Skip to main content
SpringerLink
Log in

Enhancement of the photo-chemical properties and efficacy of the mixing technique in the preparation of Schiff base-Cu(II)/poly(vinyl chloride) compounds

  • Original Article
  • Published:
Emergent Materials Aims and scope Submit manuscript

Abstract

A new Schiff base containing the 1,2,4-triazole ring system (L) was synthesized and confirmed by FTIR spectroscopy. The chemical modification of PVC with a new Schiff base (L) was synthesized to produce a homogenous blend (PVC-L). A homogenous blend (PVC-L) was added to copper chloride to produce PVC-L-Cu(II). The PVC films had been irradiated with ultraviolet light for a long period and confirmed by FTIR spectroscopy and weight loss; the surface morphology was inspected by scanning electron microscopy.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Scheme 1
Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8

Similar content being viewed by others

References

  1. M.N.A. Al-Jibouri, S.A.H. Al-Ameri, W.M. Al-Jibouri, M.A.K. Al-Souz, Spectroscopic study of the effect of a new metal chelate on the stability of PVC. J. Ass. Arab Univ. Bas. Appl. Sci. 14, 67–74 (2013)

    Google Scholar 

  2. J. Yu, L. Sun, C. Ma, Y. Qiao, H. Yao, Thermal degradation of PVC: a review. Waste Manag. 48, 300–314 (2016)

    Article  CAS  Google Scholar 

  3. S. Goodman, The microwave induced pyrolysis of problematic plastics enabling recovery and component reuse, (Civil and Environmental Engineering. Imperial College London, London, 2014)

    Google Scholar 

  4. C. Pittmann, in , ed. by P. Hodge, D. C. Sherrington. Polymer supported reactions in organic synthesis (Wiley, New York (Chapter 5), 1980)

    Google Scholar 

  5. L. Bernard, R. Cueff, D. Bourdeaux, C. Breysse, V. Sautou, Analysis of plasticizers in poly(vinyl chloride) medical devices for infusion and artificial nutrition: comparison and optimization of the extraction procedures, a pre-migration test step. Anal. Bioanal. Chem. 407, 1651–1659 (2015)

    Article  CAS  Google Scholar 

  6. S. Lakshmi, A. Jayakrishnan, Photocross-linking of dithiocarbamate-substituted PVC reduces plasticizer migration. Polymer 39, 151–157 (1998)

    Article  CAS  Google Scholar 

  7. T. Kameda, G. Grause, T. Yoshioka, Chemical modification of flexible and rigid poly(vinyl chloride) by nucleophilic substitution with thiocyanate using a phase-transfer catalyst. Mater. Chem. Phys. 124, 163–167 (2010)

    Article  CAS  Google Scholar 

  8. C. Liu, Y. Luo, B. Zhong, S. Li, B. Guo, D. Jia, Enhancement of mechanical properties of poly(vinyl chloride) with polymethyl methacrylate-grafted halloysite nanotube. Exp. Polym. Lett. 5, 591–603 (2011)

    Article  CAS  Google Scholar 

  9. J. Milenkovic, J. Hrenovic, I. Goic-Barisic, M. Tomic, J. Djonlagic, N. Rajic, Synergistic anti-biofouling effect of Ag-exchanged zeolite and D-tyrosine on PVC composite against the clinical isolate of Acinetobacter baumannii. Biofouling. 30, 965–973 (2014)

    Article  CAS  Google Scholar 

  10. M. Ghoranneviss, S. Shahidi, J. Wiener, Surface modification of poly vinyl chloride (PVC) using low pressure argon and oxygen plasma. Plas. Sci. Tech. 12, 204–207 (2010)

    Article  CAS  Google Scholar 

  11. Y. Haishima, K. Isama, C. Hasegawa, T. Yuba, A. Matsuoka, A development and biological safety evaluation of novel PVC medical devices with surface structures modified by UV irradiation to suppress plasticizer migration. J. Biomed. Mater. Res. A 101, 2630–2643 (2013)

    Article  Google Scholar 

  12. T. Kameda, M. Ono, G. Grause, T. Mizoguchi, T. Yoshioka, Chemical modification of poly(vinyl chloride) by nucleophilic substitution. Polym. Degrad. Stab. 94, 107–112 (2009)

    Article  CAS  Google Scholar 

  13. R. Li, L. Ye, Y.W. Mai, Application of plasma technologies in fibre-reinforced polymer composites: a review of recent developments. Compos. Part A: Appl.Sci. Manuf. 28, 73–86 (1997)

    Article  Google Scholar 

  14. D. Sun, G. Stylios, Investigating the plasma modification of natural fiber fabrics–the effect on fabric surface and mechanical properties. Text. Res. J. 75, 639–644 (2005)

    Article  CAS  Google Scholar 

  15. P. Jia, M. Zhang, L. Hu, R. Wang, C. Sun, Y. Zhou, Cardanol groups grafted on poly(vinyl chloride)-synthesis, performance and plasticization mechanism. Polymers 9, 621 (2017)

    Article  Google Scholar 

  16. E. Yousif, D.S. Ahmed, A.A. Ahmed, A.S. Hameed, S.H. Muhamed, R.M. Yusop, A. Redwan, S.A. Mohammed, The effect of high UV radiation exposure environment on the novel PVC polymers. Environ. Sci. Pollut. Res. Int. 26, 9945–9954 (2019)

    Article  CAS  Google Scholar 

  17. J. Chen, Z. Liu, X. Li, P. Liu, J. Jiang, X. Nie, Thermal behavior of epoxidized cardanol diethyl phosphate as novel renewable plasticizer for poly(vinyl chloride). Polym. Degrad. Stab. 126, 58–64 (2016)

