approach. J Environ Chem Eng 9(4):105277

    Article  CAS  Google Scholar 

  7. Bolshakov AD, Fedorov VV, Shugurov KY, Mozharov AM, Sapunov GA, Shtrom IV, Mukhin IS (2019) Effects of the surface preparation and buffer layer on the morphology, electronic and optical properties of the GaN nanowires on Si. Nanotechnology 30(39):395602

    Article  CAS  PubMed  Google Scholar 

  8. Bouafia A, Laouini SE, Ouahrani MR (2020) A review on green synthesis of CuO nanoparticles using plant extract and evaluation of antimicrobial activity. Asian J Res Chem 13(1):65–70

    Article  Google Scholar 

  9. Bulut Kocabas B, Attar A, Peksel A, Altikatoglu Yapaoz M (2021) Phytosynthesis of CuONPs via Laurus nobilis: Determination of antioxidant content, antibacterial activity, and dye decolorization potential. Biotechnol Appl Biochem 68(4):889–895

    Article  CAS  PubMed  Google Scholar 

  10. Danish MSS, Estrella LL, Alemaida IMA, Lisin A, Moiseev N, Ahmadi M, Senjyu T (2021) Photocatalytic applications of metal oxides for sustainable environmental remediation. Metals 11(1):80

    Article  CAS  Google Scholar 

  11. Dulta K, Koşarsoy Ağçeli G, Chauhan P, Jasrotia R, Chauhan PK, Ighalo JO (2022) Multifunctional CuO nanoparticles with enhanced photocatalytic dye degradation and antibacterial activity. Sustainable Environ Res 32(1):1–15

    Article  Google Scholar 

  12. Ethiraj AS, Kang DJ (2012) Synthesis and characterization of CuO nanowires by a simple wet chemical method. Nanoscale Res Lett 7(1):1–5

    Article  Google Scholar 

  13. Gupta P, Ramrakhiani M (2009) Influence of the particle size on the optical properties of CdSe nanoparticles. Open Nanosci J 3(1):15–19

    Article  CAS  Google Scholar 

  14. Keerthana SP, Yuvakkumar R, Kumar PS, Ravi G, Vo DVN, Velauthapillai D (2021) Influence of tin (Sn) doping on Co3O4 for enhanced photocatalytic dye degradation. Chemosphere 277:130325

    Article  CAS  PubMed  Google Scholar 

  15. Kumaran N, Vijayaraj R, Swarnakala T (2017) BIosynthesis of silver nano particles from Leucas aspera (willd.) link and its anti-inflammatory potential against carrageen induced paw edema in rats. Int J Pharm Sci Res 8(6):2588–2593

    Google Scholar 

  16. Kumaran N, Vijayaraj R, Kumaresan M, Jayaprakashvel M (2017) Eco-friendly synthesis of silver nanoparticles from marine ascidian, Didemnum psammathodes and its in vitro anti-inflammatory properties. J Bionanosci 11(6):560–566

    Article  Google Scholar 

  17. Li X, Mei Q, Chen L, Zhang H, Dong B, Dai X, Zhou J (2019) Enhancement in adsorption potential of microplastics in sewage sludge for metal pollutants after the wastewater treatment process. Water Res 157:228–237

    Article  CAS  PubMed  Google Scholar 

  18. Mehrotra T, Dev S, Banerjee A, Chatterjee A, Singh R, Aggarwal S (2021) Use of immobilized bacteria for environmental bioremediation: a review. J Environ Chem Eng 9(5):105920

    Article  CAS  Google Scholar 

  19. Mohammed WM, Mubark TH, Al-Haddad RM (2018) Effect of CuO nanoparticles on antimicrobial activity prepared by sol-gel method. Int J Appl Eng Res Dev 13:10559–10562

    Google Scholar 

  20. Naseem T, Durrani T (2021) The role of some important metal oxide nanoparticles for wastewater and antibacterial applications: a review. Environ Chem Ecotoxicol 3:59–75

    Article  CAS  Google Scholar 

  21. Niranjan R, Zafar S, Lochab B, Priyadarshini R (2022) Synthesis and characterization of sulfur and sulfur-selenium nanoparticles loaded on reduced graphene oxide and their antibacterial activity against gram-positive pathogens. Nanomaterials 12(2):191

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  22. Pérez-Hernández H, García-Mayagoitia S, Torres-Gómez PA, Campos-Montiel RG, Fernández-Luqueño F (2022) Ecological effects of copper NPs: advantages and drawbacks regarding current and potential applications. Copper nanostructures: next-generation of agrochemicals for sustainable agroecosystems. Elsevier, pp 719–750

    Chapter  Google Scholar 

  23. Priyadarshanee M, Das S (2021) Biosorption and removal of toxic heavy metals by metal tolerating bacteria for bioremediation of metal contamination: a comprehensive review. J Environ Chem Eng 9(1):104686

    Article  CAS  Google Scholar 

  24. Quast T, Varhade S, Saddeler S, Chen YT, Andronescu C, Schulz S, Schuhmann W (2021) Single particle nanoelectrochemistry reveals the catalytic oxygen evolution reaction activity of Co3O4 nanocubes. Angew Chem Int Ed 60(43):23444–23450

