Abstract
Lithium-ion batteries (LIBs) are currently the most suitable energy storage device for powering electric vehicles (EVs) owing to their attractive properties including high energy efficiency, lack of memory effect, long cycle life, high energy density and high power density. These advantages allow them to be smaller and lighter than other conventional rechargeable batteries such as lead–acid batteries, nickel–cadmium batteries (Ni–Cd) and nickel–metal hydride batteries (Ni–MH). Modern EVs, however, still suffer from performance barriers (range, charging rate, lifetime, etc.) and technological barriers (high cost, safety, reliability, etc.), limiting their widespread adoption. Given these facts, this review sets the extensive market penetration of LIB-powered EVs as an ultimate objective and then discusses recent advances and challenges of electric automobiles, mainly focusing on critical element resources, present and future EV markets, and the cost and performance of LIBs. Finally, novel battery chemistries and technologies including high-energy electrode materials and all-solid-state batteries are also evaluated for their potential capabilities in next-generation long-range EVs.
Graphical Abstract
Similar content being viewed by others
References
Global EV outlook 2017, International Energy Agency, https://www.iea.org/publications/freepublications/publication/GlobalEVOutlook2017.pdf (2017). Accessed 1 Oct 2018
Bellis, M.: A history of electric vehicles. https://www.thoughtco.com/history-of-electric-vehicles-1991603 (2017). Accessed 1 Oct 2018
Kurzweil, P.: Gaston Planté and his invention of the lead–acid battery—The genesis of the first practical rechargeable battery. J. Power Sources 195, 4424–4434 (2010). https://doi.org/10.1016/j.jpowsour.2009.12.126
Bryan, F.R.: The Birth of Ford Motor Company, Henry Ford Heritage Association. http://www.hfha.org (2012). Accessed 20 Aug 2012
Crawford, M.: Back to the energy crisis; waning US oil output, rising imports, and Middle East tensions are reheating energy policy debates of the 1970s. Science 235, 626–628 (1987)
Hondroyiannis, G., Lolos, S., Papapetrou, E.: Energy consumption and economic growth: assessing the evidence from Greece. Energy Econ. 24, 319–336 (2002)
Chan, C.: The state of the art of electric and hybrid vehicles. Proc. IEEE 90, 247–275 (2002)
Eberle, U., Von Helmolt, R.: Sustainable transportation based on electric vehicle concepts: a brief overview. Energy Environ. Sci. 3, 689–699 (2010)
Gifford, P., Adams, J., Corrigan, D., et al.: Development of advanced nickel/metal hydride batteries for electric and hybrid vehicles. J. Power Sources 80, 157–163 (1999)
Knosp, B., Jordy, C., Blanchard, P., et al.: Evaluation of Zr (Ni, Mn)2 laves phase alloys as negative active material for Ni–MH electric vehicle batteries. J. Electrochem. Soc. 145, 1478–1482 (1998)
Nishi, Y.: Lithium ion secondary batteries; past 10 years and the future. J. Power Sources 100, 101–106 (2001)
Armand, M., Tarascon, J.M.: Building better batteries. Nature 451, 652–657 (2008)
Thackeray, M.M., Wolverton, C., Isaacs, E.D.: Electrical energy storage for transportation—approaching the limits of, and going beyond, lithium-ion batteries. Energy Environ. Sci. 5, 7854–7863 (2012)
Cano, Z.P., Banham, D., Ye, S., et al.: Batteries and fuel cells for emerging electric vehicle markets. Nat. Energy 3, 279–289 (2018)
Etacheri, V., Marom, R., Elazari, R., et al.: Challenges in the development of advanced Li-ion batteries: a review. Energy Environ. Sci. 4, 3243–3262 (2011)
