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Acoustical-Physical Impact of Ternary Blends Having Hexane (Aniline + 1-Alkanols)

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Abstract

Ultrasonic velocity measurements on ternary blends of aniline + 1-alkanols + hexane are performed at 303 K. The acoustical parameters such as adiabatic compressibility, free length, free volume, and internal pressure are obtained from the experimental data for all the blends, with the view of investigating the exact nature of molecular interaction. The excess values of the above-mentioned parameters have also been estimated and found to be useful in estimating the strength of interaction in the blends. In ternary systems, the occurrence of weak dipole-induced dipole and dipole–dipole interactions of large values is verified. As such, they predict the origin of the interaction of the recommended interaction, potential azeotropic formation/destruction, and the mole of such systems. The analysis reveals that the interactions between the aniline-alcohol complexes predominate over the other hexane interactions.

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Authors and Affiliations

  1. Department of Physics, Saveetha Schools of Engineering, Chennai, 602 105, India

    P. Sasikumar

  2. University of Warith Al-Anbiyaa, Karbala Street, Karbala, 56001, Iraq

    Mustafa K. A. Mohammed

  3. Radiological Techniques Department, Al-Mustaqbal University College, Babylon, Iraq

    Safa H. Mohammed

  4. PG and Research Department of Physics, Chikkaiah Naicker College, Erode, Tamil Nadu, 600 004, India

    R. Thiyagarajan

  5. Department of Physics, Kalasalingam Academy of Research and Education, Krishnankoil, Tamil Nadu, 626 126, India

    M. S. Revathy

  6. Departments of Physics, Annamalai University, Chidambaram, Tamil Nadu, 608 002, India

    L. Palaniappan

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  1. P. Sasikumar
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  3. Safa H. Mohammed
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  4. R. Thiyagarajan
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Correspondence to P. Sasikumar or Mustafa K. A. Mohammed.

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Sasikumar, P., Mohammed, M.K.A., Mohammed, S.H. et al. Acoustical-Physical Impact of Ternary Blends Having Hexane (Aniline + 1-Alkanols). Chemistry Africa 5, 1433–1440 (2022). https://doi.org/10.1007/s42250-022-00422-4

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