Abstract
V48Fe12Ti15Cr25 alloy was prepared using vacuum arc melting and was subsequently annealed for 10 h at 1273 K. The effects of annealing on the hydrogen storage properties and microstructure of the V48Fe12Ti15Cr25 alloys were investigated. The results indicated that the alloy consisted of main body-centered cubic, Ti-rich, and TiFe phases. After annealing, the kinetic properties of the alloy were improved but its hydrogen storage capacity was slightly reduced. The kinetic mechanisms of the hydrogen absorption and desorption of the alloys were studied. The dehydrogenation enthalpy of the alloy was decreased by 2.57 kJ/mol after annealing. Differential scanning calorimetry indicated that the hydride decomposition temperature of the annealed alloy was decreased. The hydrogen desorption activation energies of the as-cast and annealed alloys were calculated to be 79.41 and 71.25 kJ/mol, respectively. The results illustrated that annealing was a beneficial method of improving the kinetic and thermodynamic properties of the hydrogen absorption/desorption of the alloy.
Similar content being viewed by others
References
J.L. Gao, Y. Qi, Y.Q. Li, H.W. Shang, D.L. Zhao, Y.H. Zhang, J. Iron Steel Res. Int. 24 (2017) 198–205.
Z.M. Yuan, T. Yang, W.G. Bu, H.W. Shang, Y. Qi, Y.H. Zhang, Int. J. Hydrogen Energy 41 (2016) 5994–6003.
H.C. Lin, K.M. Lin, K.C. Wu, H.H. Hsiung, H.K. Tsai, Int. J. Hydrogen Energy 32 (2007) 4966–4972.
D.C. Feng, H. Sun, Z.H. Hou, D.L. Zhao, X.T. Wang, Y.H. Zhang, J. Iron Steel Res. Int. 24 (2017) 50–58.
D.C. Feng, H. Sun, X.T. Wang, Y.H. Zhang, J. Iron Steel Res. Int. 25 (2018) 746–754.
M. Anik, F. Karanfil, N. Küçükdeveci, Int. J. Hydrogen Energy 37 (2012) 299–308.
Y.H. Zhang, Z.C. Jia, Z.M. Yuan, T. Yang, Y. Qi, D.L. Zhao, J. Iron Steel Res. Int. 22 (2015) 757–770.
M.V. Lototsky, V.A. Yartys, I.Y. Zavaliy, J. Alloy. Compd. 404 (2005) 421–426.
X.P. Song, P. Pei, P.L. Zhang, G.L. Chen, J. Alloy. Compd. 455 (2008) 392–397.
X.B. Yu, Z Wu, B.J. Xia, T.Z. Huang, J.Z. Chen, Z.S. Wang, N.X. Xu, J. Mater. Res. 18 (2003) 2533–2536.
X.B. Yu, J.Z. Chen, Z. Wu, B.J. Xia, N.X. Xu, Int. J. Hydrogen Energy 29 (2004) 1377–1381.
X.B. Yu, Z.X. Yang, S.L. Feng, Z. Wu, N.X. Xu, Int. J. Hydrogen Energy 31 (2006) 1176–1181.
X.B. Yu, S.L. Feng, Z. Wu, B.J. Xia, N.X. Xu, J. Alloy. Compd. 393 (2005) 129–134.
X.B. Yu, Z.W. Tang, D.L. Sun, L.Z Ouyang, M. Zhu, Prog. Mater. Sci. 88 (2017) 1–48.
T. Tamura, Y. Tominaga, K. Matsumoto, T. Fuda, T. Kuriiwa, A. Kamegawa, H. Takamura, M. Okada, J. Alloy. Compd. 330 (2002) 522–525.
S.W. Cho, C.S. Han, C.N. Park, E. Akiba, J. Alloy. Compd. 289 (1999) 244–250.
K. Asano, S. Hayashi, Y. Nakamura, E. Akiba, J. Alloy. Compd. 524 (2012) 63–68.
K. Asano, S. Hayashi, Y. Nakamura, Acta Mater. 83 (2015) 479–487.
K. Asano, S. Hayashi, Y. Nakamura, Int. J. Hydrogen Energy 41 (2016) 6369–6375.
H. Kim, K. Sakaki, I. Saita, H. Enoki, K. Noguchi, A. Machida, T. Watanuki, Y. Nakamura, Int. J. Hydrogen Energy 39 (2014) 10546–10551.
G. Mazzolai, Int. J. Hydrogen Energy 33 (2008) 7116–7121.
S.W. Cho, C.N. Park, J.H. Yoo, J. Choi, J.S. Park, C.Y. Suh, G. Shim, J. Alloy Compd. 403 (2005) 262–266.
T. Kabutomori, H. Takeda, Y. Wakisaka, K. Ohnishi, J. Alloy. Compd. 231 (1995) 528–532.
U. Ulmer, K. Asano, A. Patyk, H. Enoki, Y. Nakamur, A. Pohl, R. Dittmeyer, M. Fichtner, J. Alloy. Compd. 648 (2015) 1024–1030.
X.B. Yu, Z. Wu, F. Li, B.J. Xia, N.X. Xu, Appl. Phys. Lett. 84 (2004) 3199–3201.