Scrosati, B., Garche, J.: Lithium batteries: status, prospects and future. J. Power Sources 195, 2419–2430 (2010)
Rogelj, J., Den Elzen, M., Höhne, N., et al.: Paris Agreement climate proposals need a boost to keep warming well below 2 °C. Nature 534, 631–639 (2016)
Hulme, M.: 1.5 °C and climate research after the Paris Agreement. Nat. Clim. Change 6, 222–224 (2016)
Dimitrov, R.S.: The Paris agreement on climate change: behind closed doors. Glob. Environ. Polit. 16, 1–11 (2016)
Franke, T., Krems, J.F.: What drives range preferences in electric vehicle users? Transp. Policy 30, 56–62 (2013)
Neubauer, J., Brooker, A., Wood, E.: Sensitivity of battery electric vehicle economics to drive patterns, vehicle range, and charge strategies. J. Power Sources 209, 269–277 (2012)
Botsford, C., Szczepanek, A.: Fast charging vs. slow charging: pros and cons for the new age of electric vehicles. In: International Battery Hybrid Fuel Cell Electric Vehicle Symposium, Stavanger, Norway, May 13–16, 2019
Lam, L., Louey, R.: Development of ultra-battery for hybrid-electric vehicle applications. J. Power Sources 158, 1140–1148 (2006)
Nykvist, B., Nilsson, M.: Rapidly falling costs of battery packs for electric vehicles. Nat. Clim. Change 5, 329–332 (2015)
Schmidt, O., Hawkes, A., Gambhir, A., et al.: The future cost of electrical energy storage based on experience rates. Nat. Energy 2, 17110 (2017)
Stephan, A., Battke, B., Beuse, M., et al.: Limiting the public cost of stationary battery deployment by combining applications. Nat. Energy 1, 16079 (2016)
Rezvanizaniani, S.M., Liu, Z., Chen, Y., et al.: Review and recent advances in battery health monitoring and prognostics technologies for electric vehicle (EV) safety and mobility. J. Power Sources 256, 110–124 (2014)
Quinn, C., Zimmerle, D., Bradley, T.H.: The effect of communication architecture on the availability, reliability, and economics of plug-in hybrid electric vehicle-to-grid ancillary services. J. Power Sources 195, 1500–1509 (2010)
Yilmaz, M., Krein, P.T.: Review of battery charger topologies, charging power levels, and infrastructure for plug-in electric and hybrid vehicles. IEEE Trans. Power Electron. 28, 2151–2169 (2013)
Morrow, K., Karner, D., Francfort, J.: Plug-in hybrid electric vehicle charging infrastructure review. Idaho National Laboratory, Idaho Falls (2008)
San Román, T.G., Momber, I., Abbad, M.R., et al.: Regulatory framework and business models for charging plug-in electric vehicles: infrastructure, agents, and commercial relationships. Energy Policy 39, 6360–6375 (2011)
Liu, P., Ross, R., Newman, A.: Long-range, low-cost electric vehicles enabled by robust energy storage. MRS Energy Sustain.-A Rev. J. 2, E12 (2015)
Diamond, D.: The impact of government incentives for hybrid-electric vehicles: evidence from US states. Energy Policy 37, 972–983 (2009)
Egbue, O., Long, S.: Barriers to widespread adoption of electric vehicles: an analysis of consumer attitudes and perceptions. Energy Policy 48, 717–729 (2012)
Indiana, E.: President Obama announces $2.4 billion in grants to accelerate the manufacturing and deployment of the next generation of U.S. batteries and electric vehicles. https://energy.gov/articles/president-obama-announces-24-billion-grants-accelerate-manufacturing-and-deployment-next (2009). Accessed 1 Oct 2018
