Poly(1,2,3-triazolium imide)s Obtained Through AA + BB Click Polyaddition

Abstract

A series of poly(ionic liquid)s (PILs) incorporating 1,2,3-triazolium and imide units are synthesized in three steps by AA + BB polyaddition between α,ω-diazido tetraethylene glycol and three aromatic bis-imide dipropargyl monomers using copper(I)-catalyzed azide-alkyne cycloaddition (CuAAC) followed by N-alkylation of the resulting poly(1,2,3-triazole imide)s with iodomethane and subsequent anion exchange with lithium bis(trifluoromethylsulfonyl)imide. Structure/properties correlations of poly(1,2,3-triazole imide)s and corresponding poly(1,2,3-triazolium imide)s are discussed based on NMR spectroscopy, differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), size exclusion chromatography (SEC) and solubility measurements.

Graphic Abstract

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Acknowledgements

The authors gratefully acknowledge the financial support from the Tunisian Ministry of High Education and Scientific Research and IDEXLYON.

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Correspondence to Hatem Ben Romdhane.

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Anaya, O., Haddane, A., Drockenmuller, E. et al. Poly(1,2,3-triazolium imide)s Obtained Through AA + BB Click Polyaddition. Chemistry Africa 2, 713–721 (2019). https://doi.org/10.1007/s42250-019-00090-x

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Keywords

  • Poly(ionic-liquid)s
  • Click chemistry
  • 1, 2, 3-Triazoliums
  • Polyimides
  • Step growth polymerization