Abstract
The effects of magnesium (Mg) on the microstructure and properties of 440C stainless bearing steel melted under pressurized conditions were studied. Adding Mg improved the cleanliness of molten steel, modified the inclusions in steel, enhanced the distribution of carbides, and improved the mechanical properties and corrosion resistance of experimental steel. In detail, the contents of TO, S, and N in steel decreased from 0.0013 to 0.0003 wt.%, from 0.0032 to 0.0018 wt.% and from 0.0088 to 0.0049 wt.%, respectively. In addition, the transformation order of oxide inclusions in steel is Al2O3 → MgO·Al2O3 → MgO, where the content of Mg in steel sharply increased from 0.00 to 29 × 10−4, 81 × 10−4, and 160 × 10−4 wt.%, and the transformation order of S-containing inclusions in steel is MnS → Mg–S–Mn(–MgO) → Mg–O–S. Moreover, the number and size of inclusions and the proportion of large-size inclusions in steel decreased rapidly. Furthermore, the network structure of carbides in steel collapsed, the size of carbides was reduced, and the distribution was more uniform. Finally, the tensile strength, impact toughness, and pitting corrosion resistance of the experimental steel were significantly improved.
Similar content being viewed by others
References
H. Wu, G.X. Zhang, W.C. Zhao, Plating and Finishing 37 (2015) No. 3, 16–19.
M.Q. Yu, Shanghai Metals 30 (2008) No. 3, 49–54.
A.L. Li, Q. He, Y. Zhang, J. Anyang Inst. Tech. 16 (2018) No. 4, 8–12.
X.C. Zhang, L.J. Zhang, Bearing 12 (2001) No. 3, 8–12.
L.F. Zhang, S.Q. Wang, J.H. Duan, Non-metallic inclusions and element segregation in bearing steel, Metallurgical industry press, Beijing, China, 2017.
C.Y. Chen, Effect of magnesium on inclusions and properties of D2 cold working die steel, Northeastern University, Shenyang, China, 2016.
Z.H. Liang, Study on metal injection molding process of 440C stainless steel, Central South University, Changsha, China, 2008.
G. Prieto, A. Mandri, G. Rabbia, W.R. Tuckart, R. Dommarco, J. Mater. Eng. Perf. 29 (2020) 2216–2226.
C. Ama, A. Maha, D. Ihsb, B. Nrha, Mater. Today Proc. 44 (2021) 1750–1754.
F.M. Kustas, M.S. Misra, W.T. Tack, J. Vac. Sci. Technol. 4 (1986) 2885–2891.
A. Idayan, A. Gnanavelbabu, K. Rajkumar, Proc. Eng. 97 (2014) 1683–1691.
Q. Wang, B. Li, D.L. Sun, G.H. Wu, X.M. Tang, Trans. Mater. Heat Treat. 30 (2009) 119–122.
C. Wang, Effect of rare earth lanthanum and magnesium on cleanliness and properties of typical special steel, Northeastern University, Shenyang, China, 2017.
G. Xu, Metallurgical behavior of calcium and magnesium in molten steel and their effect on microstructure and properties of steel, Northeastern University, Shenyang, China, 2019.
H.D. Wang, Effect of magnesium on microstructure and properties of cold working die steel, Northeastern University, Shenyang, China, 2014.
W. Gong, Z.H. Jiang, L.X. Zhang, C.Y. Chen, Y.W. Dong, Mater. Sci. Eng. A 791 (2020) 139410.
S. Wang, Q. Jiang, Y. Zhao, Z. He, J. Mater. Sci. Let. 15 (1996) 256–257.
B. He, J. Li, C.B. Shi, H. Wang, Metall. Res. Technol. 115 (2018) 501.
J.X. Chen, Data manual of common charts for steelmaking, Metallurgical Industry Press, Beijing, China, 2010.
J.B. Lv, Influence of magnesium on the microstructure and performance of M7 high speed steel under pressurization, Northeastern University, Shenyang, China, 2018.
Y.F. Wang, Study on Mg treatment of 5CrNiMo hot work die steel melted under pressurization, Northeastern University, Shenyang, China, 2017.
D. Mclean, Grain boundarines in metals, Oxford University Press, London, UK, 1957.
M.V. Speight, Acta Metall. 16 (1968) 133–135.
J. Zhou, D.S. Ma, C.M. Zhang, A.H. Kang, X.Y. Li, Z.Z. Chen, Heat Treat. Met. 37 (2003) No. 5, 53–58.
J. Liu, Q.L. Lu, Z. Li, S.B. Zheng, H.G. Li, J. Iron Steel Res. 23 (2011) No. 5, 39–44.
Q.L. Lu, S.B. Zheng, X.D. Qiu, Z. Li, Shanghai Metals 30 (2008) No. 6, 28–32.
Acknowledgements
The authors are grateful for the support to the National Natural Science Foundation of China (Nos. U1760206 and 52074075).
Author information
Authors and Affiliations
Corresponding authors
Ethics declarations
Conflict of interest
On behalf of all authors, the corresponding author states that there is no conflict of interest.
Rights and permissions
Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.
About this article
Cite this article
Li, Y., Chen, Cy., Wang, Q. et al. Effect of magnesium on microstructure and properties of 440C stainless bearing steel melted under pressurized conditions. J. Iron Steel Res. Int. 30, 808–824 (2023). https://doi.org/10.1007/s42243-023-00914-8
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s42243-023-00914-8