European Commission: Press release database. http://europa.eu/rapid/press-release_MEX-17-2124_en.htm?locale=en (2017). Accessed 1 Oct 2018
Shirouzu, N.: China spooks auto makers. http://users.cla.umn.edu/~erm/data/sr486/newspaper/wsj091610.pdf (2010). Accessed 1 Oct 2018
Bradsher, K.: China leads the way toward an electric-car future. https://www.thestar.com/business/2017/10/13/china-leads-the-way-toward-an-electric-car-future.html (2017). Accessed 1 Oct 2018
Yue, P.: China’s electric vehicle charger market to reach $29B In 2020. https://www.chinamoneynetwork.com/2017/01/24/chinas-electric-vehicle-charger-market-to-reach-29b-in-2020 (2017). Accessed 1 Oct 2018
Thakkar, K.: ‘Electric is the future’ for German car majors with 50 billion euros investments. https://www.gadgetsnow.com/tech-news/electric-is-the-future-for-german-car-majors-with-50-billion-euros-investments/articleshow/60707742.cms (2017). Accessed 1 Oct 2018
Block, D., Brooker, P.: 2015 electric vehicle market summary and barriers. In: FSEC-CR-2027-16, Cocoa, FL, Florida Solar Energy Center (2016)
Loveday, S.: Elon musk says gigafactory output could Soar To 150 GWh annually. https://insideevs.com/elon-musk-says-gigafactory-output-could-soar-to-150-gwh-annually/ (2016). Accessed 1 Oct 2018
Lambert, F.: Tesla is now claiming 35% battery cost reduction at ‘Gigafactory 1’—hinting at breakthrough cost below $125/kWh. https://electrek.co/2017/02/18/tesla-battery-cost-gigafactory-model-3/ (2017). Accessed 1 Oct 2018
Zhang, S., Ueno, K., Dokko, K., et al.: Recent advances in electrolytes for lithium–sulfur batteries. Adv. Energy Mater. 5, 1500117 (2015)
Pillot, C.: The rechargeable battery market and main trends 2016–2025. In: BATTERIES 2017, Nice, France (2017)
Zubi, G., Dufo-López, R., Carvalho, M., et al.: The lithium-ion battery: state of the art and future perspectives. Renew. Sustain. Energy Rev. 89, 292–308 (2018)
Wikipedia: Plug-in electric vehicles in the United Kingdom. https://en.wikipedia.org/wiki/Plug-in_electric_vehicles_in_the_United_Kingdom (2018). Accessed 1 Oct 2018
Shahan, Z.: Electric vehicle market share in 19 countries, https://www.abb-conversations.com/2014/03/electric-vehicle-market-share-in-19-countries/ (2014). Accessed 1 Oct 2018
Navigant Research: Homepage. https://www.navigantresearch.com/newsroom/the-market-for-lithium-ion-batteries-for-vehicles-is-expected-to-reach-30-6-billion-in-2024 (2018). Accessed 1 Oct 2018
The Guardian: Electric cars to account for all new vehicle sales in Europe by 2035. https://www.theguardian.com/environment/2017/jul/13/electric-cars-to-account-for-all-new-vehicle-sales-in-europe-by-2035 (2017). Accessed 1 Oct 2018
McCrone, A., Moslener, U., D’Estais, F., et al.: Global trends in renewable energy investment 2016. Frankfurt School-UNEP Centre/Bloomberg New Energy Finance (2016)
Mills, L., Louw, A.: Global trends in clean energy investment. Bloomberg New Energy Finance (2016)
Tesla: Planned 2020 Gigafactory production exceeds 2013 global production. https://www.tesla.com/sites/default/files/blog_attachments/gigafactory.pdf (2016). Accessed 1 Oct 2018
Dow, J.: Tesla christens Buffalo solar factory ‘Gigafactory 2’, will finalize locations of Gigafactory 3, 4 and possibly 5. https://electrek.co/2017/02/22/tesla-christens-buffalo-solar-factory-gigafactory-2-will-finalize-locations-of-gigafactory-3-4-and-possibly-5-this-year/ (2017). Accessed Jun 24 2018
Jain, S.: Emerging trends in battery technology. Auto Tech Rev. 6, 52–55 (2017). https://doi.org/10.1365/s40112-017-1278-0