X.B. Yu, Z. Wu, B.J. Xia, N.X. Xu, J. Alloy. Compd. 372 (2004) 272–277.
Y.G. Yan, Y.H. Chen, C.L. Wu, M.D. Tao, H. Liang, J. Power Sources 164 (2007) 799–802.
J. Mi, F. LÜ, X.P. Liu, L.J. Jiang, Z.N. Li, S.M. Wang, J. Rare Earth 28 (2010) 781–784.
J. Matsuda, E. Akiba, J. Alloy. Compd. 581 (2013) 369–372.
Z.W. Chen, X.Z. Xiao, L.X. Chen, X.L. Fan, L.X. Liu, S.Q. Li, H.W. Ge, Q.D. Wang, Int. J. Hydrogen Energy 38 (2013) 12803–12810.
Y.H. Zhang, Z.H. Hou, Y. Cai, H.W. Shang, Y. Qi, D.L. Zhao, J. Iron Steel Res. Int. 24 (2017) 296–305.
S. Suwarno, J.K. Solberg, J.P. Maehlen, B. Krogh, V.A. Yartys, Int. J. Hydrogen Energy 37 (2012) 7624–7628.
A. Kamegawa, T. Tamura, H. Takamura, M. Okada, J. Alloy. Compd. 356–357 (2003) 447–451.
X.P. Liu, L.J. Jiang, Z.N. Li, Z. Huang, S.M. Wang, J. Alloy. Compd. 471 (2009) L36–L38.
M. Okada, T. Kuriiwa, T. Tamura, H. Takamura, A. Kamegawa, J. Alloy. Compd. 330 (2002) 511–516.
S. Cho, G. Shim, G. Cho, C. Park, J. Yoo, J. Choi, J. Alloy. Compd. 430 (2007) 136–141.
M. Tsukahara, Mater. Trans. 52 (2011) 68–72.
Z.M. Hang, X.Z. Xiao, S.Q. Li, H.W. Ge, C.P. Chen, L.X. Chen, J. Alloy. Compd. 529 (2012) 128–133.
Y.F. Zhu, H.G. Pan, M.X. Gao, Y.F. Liu, Q.D. Wang, J. Alloy. Compd. 348 (2003) 301–308.
M.H. Rong, F. Wang, J. Wang, Z.M. Wang, H.Y. Zhou, Prog. Nat. Sci. 27 (2017) 543–549.
E. Akiba, H. Iba, Intermetallics 6 (1998) 461–470.
Y.G. Yan, Y.G. Chen, X.X. Zhou, H. Liang, C.L. Wu, M.D. Tao, J. Alloy. Compd. 453 (2008) 428–432.
Y.G. Yan, Y.G. Chen, H. Liang, X.X. Zhou, C.L. Wu, M.D. Tao, L.J. Pang, J. Alloy. Compd. 454 (2008) 427–431.
J.Y. Wang, R.R. Jeng, J.K. Nieh, S.Y. Lee, S.L. Lee, H.Y. Bor, Int. J. Hydrogen Energy 32 (2007) 3959–3964.
Y. Nakamura, K. Oikawa, T. Kamiyama, E. Akiba, J. Alloy. Comp. 316 (2001) 284–289.
N. Endo, I. Saita, Y. Nakamura, H. Saitoh, A. Machida, Int. J. Hydrogen Energy 40 (2015) 3283–3287.
H.Y. Leng, Z.G. Yu, J. Yin, Q. Li, Z. Wu, K.C. Chou, Int. J. Hydrogen Energy 42 (2017) 23731–23736.
P. Lv, J. Huot, Energy 138 (2017) 375–382.
Y.P. Pang, Q. Li, Int. J. Hydrogen Energy 41 (2016) 18072–18087.
B.K. Singh, S.W. Cho, K.S. Bartwal, Int. J. Hydrogen Energy 39 (2014) 8351–8356.
P. Pei, X.P. Song, J. Liu, G.L. Chen, X.B. Qin, B.Y. Wang, Int. J. Hydrogen Energy 34 (2009) 8094–8100.
H.Y. Zhou, F. Wang, J. Wang, Z.M. Wang, Q.R. Yao, J.Q. Deng, C.Y. Tang, G.H. Rao, Int. J. Hydrogen Energy 39 (2014) 14887–14895.
E.D. Wu, W.H. Li, J. Li, Int. J. Hydrogen Energy 37 (2012) 1509–1517.
T.D. Wu, X.Y. Xue, T.B. Zhang, R. Hu, H.C. Kou, J.S. Li, J. Alloy. Compd. 645 (2015) 358–368.
H.E. Kissinger, Anal. Chem. 29 (1957) 1702–1706.
Acknowledgements
This study was funded by the National Natural Science Foundation of China (Grant No. 51901105) and Natural Science Foundation of Inner Mongolia, China (Grant Nos. 2018LH05010, 2019BS05005, and 2017BS0507).
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Luo, L., Bian, X., Wu, Wy. et al. Influence of annealing on microstructure and hydrogen storage properties of V48Fe12Ti15Cr25 alloy. J. Iron Steel Res. Int. 27, 217–227 (2020). https://doi.org/10.1007/s42243-019-00337-4
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s42243-019-00337-4