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Dealloyed nanoporous materials for rechargeable lithium batteries

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Abstract

Dealloying has been recognized as a universal strategy to fabricate various functional electrode materials with open networks, nanoscale ligaments, tunable pore sizes and rich surface chemistry, all of which are very attractive characteristics for rechargeable lithium batteries. In particular, lithium ion insertion/extraction in metal anodes is naturally associated with the alloying/dealloying mechanism. The past decade has witnessed rapid growth of this research field with enormous progress. In this review article, we first summarize the recent development and microstructural regulation of dealloyed materials. Next, we focus on the rational design of nanoporous electrodes for rechargeable lithium batteries and related structure-performance correlations. Finally, some critical issues and perspectives are presented to guide the future development directions of such promising technology for high-energy batteries.

Graphic abstract

This review systematically summarizes the recent progress of dealloyed nanoporous materials and their application in rechargeable lithium batteries.

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Acknowledgements

This work was supported by the National Key Research and Development Program of China (2019YFA0205700), the National Natural Science Foundation of China (51602219, 51671145), the National Science Fund for Distinguished Young Scholars (51825102), the joint research fund of NSFC (51761165012) and the Macau Science and Technology Fund (FDCT, 002/2017/AFJ), and the Tianjin Municipal Science and Technology Commission (17JCYBJC42000). X.W. and G.H. contributed equally to this work.

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  1. Tianjin Key Laboratory of Advanced Functional Porous Materials, Institute for New Energy Materials and Low-Carbon Technologies, School of Materials Science and Engineering, Tianjin University of Technology, Tianjin, 300384, China

    Xuan Wu, Guang He & Yi Ding

  2. State Key Laboratory of Quality Research in Chinese Medicines, Macau University of Science and Technology, Taipa, Macau, China

    Xuan Wu

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Wu, X., He, G. & Ding, Y. Dealloyed nanoporous materials for rechargeable lithium batteries. Electrochem. Energ. Rev. 3, 541–580 (2020). https://doi.org/10.1007/s41918-020-00070-7

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