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Impact toughness variations of EH36 weld metal treated by CaF2–SiO2–MnO submerged arc welding flux

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Abstract

Fused ternary CaF2–SiO2–MnO fluxes have been manufactured and applied to join EH36 shipbuilding steel under high heat input submerged arc welding. Five fluxes have been designed to clarify the effect of MnO content in CaF2–SiO2–MnO flux on the impact toughness of the weld metal, with the added amount of MnO from 10 to 50 wt.% at the expense of CaF2. With the increase in MnO content, the Charpy impact energy increases first and then decreases, experiencing a maximum value at 30 wt.% MnO. Microstructure of the weld metals has also been studied to account for impact toughness variations. It has been demonstrated that the highest acicular ferrite volume fraction in the weld metal is achieved at 30 wt.% MnO, which is concurrent to the maximum value of Charpy impact energy. It is believed that the Mn and O content variations in the weld metal contribute synergistically to such an interesting phenomenon.

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References

  1. Y. Wang, X. Zhang, L. Cheng, J. Liu, T. Hou, K. Wu, J. Mater. Res. Technol. 13 (2021) 2419–2432.

    Article  Google Scholar 

  2. J. Wang, W.J. Wu, W. Jing, X. Tan, G.J. Bi, S.B. Tor, K.F. Leong, C.K. Chua, E. Liu, Mater. Sci. Eng. A 746 (2019) 300–313.

