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Surface post-functionalization of COFs by economical strategy via multiple-component one-pot tandem reactions and their application in adsorption of pesticides

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Abstract

The economical and convenient one-pot approach plays a substantial role in chemical synthesis and material design. However, the related reports on the synthesis and functionalization of covalent organic frameworks (COFs) by the one-pot approach are limited. Herein, we selectively introduced three different functional groups (fluoroalkyl, borate, and alkyl groups) to verify that the multi-component one-pot tandem reaction could be applied into surface post-functionalization of COFs as an economical strategy. After proving the practicability of the economical strategy, we also prepared two kinds of fluorine-containing COFs (COF-F0.5 and COF-F) and butyl-containing COF (COF-Bu) via the economical strategy to explore the effect of COF nature (porosity and the number of functional groups) on fipronil adsorption. The results showed that COF-F0.5 possessing the largest Brunauer–Emmett–Teller (BET) specific surface area (1573 m2 g−1) exhibited a larger saturated adsorption capacity (194.7 mg g−1) than COF-F (149.8 mg g−1). Furthermore, comparing with COF-Bu (122.4 mg g−1), COF-F (149.8 mg g−1) containing functional groups showed a greater adsorption capacity.

Graphical abstract

Post-functionalization of covalent organic frameworks by multiple-component one-pot tandem reactions was reported and the related application in the adsorption of pesticides was also studied.

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Funding

This work was supported by the Hainan Science and Technology Major Project (ZDKJ2019013), the National Natural Science Foundation of China (52063014, 51873053, 51775152, 61761016, and U1967213), the National Key R&D program of China (2019YFC1904304 and 2018YFE0103500), and the Fundamental Research Funds for the Central Universities (2020YQHH01). Ning Yuan also received funding from the Foundation of State Key Laboratory of Structural Chemistry (20190003).

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Author notes

  1. Shunli Wang and Ning Yuan contributed equally.

Authors and Affiliations

  1. State Key Laboratory of Marine Resource Utilization in South China Sea, Hainan University, Haikou, 570228, China

    Shunli Wang, Tingting Dai, Zhaosen Chang, Ying Liang, Xin Liu, Qi Chen & Ning Wang

  2. School of Life Science, Shaoxing University, Shaoxing, 312000, China

    Shunli Wang & Baowei Hu

  3. School of Chemical and Environmental Engineering, China University of Mining and Technology, Beijing, 100083, China

    Ning Yuan

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  1. Shunli Wang
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Correspondence to Qi Chen.

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Wang, S., Yuan, N., Dai, T. et al. Surface post-functionalization of COFs by economical strategy via multiple-component one-pot tandem reactions and their application in adsorption of pesticides. Adv Compos Hybrid Mater 5, 1439–1449 (2022). https://doi.org/10.1007/s42114-021-00241-0

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