    Article  CAS  Google Scholar 

  18. E. Yousif, D.S. Ahmed, A.A. Ahmed, A.S. Hameed, S.H. Muhamed, R.M. Yusop, A. Redwan, S.A. Mohammed, The effect of high UV radiation exposure environment on the novel PVC polymers. Environ. Sci. Pollut. Res. (2019). https://doi.org/10.1007/s11356-019-04323-x

    Article  CAS  Google Scholar 

  19. S. Moulay, Chemical modification of poly (vinyl chloride)—still on the run. Prog. Polym. Sci. 35, 303–331 (2010)

    Article  CAS  Google Scholar 

  20. E. Yousif, N. Asaad, D.S. Ahmed, S.A. Mohammed, A.H. Jawad, A spectral, optical, microscopic study, synthesis and characterization of PVC films containing Schiff base complexes. Bagh. Sci. J. 16, 56–60 (2019)

    Article  Google Scholar 

  21. L. Claudiu, R. Edina, M. Bogdan, Z. Teodora, H. Gheorghe, UPB Sci. Bull. Series B 72, 127–140 (2010)

    Google Scholar 

  22. S. Nikafshar, O. Zabihi, M. Ahmadi, A. Mirmohseni, M. Taseidifar, M. Naebe, The effect of UV light on the chemical and mechanical properties of a transparent epoxy-diamine system in the presence of an organic UV absorber. Materials 10, 180 (2017)

    Article  Google Scholar 

  23. H. Hashim, G.A. El-Hiti, M.H. Alotaibi, D.S. Ahmed, E. Yousif, Fabrication of ordered honeycomb porous poly(vinyl chloride) thin film doped with a Schiff base and nickel(II) chloride. Heliyon 4, e00743 (2018)

    Article  Google Scholar 

  24. M.H. Alotaibi, G.A. El-Hiti, H. Hashim, A.S. Hameed, D.S. Ahmed, E. Yousif, SEM analysis of the tunable honeycomb structure of irradiated poly(vinyl chloride) films doped with polyphosphate. Heliyon 4, e01013 (2018)

    Article  Google Scholar 

  25. T.M. Wu, Y.W. Lin, C.S. Liao, Preparation and characterization of polyaniline/multi-walled carbon nanotube composites. Carbon 43, 734–740 (2005)

    Article  CAS  Google Scholar 

  26. H.J. Rhoo, H.T. Kim, J.K. Park, T.S. Hwang, Ionic conduction in plasticized PVC/PMMA blend polymer electrolytes. Electrochim. Acta. 42, 1571–1579 (1997)

    Article  CAS  Google Scholar 

  27. M.Y.A. Rahman, A. Ahmad, T.K. Lee, Y. Farina, H.D. Dahlan, Effect of ethylene carbonate(EC) plasticizer on poly(vinyl chloride)-liquid 50% epoxidised natural rubber (LENR50) based polymer electrolyte. Mater. Sci. Appl. 2, 817–825 (2011)

    Google Scholar 

  28. M. Huh, M. Gauthier, S. Yun, Honeycomb structured porous films prepared from arborescent graft polystyrenes via the breath figures method. Polymer. 107, 273–281 (2016)

    Article  CAS  Google Scholar 

  29. O. Amiri, M. Salavati-Niasari, N. Mir, F. Beshkar, M. Saadat, F. Ansari, Plasmonic enhancement of dye-sensitized solar cells by using Au-decorated Ag dendrites as a morphology-engineered. Renew. Energy 125, 590–598 (2018)

    Article  CAS  Google Scholar 

  30. S.G. Chiuzbăian, S. Brignolo, C.F. Hague, R. Delaunay, M. Guarise, A. Nicolaou, Z. Yang, H. Zhou, J.M. Mariot, Spectroscopic evidence for super exchange in the ferromagnetic spinel FeCr2S4. J. Phys. Chem. C. 121, 21935–21944 (2017)

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Chemistry, College of Science, Al-Nahrain University, Baghdad, 64021, Iraq

    Emad Yousif, Mustafa Abdallh & Ahmed A. Ahmed

  2. Department of Physics, College of Science, Al-Nahrain University, Baghdad, 64021, Iraq

    Hassan Hashim

  3. Polymer Research Unit, College of Science, Al-Mustansiriyah University, Baghdad, Iraq

    Ahmed Ahmed

  4. Department of Medical Instrumentation Engineering, Al-Mansour University College, Baghdad, 64021, Iraq

    Dina S. Ahmed

  5. School of Chemical Science and Food Technology, Faculty of Science and Technology, University Kebangsaan Malaysia, 43600, Bangi, Selangor, Malaysia

    Rahimi M. Yusop

Authors
  1. Emad Yousif
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Mustafa Abdallh
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Hassan Hashim
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Ahmed Ahmed
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Dina S. Ahmed
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Rahimi M. Yusop
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. Ahmed A. Ahmed
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Emad Yousif.

Ethics declarations

Conflict of interest

The authors declare that they have no conflict of interest.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Yousif, E., Abdallh, M., Hashim, H. et al. Enhancement of the photo-chemical properties and efficacy of the mixing technique in the preparation of Schiff base-Cu(II)/poly(vinyl chloride) compounds. emergent mater. 2, 505–512 (2019). https://doi.org/10.1007/s42247-019-00059-z

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s42247-019-00059-z

Keywords

Search

Navigation