    Article  Google Scholar 

  3. C. Roepke, S. Liu, S. Kelly, R. Martukanitz, Weld. J. 89 (2010) 140–149.

    Google Scholar 

  4. C. Wang, J. Zhang, Acta Metall. Sin. 57 (2021) 1126–1140.

    Google Scholar 

  5. S. Shen, I.N.A. Oguocha, S. Yannacopoulos, J. Mater. Process. Technol. 212 (2012) 286–294.

    Article  Google Scholar 

  6. X. Yuan, Y. Wu, M. Zhong, S. Basu, Z. Wang, C. Wang, Sci. Technol. Weld. Join. 27 (2022) 683–690.

    Article  Google Scholar 

  7. Y. Wu, X. Yuan, I. Kaldre, M. Zhong, Z. Wang, C. Wang, Metall. Mater. Trans. B 54 (2023) 50–55.

    Article  Google Scholar 

  8. M. Zhong, T. Li, S. Basu, Z. Wang, C. Wang, Metall. Mater. Trans. B 53 (2022) 2774–2778.

    Article  Google Scholar 

  9. X. Zou, D. Zhao, J. Sun, C. Wang, H. Matsuura, Metall. Mater. Trans. B 49 (2018) 481–489.

    Article  Google Scholar 

  10. K. Nakashima, K. Hase, T. Eto, JFE Tech. Rep. 20 (2015) 8–13.

    Article  Google Scholar 

  11. M. Zhong, H. Matsuura, F. Tsukihashi, Mater. Trans. 56 (2015) 1192–1198.

    Article  Google Scholar 

  12. M. Zhong, H. Matsuura, F. Tsukihashi, ISIJ Int. 55 (2015) 2283–2288.

    Article  Google Scholar 

  13. M. Zhong, H. Matsuura, F. Tsukihashi, Metall. Mater. Trans. B 47 (2016) 1745–1752.

    Article  Google Scholar 

  14. M. Minagawa, K. Ishida, Y. Funatsu, S. Imai, Nippon Steel Tech. Rep. 57 (2004) 6–8.

    Google Scholar 

  15. D.Y. Kim, T.W. Uhm, H. Lee, Y.J. Lee, B.J. Ryu, J.H. Kim, Korean J. Chem. Eng. 22 (2005) 569–572.

    Article  Google Scholar 

  16. S. Kumar, A.S. Shahi, Mater. Des. 32 (2011) 3617–3623.

    Article  Google Scholar 

  17. R.A. Ricks, P.R. Howell, G.S. Barritte, J. Mater. Sci. 17 (1982) 732–740.

    Article  Google Scholar 

  18. J.S. Byun, J.H. Shim, J.Y. Suh, Y.J. Oh, Y.W. Cho, J.D. Shim, D.N. Lee, Mater. Sci. Eng. A 319–321 (2001) 326–331.

    Article  Google Scholar 

  19. X. Zou, L. Zhou, H. Matsuura, C. Wang, JOM 73 (2021) 1110–1117.

    Article  Google Scholar 

  20. J. Zhang, T. Coetsee, H. Dong, C. Wang, Metall. Mater. Trans. B 51 (2020) 1953–1957.

    Article  Google Scholar 

  21. J. Zhang, T. Coetsee, C. Wang, Metall. Mater. Trans. B 51 (2020) 16–21.

    Article  Google Scholar 

  22. Y. Shao, C. Liu, Z. Yan, H. Li, Y. Liu, J. Mater. Sci. Technol. 34 (2018) 737–744.

    Article  Google Scholar 

  23. Z. Xiong, S. Liu, X. Wang, C. Shang, X. Li, R.D.K. Misra, Mater. Sci. Eng. A 636 (2015) 117–123.

    Article  Google Scholar 

  24. M. Fattahi, N. Nabhani, M. Hosseini, N. Arabian, E. Rahimi, Micron 45 (2013) 107–114.

    Article  Google Scholar 

  25. X. Xie, M. Zhong, T. Zhao, C. Wang, Sci. Technol. Weld. Join. 27 (2022) 472–478.

    Article  Google Scholar 

  26. X. Xie, M. Zhong, T. Zhao, C. Wang, J. Iron Steel Res. Int. 30 (2023) 150–157.

    Article  Google Scholar 

  27. J. Zhang, J. Leng, C. Wang, Metall. Mater. Trans. B 50 (2019) 2083–2087.

    Article  Google Scholar 

  28. J. Pu, S. Yu, Y. Li, J. Mater. Process. Technol. 240 (2017) 145–153.

    Article  Google Scholar 

  29. G.M. Evans, Weld. J. 59 (1980) 67–75.

    Google Scholar 

  30. S. Hanai, N. Takemoto, Y. Tokunaga, Y. Mizuyama, ISIJ Int. 24 (1984) 17–23.

    Article  Google Scholar 

  31. R.L. Klueh, P.J. Maziasz, E.H. Lee, Mater. Sci. Eng. A 102 (1988) 115–124.

    Article  Google Scholar 

  32. P.F. Chaveriat, G.S. Kim, S. Shah, J.E. Indacochea, J. Mater. Eng. 9 (1987) 253–267.

    Article  Google Scholar 

  33. X. Yuan, M. Zhong, Y. Wu, C. Wang, Metall. Mater. Trans. B 53 (2022) 656–661.

    Article  Google Scholar 

  34. D. Loder, S.K. Michelic, C. Bernhard, J. Mater. Sci. Res. 6 (2016) 24.

    Google Scholar 

  35. B. Beidokhti, A.H. Koukabi, A. Dolati, Mater. Charact. 60 (2009) 225–233.

    Article  Google Scholar 

  36. C.S. Chai, T.W. Eagar, Weld. J. 61 (1982) 229–232.

    Google Scholar 

  37. C.S. Chai, T.W. Eagar, Metall. Trans. B 12 (1981) 539–547.

    Article  Google Scholar 

  38. U. Mitra, T.W. Eagar, Metall. Trans. B 22 (1991) 65–71.

    Article  Google Scholar 

  39. U. Mitra, T.W. Eagar, Metall. Trans. B 22 (1991) 73–81.

    Article  Google Scholar 

  40. J. Zhang, T. Coetsee, H. Dong, C. Wang, Metall. Mater. Trans. B 51 (2020) 885–890.

    Article  Google Scholar 

  41. E.L. Singleton, L. Carpenter, R.V. Lundquist, Studies of the MnO–SiO2 binary system, U.S. Department of the Interior, Bureau of Mines, 1962.

  42. Y. Putilin, A. Romanova, A. Milov, Ionnye Rasplav. 4 (1976) 79–83.

    Google Scholar 

  43. B. Kim, S. Uhm, C. Lee, J. Lee, Y. An, J. Eng. Mater. Technol. 127 (2005) 204–213.

    Article  Google Scholar 

  44. X.D. Zou, J.C. Sun, D.P. Zhao, H. Matsuura, C. Wang, J. Iron Steel Res. Int. 25 (2018) 164–172.

    Article  Google Scholar 

  45. J. Jang, J.E. Indacochea, J. Mater. Sci. 22 (1987) 689–700.

    Article  Google Scholar 

  46. R. Homma, K. Kadoi, H. Inoue, Mater. Today Commun. 29 (2021) 102963.

    Article  Google Scholar 

  47. S. Liu, D.L. Olson, Weld. J. 65 (1986) 139–149.

    Google Scholar 

  48. C.L. Choi, D.C. Hill, Weld. J. 57 (1978) 232–236.

    Google Scholar 

  49. F. Chai, H. Su, C.F. Yang, D.M. Xue, J. Iron Steel Res. Int. 21 (2014) 369–374.

    Article  Google Scholar 

  50. R.A. Farrar, P.L. Harrison, J. Mater. Sci. 22 (1987) 3812–3820.

    Article  Google Scholar 

  51. G.M. Evans, Weld. J. 61 (1982) 125–132.

    Google Scholar 

  52. O. Grong, D.K. Matlock, Int. Met. Rev. 31 (1986) 27–48.

    Article  Google Scholar 

Download references

Acknowledgements

The authors sincerely thank the State Key Laboratory of Refractories and Metallurgy (Grant No. G202206), National Natural Science Foundation of China (Grant Nos. U20A20277 and 52150610494), and National Key Research and Development Program of China (Grant No. 2022YFE0123300).

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Correspondence to Cong Wang.

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Zhong, M., Guo, Dm., Basu, S. et al. Impact toughness variations of EH36 weld metal treated by CaF2–SiO2–MnO submerged arc welding flux. J. Iron Steel Res. Int. 30, 1873–1878 (2023). https://doi.org/10.1007/s42243-023-01017-0

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