Televisory: Electric vehicles revolution, China leads the global boom. https://benchmark.televisory.com/blogs/-/blogs/electric-vehicles-revolution-china-leads-the-global-boom (2017). Accessed 1 Oct 2018
Olivetti, E.A., Ceder, G., Gaustad, G.G., et al.: Lithium-ion battery supply chain considerations: analysis of potential bottlenecks in critical metals. Joule 1, 229–243 (2017)
Gruber, P.W., Medina, P.A., Keoleian, G.A., et al.: Global lithium availability. J. Ind. Ecol. 15, 760–775 (2011)
Forster, J.: A lithium shortage: are electric vehicles under threat? Swiss Federal Institute of Technology Zurich. http://www.files.ethz.ch/cepe/Top10/Forster.pdf (2011). Accessed 1 Oct 2018
Ebensperger, A., Maxwell, P., Moscoso, C.: The lithium industry: its recent evolution and future prospects. Resources Policy 30, 218–231 (2005)
Desjardins, J.: Lithium: the future of the green revolution. http://www.visualcapitalist.com/lithium-fuel-green-revolution/ (2017). Accessed 1 Oct 2018
Vaalma, C., Buchholz, D., Weil, M., et al.: A cost and resource analysis of sodium-ion batteries. Nat. Rev. Mater. 3, 18013 (2018)
Liu, P., Liang, K., Gu, S.: High-temperature oxidation behavior of aluminide coatings on a new cobalt-base superalloy in air. Corros. Sci. 43, 1217–1226 (2001)
Small, B.L., Brookhart, M., Bennett, A.M.: Highly active iron and cobalt catalysts for the polymerization of ethylene. J. Am. Chem. Soc. 120, 4049–4050 (1998)
Lu, X.B., Darensbourg, D.J.: Cobalt catalysts for the coupling of CO2 and epoxides to provide polycarbonates and cyclic carbonates. Chem. Soc. Rev. 41, 1462–1484 (2012)
Murrie, M., Teat, S.J., Stœckli-Evans, H., et al.: Synthesis and characterization of a cobalt (II) single-molecule magnet. Angew. Chem. Int. Ed. 42, 4653–4656 (2003)
Lebedeva, N., Di Persio, F., Boon-Brett, L.: Lithium ion battery value chain and related opportunities for Europe. JRC Science for policy report (2016)
Cho, J.: Dependence of AlPO4 coating thickness on overcharge behaviour of LiCoO2 cathode material at 1 and 2 C rates. J. Power Sources 126, 186–189 (2004)
Janek, J., Zeier, W.G.: A solid future for battery development. Nat. Energy 1, 16141 (2016). https://doi.org/10.1038/nenergy.2016.141
Padhi, A.K., Nanjundaswamy, K.S., Goodenough, J.B.: Phospho-olivines as positive-electrode materials for rechargeable lithium batteries. J. Electrochem. Soc. 144, 1188–1194 (1997)
Chung, S.Y., Bloking, J.T., Chiang, Y.M.: Electronically conductive phospho-olivines as lithium storage electrodes. Nat. Mater. 1, 123 (2002). https://doi.org/10.1038/nmat732
Wagemaker, M., Ellis, B.L., Lützenkirchen-Hecht, D., et al.: Proof of supervalent doping in olivine LiFePO4. Chem. Mater. 20, 6313–6315 (2008). https://doi.org/10.1021/cm801781k
Sun, C., Rajasekhara, S., Goodenough, J.B., et al.: Monodisperse porous LiFePO4 Microspheres for a high power Li-ion battery cathode. J. Am. Chem. Soc. 133, 2132–2135 (2011). https://doi.org/10.1021/ja1110464
Ravnsbæk, D.B., Xiang, K., Xing, W., et al.: Extended solid solutions and coherent transformations in nanoscale olivine cathodes. Nano Lett. 14, 1484–1491 (2014)
Shin, H.C., Cho, W.I., Jang, H.: Electrochemical properties of carbon-coated LiFePO4 cathode using graphite, carbon black, and acetylene black. Electrochim. Acta 52, 1472–1476 (2006)
Andre, D., Kim, S.J., Lamp, P., et al.: Future generations of cathode materials: an automotive industry perspective. J. Mater. Chem. A 3, 6709–6732 (2015). https://doi.org/10.1039/c5ta00361j