    Article  CAS  Google Scholar 

  25. Rafique M, Shafiq F, Gillani SSA, Shakil M, Tahir MB, Sadaf I (2020) Eco-friendly green and biosynthesis of copper oxide nanoparticles using Citrofortunella microcarpa leaves extract for efficient photocatalytic degradation of Rhodamin B dye form textile wastewater. Optik 208:164053

    Article  CAS  Google Scholar 

  26. Raizada P, Sudhaik A, Patial S, Hasija V, Khan AAP, Singh P, Nguyen VH (2020) Engineering nanostructures of CuO-based photocatalysts for water treatment: current progress and future challenges. Arab J Chem 13(11):8424–8457

    Article  CAS  Google Scholar 

  27. Sahu K, Singh J, Mohapatra S (2019) Catalytic reduction of 4-nitrophenol and photocatalytic degradation of organic pollutants in water by copper oxide nanosheets. Opt Mater 93:58–69

    Article  CAS  Google Scholar 

  28. Sathiyavimal S, Vasantharaj S, Bharathi D, Saravanan M, Manikandan E, Kumar SS, Pugazhendhi A (2018) Biogenesis of copper oxide nanoparticles (CuONPs) using Sida acuta and their incorporation over cotton fabrics to prevent the pathogenicity of Gram negative and Gram positive bacteria. J Photochem Photobiol, B 188:126–134

    Article  CAS  PubMed  Google Scholar 

  29. Sherif ESM, Erasmus RM, Comins JD (2007) Corrosion of copper in aerated acidic pickling solutions and its inhibition by 3-amino-1, 2, 4-triazole-5-thiol. J Colloid Interface Sci 306(1):96–104

    Article  CAS  PubMed  Google Scholar 

  30. Snetkov P, Zakharova K, Morozkina S, Olekhnovich R, Uspenskaya M (2020) Hyaluronic acid: the influence of molecular weight on structural, physical, physico-chemical, and degradable properties of biopolymer. Polymers 12(8):1800

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  31. Subbulekshmi NL, Subramanian E (2017) Nano CuO immobilized fly ash zeolite Fenton-like catalyst for oxidative degradation of p-nitrophenol and p-nitroaniline. J Environ Chem Eng 5(2):1360–1371

    Article  CAS  Google Scholar 

  32. Theivasanthi T, Alagar M (2010) X-ray diffraction studies of copper nanopowder. arXiv preprint arXiv:1003.6068

  33. Thota S, Wang Y, Zhao J (2018) Colloidal Au–Cu alloy nanoparticles: synthesis, optical properties and applications. Mater Chem Front 2(6):1074–1089

    Article  CAS  Google Scholar 

  34. Verma N, Kumar N (2019) Synthesis and biomedical applications of copper oxide nanoparticles: an expanding horizon. ACS Biomater Sci Eng 5(3):1170–1188

    Article  CAS  PubMed  Google Scholar 

  35. Verma RK, Sankhla MS, Rathod NV, Sonone SS, Parihar K, Singh GK (2021) Eradication of fatal textile industrial dyes by wastewater treatment. Biointerface Res Appl Chem 12:567–587

    Article  Google Scholar 

  36. Vijayaraj R, Kumaran NS (2017) Biosynthesis of silver nanoparticles from Hibiscus rosa sinensis: an approach towards animicrobial activity on fish pathogen aeromonas hydrophila. Int J Pharm Sci Res 8(8):5241–5246

    CAS  Google Scholar 

  37. Vijayaraj R, Sri Kumaran N, Altaff K, Ramadevi S, Sherlin Rosita A (2019) In silico pharmacokinetics and molecular docking of novel bioactive compound (11-methoxy-2-methyltridecane-4-ol) for inhibiting carbohydrates hydrolyzing enzyme. J Biologically Active Products Nature 9(6):445–456

    Article  CAS  Google Scholar 

  38. Xiao M, Wang Z, Lyu M, Luo B, Wang S, Liu G, Wang L (2019) Hollow nanostructures for photocatalysis: advantages and challenges. Adv Mater 31(38):1801369

    Article  Google Scholar 

  39. Xiao W, Lei W, Gong M, Xin HL, Wang D (2018) Recent advances of structurally ordered intermetallic nanoparticles for electrocatalysis. ACS Catal 8(4):3237–3256

    Article  CAS  Google Scholar 

  40. Xu F (2018) Review of analytical studies on TiO2 nanoparticles and particle aggregation, coagulation, flocculation, sedimentation, stabilization. Chemosphere 212:662–677

    Article  CAS  PubMed  Google Scholar 

  41. You-Kang P, Aminuzzaman M, Akhtaruzzaman M, Muhammad G, Ogawa S, Watanabe A, Tey LH (2021) Green synthesis and characterization of CuO nanoparticles derived from papaya peel extract for the photocatalytic degradation of palm oil mill effluent (POME). Sustainability 13(2):796

    Article  Google Scholar 

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Correspondence to K. Rajesh.

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Vijayaraj, R., Kurinjinathan, P., Rajesh, K. et al. Investigation on Photocatalytic Activity of Copper (II) Oxide Nanoparticles for the Bio Fabrication and Industrial Applications. Chemistry Africa 6, 1297–1303 (2023). https://doi.org/10.1007/s42250-022-00566-3

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