Skip to main content
SpringerLink
Log in

Characteristics and stability of oxide + carbonitride in H13 steel at 1250 °C

  • Original Paper
  • Published:
Journal of Iron and Steel Research International Aims and scope Submit manuscript

Abstract

The morphology, size, quantity, and composition of complex oxide + carbonitride in H13 steel held at 1250 °C for 5, 10, and 15 h were determined. The results show that the ratio and number of complex carbonitrides with cores in H13 steel are gradually increased when holding at 1250 °C compared with those in the original H13 steel, and the core size increases. There are one or more oxide cores in (Tix,V1−x)(Cy,N1−y), including xCaO·zAl2O3, xCaO·yMgO·zAl2O3, and CaO after holding at 1250 °C, in addition to MgO·Al2O3 and Al2O3 in the original steel. The equilibrium temperature for (Tix, V1−x)(Cy,N1−y) precipitation at the solidification front and decomposition in the solid state was theoretically analyzed, which was affected by the x value and the product of Ti and N contents in H13 steel. Meanwhile, the composition of (Tix,V1−x)(Cy,N1−y) is influenced by the oxide cores. It is convinced that (Tix,V1−x)(Cy,N1−y) with oxide cores has a higher stability, especially for oxides with a high Al2O3 content. Heat treatment at high temperature facilitates a more reasonable analysis of oxide + carbonitride, and the generation mechanism of oxide + carbonitride was discussed.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10

