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Influence of selenium dioxide (SeO2) on properties of bioglass in SiO2-Na2O-CaO-P2O5 system

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Abstract

The influence of selenium dioxide on bioglass in (45.0-x) SiO2 24.5Na2O 24.5CaO 6.0P2O5 xSeO2 (x = 0.0, 0.5, 1.0, 1.5, and 2.0 wt%) system was investigated by preparing the glass through conventional melting and annealing method. The glass transition temperature (Tg), crystallization temperature (Tc), and density of prepared glasses were measured by differential thermal analysis and Archimedes’ principle respectively. The structural and microstructure analyses of glasses were characterized by Raman spectroscopy, Fourier transformed infrared (FTIR) spectroscopy, and scanning electron microscopy (SEM) with energy dispersive X-ray analysis (EDX). The formation of hydroxy apatite carbonate (HCA) layer for glasses was investigated by Raman spectroscopy, FTIR, SEM with EDS, pH measurement, ion concentrations analysis, and (%) weight loss after immersion in simulated body fluid (SBF) for 10 h to 14 days at 37.5°C. Experimental results showed that SeO2 substitution for SiO2 in the glass had increased glass density and molar volume whereas network connectivity was decreased. The addition of selenium oxide reduced the glass transition temperature and also crystallization temperature. The FTIR study of glass confirmed the P–O bonding after immersion for 14 days in SBF, which was also identified in the Raman spectroscopy. SEM of the 14 days immersed sample showed the formation of cauliflower like morphology of HA particles on the glass. pH and ion concentrations analysis also confirmed the formation of HCA layer after 14 days of immersion in SBF.

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Acknowledgments

The authors thankfully acknowledge the Department of Ceramic Technology, Government College of Engineering and Ceramic Technology, Kolkata, India, for providing necessary facilities for the present research work.

Funding

This study was financially supported by the University Grants Commission (UGC) of Minor Research Project (File No. F.PSW-269/15-16 (ERO) DT19.01.2017). One of the authors (Ram Karan) would like to thank University Grants Commission (UGC) New Delhi, India, for financial support of Research Fellowship (UGC-RGNF, F1-17.1/2014-15/RGNF-2014-15-SC-RAJ-61456).

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Authors and Affiliations

  1. Department of Chemical Technology, University of Calcutta, 92, A. P. C. Road, Kolkata, 700 009, India

    Ram Karan, Priyabrata Manna & P. K. Maiti

  2. Department of Ceramic Technology, Government College of Engineering and Ceramic Technology, 73, Abinash Chandra Banerjee Lane, Kolkata, 700 010, India

    Kaberi Das

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  1. Ram Karan
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Correspondence to Ram Karan.

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Karan, R., Manna, P., Maiti, P.K. et al. Influence of selenium dioxide (SeO2) on properties of bioglass in SiO2-Na2O-CaO-P2O5 system. J Aust Ceram Soc 56, 1135–1145 (2020). https://doi.org/10.1007/s41779-020-00459-z

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