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Poly(1,2,3-triazolium imide)s Obtained Through AA + BB Click Polyaddition

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Abstract

A series of poly(ionic liquid)s (PILs) incorporating 1,2,3-triazolium and imide units are synthesized in three steps by AA + BB polyaddition between α,ω-diazido tetraethylene glycol and three aromatic bis-imide dipropargyl monomers using copper(I)-catalyzed azide-alkyne cycloaddition (CuAAC) followed by N-alkylation of the resulting poly(1,2,3-triazole imide)s with iodomethane and subsequent anion exchange with lithium bis(trifluoromethylsulfonyl)imide. Structure/properties correlations of poly(1,2,3-triazole imide)s and corresponding poly(1,2,3-triazolium imide)s are discussed based on NMR spectroscopy, differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), size exclusion chromatography (SEC) and solubility measurements.

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Acknowledgements

The authors gratefully acknowledge the financial support from the Tunisian Ministry of High Education and Scientific Research and IDEXLYON.

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Authors and Affiliations

  1. Laboratoire de Chimie (Bio)Organique, Structurale et de Polymères - Synthèse et Étude Physico-Chimique (LR99ES14), Faculté des Sciences de Tunis, Université de Tunis El Manar, 2092, El Manar, Tunis, Tunisia

    Omaima Anaya, Imen Abdelhedi-Miladi & Hatem Ben Romdhane

  2. Univ Lyon, Université Lyon 1, CNRS, Ingénierie des Matériaux Polymères, UMR 5223, 69003, Lyon, France

    Omaima Anaya, Ali Haddane & Eric Drockenmuller

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  1. Omaima Anaya
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  2. Ali Haddane
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  4. Imen Abdelhedi-Miladi
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  5. Hatem Ben Romdhane
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Correspondence to Hatem Ben Romdhane.

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Anaya, O., Haddane, A., Drockenmuller, E. et al. Poly(1,2,3-triazolium imide)s Obtained Through AA + BB Click Polyaddition. Chemistry Africa 2, 713–721 (2019). https://doi.org/10.1007/s42250-019-00090-x

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  • DOI: https://doi.org/10.1007/s42250-019-00090-x

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