Similar content being viewed by others

References

  1. K.M. McHugh, Y. Lin, Y. Zhou, E.J. Lavernia, Mater. Sci. Eng. A 477 (2008) 50–57.

    Article  Google Scholar 

  2. L.L. Mishnaevsky, N. Lippmann, S. Schmauder, Int. J. Mater. Res. 94 (2003) 676–681.

    Article  CAS  Google Scholar 

  3. Y.Y. Hou, G.G. Cheng, H.J. Cheng, Metall. Mater. Trans. B 51 (2020) 709–721.

    Article  CAS  Google Scholar 

  4. W. Choi, H. Matsuura, F. Tsukihashi, ISIJ Int. 53 (2013) 2007–2012.

    Article  CAS  Google Scholar 

  5. M.G. Li, H. Matsuura, F. Tsukihashi, Metall. Mater. Trans. B 50 (2019) 748–760.

    Article  CAS  Google Scholar 

  6. M.T. Mao, H.J. Guo, F. Wang, X.L. Sun, Int. J. Miner. Metall. Mater. 26 (2019) 839–848.

    Article  CAS  Google Scholar 

  7. Y. Huang, G.G. Cheng, S.J. Li, W.X. Dai, Steel Res. Int. 90 (2019) 1900035.

    Article  Google Scholar 

  8. X.L. Sun, F. Wang, X.C. Chen, H.J. Guo, M.T. Mao, Chin. J. Eng. 39 (2017) 61–67.

    CAS  Google Scholar 

  9. Y. Xie, G.G. Cheng, X.L. Meng, L. Chen, Y.D. Zhang, ISIJ Int. 56 (2016) 1996–2005.

    Article  CAS  Google Scholar 

  10. S. Gao, M. Wang, J.L. Guo, H. Wang, J.G. Zhi, Y.P. Bao, Met. Mater. Int. 27 (2021) 1306–1314.

    Article  CAS  Google Scholar 

  11. X.J. Wang, G.Q. Li, Y. Liu, Y.L. Cao, F. Wang, Q. Wang, Metals 9 (2019) 1247.

    Article  CAS  Google Scholar 

  12. J. Li, J. Li, C.B. Shi, L.L. Wang, Z. Wu, H. Wang, Can. Metall. Quart. 55 (2016) 321–327.

    Article  CAS  Google Scholar 

  13. B. He, J. Li, C.B. Shi, H. Wang, Metall. Res. Technol. 115 (2018) 501.

    Article  CAS  Google Scholar 

  14. C.B. Shi, X.C. Chen, H.J. Guo, Z.J. Zhu, X.L. Sun, Metall. Mater. Trans. B 44 (2013) 378–389.

    Article  CAS  Google Scholar 

  15. C.B. Shi, Q.T. Zhu, W.T. Yu, H.D. Song, J. Li, J. Mater. Eng. Perform. 25 (2016) 4785–4795.

    Article  CAS  Google Scholar 

  16. Y. Huang, G.G. Cheng, S.J, Li, W.X. Dai, Steel Res. Int. 89 (2018) 1800371.

  17. X.L. Sun, F. Wang, X.C. Chen, M.T. Mao, H.J. Guo, Chin. J. Eng. 39 (2017) 721–730.

    CAS  Google Scholar 

  18. M. Jiang, K.P. Wang, Z.W. Hou, X.H. Wang, Chin. J. Eng. 38 (2016) 780–786.

    CAS  Google Scholar 

  19. D.S. Ma, J. Zhou, Z.Z. Chen, Z.K. Zhang, Q.A. Chen, D.H. Li, J. Iron Steel Res. Int. 16 (2009) No. 5, 56–60.

    Article  CAS  Google Scholar 

  20. J.H. Liu, G.X. Wang, Y.P. Bao, Y. Yang, W. Yao, X.N. Cui, J. Iron Steel Res. Int. 19 (2012) No. 11, 1–7.

    Article  ADS  Google Scholar 

  21. J.X. Chen, Common chart data sheet for steelmaking, Metallurgical Industry Press, Beijing, China, 2010.

    Google Scholar 

  22. P. Rocabois, J. Lehmann, H. Gaye, M. Wintz, J. Cryst. Growth 198–199 (1999) 838–843.

    Article  ADS  Google Scholar 

  23. Q.L. Yong, Y.F. Li, Z.B. Sun, B.R. Wu, Acta Metall. Sin. 24 (1988) A373–A375.

    CAS  Google Scholar 

  24. S.K. Choudhary, A. Ghosh, ISIJ Int. 49 (2009) 1819–1827.

    Article  CAS  Google Scholar 

  25. H. Shibata, D.R. Poirier, T. Emi, ISIJ Int. 38 (1998) 339–347.

    Article  CAS  Google Scholar 

Download references

Acknowledgements

This work is financially supported by Hebei Natural Science Foundation under Grant Nos. E2020402067, E2018402098, and E2021402056, Open Program of State Key Laboratory of Advanced Metallurgy under Grant No. K1:21-08, Key Project of Handan Scientific Research Program under Grant No. 21122015004, and the Science and Technology Research and Development Program of Handan City under Grant No. 21422101235. The authors would like to express their sincere thanks to Tianjin CISRI-HARDER Materials & Technology Co., Ltd. for the experiment.

Author information

Authors and Affiliations

  1. School of Materials Science and Engineering, Hebei University of Engineering, Handan, 056038, Hebei, China

    Xiao-lin Sun, Dong Xu, Gao-yang Song & Shuai Wang

  2. School of Metallurgical and Ecological Engineering, University of Science and Technology Beijing, Beijing, 100083, China

    Han-jie Guo & Jing Guo

  3. High Temperature Materials Research Institute, Central Iron and Steel Research Institute Co., Ltd., Beijing, 100081, China

    Fei Wang

  4. Technology Innovation Center for High Quality Cold Heading Steel of Hebei Province, Hebei University of Engineering, Handan, 056038, Hebei, China

    Dong Xu & Shuai Wang

Authors
  1. Xiao-lin Sun
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Han-jie Guo
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Jing Guo
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Fei Wang
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Dong Xu
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Gao-yang Song
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. Shuai Wang
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Xiao-lin Sun.

Ethics declarations

Conflict of interest

The authors declare no conflict of interest.

Rights and permissions

Springer Nature or its licensor holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Sun, Xl., Guo, Hj., Guo, J. et al. Characteristics and stability of oxide + carbonitride in H13 steel at 1250 °C. J. Iron Steel Res. Int. 31, 134–142 (2024). https://doi.org/10.1007/s42243-022-00833-0

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s42243-022-00833-0

Keywords

Search

Navigation