Abstract
The study investigates soil contamination by metal trace elements (MTEs) in areas impacted by wastewater discharge, emphasizing the importance of understanding both bioavailability and mobility for a comprehensive assessment. Three soil samples, corresponding to different distances from wastewater entry points into a lake, were analyzed using a combination of inductively coupled plasma (ICP) methods and impedance spectroscopy. The results revealed contrasting concentrations of harmful elements in wastewater and soil, with heavy metals accumulating in soils. The impedance spectroscopy analysis, incorporating complex dielectric spectroscopy and equivalent circuit modeling, provided insights into the electrical properties of the soil samples. The observed correlation between relaxation times, dielectric parameters, and pollutant concentrations enhances our understanding of the environmental impact, emphasizing the need for a multidimensional approach to soil contamination studies.
Similar content being viewed by others
Data availability
The datasets generated during the current study are available from the corresponding author on reasonable request.
References
Butler MJ, Yellen BC, Oyewumi O, Ouimet W, Richardson JB (2023) Accumulation and transport of nutrient and pollutant elements in riparian soils, sediments, and river waters across the Thames River Watershed, Connecticut, USA. Sci Total Environ 899:165630. https://doi.org/10.1016/j.scitotenv.2023.165630
Chahid E, El Moznine R, Zradba A, Dani A, El Melouky A, Idrissi L et al (2013) Analysis of relaxation processes and low frequency dispersion in waste water. J Optoelectron Adv Mater 15:1209–1216
Chu Y, Nie S, Liu S, Lee C, Bate B (2019) Complex dielectric permittivity of metal and polymer modified montmorillonite. J Hazard Mater 374:382–391. https://doi.org/10.1016/j.jhazmat.2019.04.066
El Hafidi EM, Mortadi A, Graich A, Chahid EG, Laasri S, Moznine RE, Monkade M (2023) Monitoring treatment of industrial wastewater using conventional methods and impedance spectroscopy. Environ Monitor Assess 195(7):832. https://doi.org/10.1007/s13762-016-1222-x
Fang Y, Wang T, Sun C (2023) A stable solid-state lithium battery with a fluorine-rich interfacial layer electrolyte membrane. Electrochim Acta. https://doi.org/10.1016/j.electacta.2023.143224
Golia EE (2023) The impact of heavy metal contamination on soil quality and plant nutrition. Sustainable management of moderate contaminated agricultural and urban soils, using low cost materials and promoting circular economy. Sustain Chem Pharm 33:101046. https://doi.org/10.1016/j.scp.2023.101046
Jonscher AK (1983) Dielectric relaxation in solids. Chelsea Dilectric Press, London
Kumbhakar K, Pham TD, Lee KK, Kwak K, Cho M (2023) Dielectric relaxation spectroscopy for the characterization of ion transport in solid polymer electrolytes in Li-ion cells. Electrochim Acta. https://doi.org/10.1016/j.electacta.2023.142759
Li M, Jwo KW, Yi W (2021) A novel spectroscopy-based method using monopole antenna for measuring soil water content. Measurement 168:108459. https://doi.org/10.1016/j.measurement.2020.108459
Mortadi A, Chahid EG, Elmelouky A, Chahbi M, Ghyati NE, Zaim S et al (2020a) Complex electrical conductivity as a new technique to monitor the coagulation–flocculation processes in the wastewater treatment of the textile Industry. Water Resour Ind 24:100130. https://doi.org/10.1016/j.wri.2020.100130
Mortadi A, Elmelouky A, Chahid EG, Essajai R, Naserllah H, Chahbi M et al (2020b) Effects of calcium oxide on the surface properties of industrial sludge by analyzing rheological and electrical properties. J Environ Chem Eng 8(3):103764. https://doi.org/10.1016/j.jece.2020.103764
Ngai KL (2023) Universal properties of relaxation and diffusion in complex materials: originating from fundamental physics with rich applications. Progr Mater Sci. https://doi.org/10.1016/j.pmatsci.2023.101130
Prasanth R, Shubha N, Hng HH, Srinivasan M (2014) Effect of poly (ethylene oxide) on ionic conductivity and electrochemical properties of poly (vinylidenefluoride) based polymer gel electrolytes prepared by electrospinning for lithium ion batteries. J Power Sources 245:283–291. https://doi.org/10.1016/j.jpowsour.2013.05.178
Ram M (2008) Transport phenomena in the compound: LiFe1/2Mn1/2VO4. Solid State Ion 178(37–38):1922–1929. https://doi.org/10.1016/j.ssi.2007.12.016
Ram M (2010) Synthesis and electrical properties of (LiCo3/5Fe1/5Mn1/5) VO4 ceramics. Solid State Sci 12(3):350–354. https://doi.org/10.1016/j.solidstatesciences.2009.11.012
Saha A, Gupta BS, Patidar S, Martínez-Villegas N (2023) Optimal GIS interpolation techniques and multivariate statistical approach to study the soil-trace metal (loid) s distribution patterns in the agricultural surface soil of Matehuala, Mexico. J Hazard Mater Adv 9:100243. https://doi.org/10.1016/j.hazadv.2023.100243
Salhi A, Sayouri S, Alimoussa A, Kadira L (2019) Impedance spectroscopy analysis of Ca doped BaTiO3 ferroelectric ceramic manufactured with a new synthesis technique. Mater Today Proc 13:1248–1258. https://doi.org/10.1016/j.matpr.2019.05.084
Sena IC, Souza LA, Patire VF, Arias-Ortiz A, Creed JC, Cruz I, Hatje V (2022) Environmental settings of seagrass meadows control rare earth element distribution and transfer from soil to plant compartments. Sci Total Environ 843:157095. https://doi.org/10.1016/j.scitotenv.2022.157095
Szypłowska A, Lewandowski A, Yagihara S, Saito H, Furuhata K, Szerement J et al (2021) Dielectric models for moisture determination of soils with variable organic matter content. Geoderma 401:115288. https://doi.org/10.1016/j.geoderma.2021.115288
Tian X, Fang Z, Zheng F, Ma Z, Gao W, Shi G et al (2023) Continuous control of polarization state and tunable dual-channel optical communication based on highly transparent PMN-PT electro-optic ceramics. Ceramics Int. https://doi.org/10.1016/j.ceramint.2023.04.247
Veirana GM, Verhegge J, Cornelis W, De Smedt P (2023) Soil dielectric permittivity modelling for 50 MHz instrumentation. Geoderma 438:116624. https://doi.org/10.1016/j.geoderma.2023.116624
Zhang H, Mak CL (2012) Impedance spectroscopic characterization of fine-grained magnetoelectric Pb (Zr0.53Ti0.47)O3–(Ni0.5Zn0.5)Fe2O4 ceramic composites. J Alloy Compd 513:165–171. https://doi.org/10.1016/j.jallcom.2011.10.013
Author information
Authors and Affiliations
Corresponding author
Ethics declarations
Conflict of interest
The authors declare no competing financial interests.
Additional information
Responsible Editor: Rachid Soulimani.
This paper belongs to Special Issue: Advances in Environmental Sciences and Engineering.
Supplementary Information
Below is the link to the electronic supplementary material.
Rights and permissions
Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.
About this article
Cite this article
Chahid, E., Mortadi, A., Mghaiouini, R. et al. Analysis of relaxation processes and low frequency dispersion of soil contaminated. Euro-Mediterr J Environ Integr (2024). https://doi.org/10.1007/s41207-024-00503-5
Received:
Accepted:
Published:
DOI: https://doi.org/10.1007/s41207-024-00503-5