Ma, Z., Zou, S., Liu, X.: A distributed charging coordination for large-scale plug-in electric vehicles considering battery degradation cost. IEEE Trans. Control Syst. Technol. 23, 2044–2052 (2015)
Wang, J.G., Yang, J. (eds.): The power of batteries: the story of BYD. In: Who Gets Funds from China’s Capital Market? pp. 7–18. Springer, Berlin (2013)
Srinivasan, V., Newman, J.: Discharge model for the lithium iron-phosphate electrode. J. Electrochem. Soc. 151, A1517–A1529 (2004)
Wu, J., Dathar, G.K.P., Sun, C., et al.: In situ Raman spectroscopy of LiFePO4: size and morphology dependence during charge and self-discharge. Nanotechnology 24, 424009 (2013)
Schmuch, R., Wagner, R., Hörpel, G., et al.: Performance and cost of materials for lithium-based rechargeable automotive batteries. Nat. Energy 3, 267 (2018)
Lu, L., Han, X., Li, J., et al.: A review on the key issues for lithium-ion battery management in electric vehicles. J. Power Sources 226, 272–288 (2013)
Blomgren, G.E.: The development and future of lithium ion batteries. J. Electrochem. Soc. 164, A5019–A5025 (2017)
Thackeray, M., David, W., Bruce, P., et al.: Lithium insertion into manganese spinels. Mater. Res. Bull. 18, 461–472 (1983)
Cho, J., Kim, T.J., Kim, Y.J., et al.: Complete blocking of Mn3+ ion dissolution from a LiMn2O4 spinel intercalation compound by Co3O4 coating. Chem. Commun. (12), 1704–1705 (2001). https://doi.org/10.1039/b101677f
Ding, Y.L., Xie, J., Cao, G.S., et al.: Single-crystalline LiMn2O4 nanotubes synthesized via template-engaged reaction as cathodes for high-power lithium ion batteries. Adv. Func. Mater. 21, 348–355 (2011). https://doi.org/10.1002/adfm.201001448
Wu, S.H., Lee, P.H.: Storage fading of a commercial 18650 cell comprised with NMC/LMO cathode and graphite anode. J. Power Sources 349, 27–36 (2017)
Arai, H., Okada, S., Sakurai, Y., et al.: Reversibility of LiNiO2 cathode. Solid State Ionics 95, 275–282 (1997). https://doi.org/10.1016/S0167-2738(96)00598-X
Ohzuku, T., Ueda, A., Nagayama, M., et al.: Comparative study of LiCoO2, LiNi12Co12O2 and LiNiO2 for 4 volt secondary lithium cells. Electrochim. Acta 38, 1159–1167 (1993). https://doi.org/10.1016/0013-4686(93)80046-3
Nohma, T., Kurokawa, H., Uehara, M., et al.: Electrochemical characteristics of LiNiO2 and LiCoO2 as a positive material for lithium secondary batteries. J. Power Sources 54, 522–524 (1995). https://doi.org/10.1016/0378-7753(94)02140-X
Liu, Z., Zhen, H., Kim, Y., et al.: Synthesis of LiNiO2 cathode materials with homogeneous Al doping at the atomic level. J. Power Sources 196, 10201–10206 (2011). https://doi.org/10.1016/j.jpowsour.2011.08.059
Hwang, B.J., Santhanam, R., Chen, C.H.: Effect of synthesis conditions on electrochemical properties of LiNi1−yCoyO2 cathode for lithium rechargeable batteries. J. Power Sources 114, 244–252 (2003). https://doi.org/10.1016/S0378-7753(02)00584-0
Liu, Z., Yu, A., Lee, J.Y.: Synthesis and characterization of LiNi1−x−y CoxMnyO2 as the cathode materials of secondary lithium batteries. J. Power Sources 81–82, 416–419 (1999). https://doi.org/10.1016/S0378-7753(99)00221-9
Ohzuku, T., Ueda, A., Kouguchi, M.: Synthesis and Characterization of LiAl1/4Ni3/4O2 (R 3̄m) for lithium-ion (Shuttlecock) batteries. J. Electrochem. Soc. 142, 4033–4039 (1995). https://doi.org/10.1149/1.2048458
Aydinol, M.K., Kohan, A.F., Ceder, G.: Ab initio calculation of the intercalation voltage of lithium-transition-metal oxide electrodes for rechargeable batteries. J. Power Sources 68, 664–668 (1997). https://doi.org/10.1016/S0378-7753(96)02638-9
Ceder, G., Chiang, Y.M., Sadoway, D.R., et al.: Identification of cathode materials for lithium batteries guided by first-principles calculations. Nature 392, 694–696 (1998). https://doi.org/10.1038/33647
Delmas, C., Saadoune, I., Rougier, A.: The cycling properties of the LixNi1−yCoyO2 electrode. J. Power Sources 44, 595–602 (1993). https://doi.org/10.1016/0378-7753(93)80208-7
Ueda, A., Ohzuku, T.: Solid-state redox reactions of LiNi1/2Co1/2O2 (R 3̄m) for 4 volt secondary lithium cells. J. Electrochem. Soc. 141, 2010–2014 (1994). https://doi.org/10.1149/1.2055051
Lee, K.K., Yoon, W.S., Kim, K.B., et al.: Characterization of LiNi0.85Co0.10M0.05O2 (M = Al, Fe) as a cathode material for lithium secondary batteries. J. Power Sources 97–98, 308–312 (2001). https://doi.org/10.1016/S0378-7753(01)00516-X
Jo, M., Noh, M., Oh, P., et al.: A new high power LiNi0.81Co0.1Al0.09O2 cathode material for lithium-ion batteries. Adv. Energy Mater. 4, 1301583 (2014). https://doi.org/10.1002/aenm.201301583
Myung, S.T., Maglia, F., Park, K.J., et al.: Nickel-rich layered cathode materials for automotive lithium-ion batteries: achievements and perspectives. ACS Energy Lett. 2, 196–223 (2017). https://doi.org/10.1021/acsenergylett.6b00594
Choi, J., Manthiram, A.: Role of chemical and structural stabilities on the electrochemical properties of layered LiNi1/3Mn1/3Co1/3O2 cathodes. J. Electrochem. Soc. 152, A1714–A1718 (2005). https://doi.org/10.1149/1.1954927
An, S.J., Li, J., Mohanty, D., et al.: Correlation of electrolyte volume and electrochemical performance in lithium-ion pouch cells with graphite anodes and NMC532 cathodes. J. Electrochem. Soc. 164, A1195–A1202 (2017). https://doi.org/10.1149/2.1131706jes
Kim, J.H., Myung, S.T., Yoon, C.S., et al.: Comparative study of LiNi0.5Mn1.5O4-δ and LiNi0.5Mn1.5O4 cathodes having two crystallographic structures: Fd3̄m and P4332. Chem. Mater. 16, 906–914 (2004). https://doi.org/10.1021/cm035050s
Kunduraci, M., Al-Sharab, J.F., Amatucci, G.G.: High-power nanostructured LiMn2-xNixO4 high-voltage lithium-ion battery electrode materials: electrochemical impact of electronic conductivity and morphology. Chem. Mater. 18, 3585–3592 (2006). https://doi.org/10.1021/cm060729s
Lu, D., Xu, M., Zhou, L., et al.: Failure mechanism of graphite/LiNi0.5Mn1.5O4 cells at high voltage and elevated temperature. J. Electrochem. Soc. 160, A3138–A3143 (2013). https://doi.org/10.1149/2.022305jes
Thackeray, M.M., Kang, S.H., Johnson, C.S., et al.: Li2MnO3-stabilized LiMO2 (M = Mn, Ni, Co) electrodes for lithium-ion batteries. J. Mater. Chem. 17, 3112–3125 (2007). https://doi.org/10.1039/b702425h
Lu, Z., MacNeil, D.D., Dahn, J.R.: Layered cathode materials Li [NixLi(1/3–2x/3) Mn(2/3−x/3)] O2 for lithium-ion batteries. Electrochem. Solid-State Lett. 4, A191–A194 (2001). https://doi.org/10.1149/1.1407994
Nayak, P.K., Grinblat, J., Levi, M., et al.: Structural and electrochemical evidence of layered to spinel phase transformation of Li and Mn rich layered cathode materials of the formulae xLi[Li1/3Mn2/3]O2. (1−x)LiMn1/3Ni1/3Co1/3O2 (x = 0.2, 0.4, 0.6) upon cycling. J. Electrochem. Soc. 161, A1534–A1547 (2014). https://doi.org/10.1149/2.0101410jes
Manthiram, A., Song, B., Li, W.: A perspective on nickel-rich layered oxide cathodes for lithium-ion batteries. Energy Storage Mater. 6, 125–139 (2017). https://doi.org/10.1016/j.ensm.2016.10.007
Noh, H.J., Youn, S., Yoon, C.S., et al.: Comparison of the structural and electrochemical properties of layered Li [NixCoyMnz] O2 (x = 1/3, 0.5, 0.6, 0.7, 0.8 and 0.85) cathode material for lithium-ion batteries. J. Power Sources 233, 121–130 (2013)
Abraham, D., Roth, E., Kostecki, R., et al.: Diagnostic examination of thermally abused high-power lithium-ion cells. J. Power Sources 161, 648–657 (2006)
Myung, S.T., Maglia, F., Park, K.J., et al.: Nickel-rich layered cathode materials for automotive lithium-ion batteries: achievements and perspectives. ACS Energy Lett. 2, 196–223 (2016)
Lim, B.B., Myung, S.T., Yoon, C.S., et al.: Comparative study of Ni-rich layered cathodes for rechargeable lithium batteries: Li[Ni0. 85Co0.11Al0.04] O2 and Li[Ni0.84Co0. 06Mn0.09Al0.01] O2 with two-step full concentration gradients. ACS Energy Lett. 1, 283–289 (2016)
Noh, H.J., Youn, S., Yoon, C.S., et al.: Comparison of the structural and electrochemical properties of layered Li[NixCoyMnz]O2 (x = 1/3, 0.5, 0.6, 0.7, 0.8 and 0.85) cathode material for lithium-ion batteries. J. Power Sources 233, 121–130 (2013). https://doi.org/10.1016/j.jpowsour.2013.01.063
InvestmentMine: Cobalt investing - cobalt stocks, mining companies, prices and news. http://www.infomine.com/investment/cobalt/ (2017). Accessed 1 Oct 2018
Ma, L., Nie, M., Xia, J., et al.: A systematic study on the reactivity of different grades of charged Li[NixMnyCoz]O2 with electrolyte at elevated temperatures using accelerating rate calorimetry. J. Power Sources 327, 145–150 (2016). https://doi.org/10.1016/j.jpowsour.2016.07.039
Sun, Y.K., Myung, S.T., Kim, M.H., et al.: Synthesis and characterization of Li[(Ni0.8Co0.1Mn0.1)0.8(Ni0.5Mn0.5)0.2]O2 with the microscale core − shell structure as the positive electrode material for lithium batteries. J. Am. Chem. Soc. 127, 13411–13418 (2005). https://doi.org/10.1021/ja053675g
Sun, Y.K., Myung, S.T., Park, B.C., et al.: High-energy cathode material for long-life and safe lithium batteries. Nat. Mater. 8, 320–324 (2009). https://doi.org/10.1038/nmat2418. https://www.nature.com/articles/nmat2418#supplementary-information
Wang, Y.Q., Gu, L., Guo, Y.G., et al.: Rutile-TiO2 nanocoating for a high-rate Li4Ti5O12 anode of a lithium-ion battery. J. Am. Chem. Soc. 134, 7874–7879 (2012)
Jung, H.G., Jang, M.W., Hassoun, J., et al.: A high-rate long-life Li4Ti5O12/Li[Ni0.45Co0.1Mn1.45] O4 lithium-ion battery. Nat. Commun. 2, 516 (2011)
Zaghib, K., Mauger, A., Julien, C.: Rechargeable lithium batteries for energy storage in smart grids. In: Owen, J.R. (ed.) Rechargeable Lithium Batteries, pp. 319–351. Elsevier, Amsterdam (2015)
Lu, J., Chen, Z., Ma, Z., et al.: The role of nanotechnology in the development of battery materials for electric vehicles. Nat. Nanotechnol. 11, 1031–1038 (2016)
Arrebola, J.C., Caballero, A., Cruz, M., et al.: Crystallinity control of a nanostructured LiNi0.5Mn1.5O4 spinel via polymer-assisted synthesis: a method for improving its rate capability and performance in 5 V lithium batteries. Adv. Func. Mater. 16, 1904–1912 (2006)
Cui, L.F., Yang, Y., Hsu, C.M., et al.: Carbon − silicon core − shell nanowires as high capacity electrode for lithium ion batteries. Nano Lett. 9, 3370–3374 (2009)
Ko, M., Chae, S., Ma, J., et al.: Scalable synthesis of silicon-nanolayer-embedded graphite for high-energy lithium-ion batteries. Nat. Energy 1, 16113 (2016)
Kamaya, N., Homma, K., Yamakawa, Y., et al.: A lithium superionic conductor. Nat. Mater. 10, 682–686 (2011). https://doi.org/10.1038/nmat3066. https://www.nature.com/articles/nmat3066#supplementary-information
Yang, C., Fu, K., Zhang, Y., et al.: Protected lithium-metal anodes in batteries: from liquid to solid. Adv. Mater. 29, 1701169 (2017). https://doi.org/10.1002/adma.201701169
Suzuki, N., Inaba, T., Shiga, T.: Electrochemical properties of LiPON films made from a mixed powder target of Li3PO4 and Li2O. Thin Solid Films 520, 1821–1825 (2012)
Manthiram, A., Yu, X., Wang, S.: Lithium battery chemistries enabled by solid-state electrolytes. Nat. Rev. Mater. 2, 16103 (2017)
Martinez-Juarez, A., Pecharromán, C., Iglesias, J.E., et al.: Relationship between activation energy and bottleneck size for Li+ ion conduction in NASICON materials of composition LiMM ‘(PO4)3; M, M ‘= Ge, Ti, Sn, Hf. J. Phys. Chem. B 102, 372–375 (1998)
Itoh, M., Inaguma, Y., Jung, W.H., et al.: High lithium ion conductivity in the perovskite-type compounds Ln12Li12TiO3 (Ln = La, Pr, Nd, Sm). Solid State Ionics 70, 203–207 (1994)
Thangadurai, V., Weppner, W.: Li6ALa2Ta2O12 (A = Sr, Ba): novel garnet-like oxides for fast lithium ion conduction. Adv. Func. Mater. 15, 107–112 (2005)
Liu, Z., Fu, W., Payzant, E.A., et al.: Anomalous high ionic conductivity of nanoporous β-Li3PS4. J. Am. Chem. Soc. 135, 975–978 (2013)
Boulineau, S., Courty, M., Tarascon, J.M., et al.: Mechanochemical synthesis of Li-argyrodite Li6PS5 X (X = Cl, Br, I) as sulfur-based solid electrolytes for all solid state batteries application. Solid State Ionics 221, 1–5 (2012)
Kong, S.T., Deiseroth, H.J., Maier, J., et al.: Li6PO5Br and Li6PO5Cl: the first lithium-oxide-argyrodites. Zeitschrift für Anorganische und Allgemeine Chemie 636, 1920–1924 (2010)
Kato, Y., Hori, S., Saito, T., et al.: High-power all-solid-state batteries using sulfide superionic conductors. Nat. Energy 1, 16030 (2016). https://doi.org/10.1038/nenergy.2016.30. https://www.nature.com/articles/nenergy201630#supplementary-information
Lin, D., Liu, Y., Cui, Y.: Reviving the lithium metal anode for high-energy batteries. Nat. Nanotechnol. 12, 194 (2017)
Thangadurai, V., Narayanan, S., Pinzaru, D.: Garnet-type solid-state fast Li ion conductors for Li batteries: critical review. Chem. Soc. Rev. 43, 4714–4727 (2014). https://doi.org/10.1039/c4cs00020j
Zhang, Z., Zhao, Y., Chen, S., et al.: An advanced construction strategy of all-solid-state lithium batteries with excellent interfacial compatibility and ultralong cycle life. J. Mater. Chem. A 5, 16984–16993 (2017). https://doi.org/10.1039/c7ta04320a
Acknowledgements
The authors greatly appreciate the financial support from the Natural Sciences and Engineering Research Council of Canada (NSERC), the University of Waterloo and the Waterloo Institute of Nanotechnology. J. Lu gratefully acknowledges support from the U. S. Department of Energy (DOE), Office of Energy Efficiency and Renewable Energy, Vehicle Technologies Office. Argonne National Laboratory is operated for DOE Office of Science by UChicago Argonne, LLC, under contract number DE-AC02-06CH11357.
Author information
Authors and Affiliations
Corresponding authors
Rights and permissions
About this article
Cite this article
Ding, Y., Cano, Z.P., Yu, A. et al. Automotive Li-Ion Batteries: Current Status and Future Perspectives. Electrochem. Energ. Rev. 2, 1–28 (2019). https://doi.org/10.1007/s41918-018-0022-z
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s41918-018-0022-z