Skip to main content
Log in

Impact of novel chloride-binding on strength, chloride penetration and resistance to corrosion of concrete exposed to chloride-bearing environment

  • Technical Paper
  • Published:
Innovative Infrastructure Solutions Aims and scope Submit manuscript

Abstract

Among the various efforts that have been recently taken to combat chloride-induced corrosion is the usage of chloride-binding chemical additives. The current study investigated the performance of various chemical compounds (PbO, Pb (NO3)2 and TiO2) as chloride binders in concrete. Various dosages (0, 0.2, 0.5, 1.0, 1.5 and 2%) were tried in cement pastes for selection of optimum ratios for application in concrete. This work was concerned with the effect of chloride binders on strength (compressive and flexural) properties of concrete, resistance to chloride penetration and rate of steel corrosion in concrete exposed to chloride medium. Chloride binders prolonged the initial and final setting time without negative effect on strength. Using 0.2% PbO provided the highest strength results whereas 0.5% Pb(NO3)2 and 1% TiO2 yielded similar strength to plain concrete without binder but proved resistant to chloride-induced corrosion, making them appropriate chemical compounds for use as chloride binders.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig.1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10

Similar content being viewed by others

Data availability

The datasets used or analyzed during the current study are available from the corresponding author upon reasonable request.

References

  1. Fei-Long F, Jie H, Jaing-xiong W, Qi-Jun Y, Zheng-Shan C (2014) Corrosion performance of steel reinforcement in simulated concrete pore solutions in the presence of lmidazoline quaternary ammonium salt corrosion inhibitor. Construct Build Mater 70:43

    Article  Google Scholar 

  2. Klaartje DW (2021) Chloride binding in concrete: recent investigations and recognized knowledge gaps: RILEM Robert L’Hermite medal paper. Mater Struct 54(214):1793–1799

    Google Scholar 

  3. Ribeiro DV, Pinto SA, Junior NSA, Neto JSA, Ivan H, Santos L, Marques SL, Franca MJS (2021) Effects of binders characteristics and concrete dosing parameters on the chloride diffusion coefficient. Cem Concr Compos 122:104114

    Article  CAS  Google Scholar 

  4. Bertolini L, Elsener B, Pedeferri P, Redaelli E, Polder R (2004) Corrosion of steel in concrete: prevention, diagnosis, repair, 2nd edn. Wiley, Weinheim

    Google Scholar 

  5. Talib AY, Al-Gahtani RAS (1993) Chloride binding and corrosion in silica fume concrete. Concr 2000 Econ Durable Constr Thr Excell 2000:1452

    Google Scholar 

  6. Borade AN, Kondraivendhan B (2018) Performance of concrete blended with inhibitors and slag exposed to chloride environment. Mater Sci Eng 371:012004

    Google Scholar 

  7. Yupen T, BaO J, Zhang P, Zhao T (2022) Influence of internal chloride and cracking on the corrosion behavior of steel in mortar. Int J Electrochem Soc 17:220853

    Article  Google Scholar 

  8. Melchers RE (2020) Long-term durability of marine reinforced concrete structures. J Mat Sci Eng 8:290

    Google Scholar 

  9. Yang et al (2018) Analytical solution and experimental validation for dual time-dependent chloride diffusion in concrete. Constr Build Mater 161:676–686

    Article  CAS  Google Scholar 

  10. Martın-Pérez et al (2000) A study of the effect of chloride binding on service life predictions. Cem concrete Res 30:1215–1223

    Article  Google Scholar 

  11. Yuan et al (2009) Chloride binding of cement-based materials subjected to external chloride environment—A review. Constr Build Mater 23:1–13

    Article  Google Scholar 

  12. Yousef MM, El-Sayed HA, Kandeel AM, Gharieb M, Abdel-Aziz AA (2021) Chloride-binders and their effect on the physico-mechanical properties of sulfate-resisting cement (SRC) hardened pastes upon exposure to sea water attack. Environ Sci Pollut Res 29:20817–20828

    Article  Google Scholar 

  13. ASTM C150 (2001) Standard specification for Portland cement. American Society for Testing and Materials, West Conshohocken, PA

  14. ASTM C191 (2021) Standard test methods for time of setting of hydraulic cement by Vicat needle. West Conshohocken, PA: ASTM International, C191-08

  15. C 109/C 109M (2011) Test Method for Compressive Strength of Hydraulic Cement Mortars (Using 2-in. or [50-mm] Cube Specimens)

  16. Standard specification for chemical admixtures for concrete, ASTM C494/494M-19, ASTM International, 2019

  17. ASTM C192/C192M-02 Standard Practice for Making and Curing Concrete Test Specimens in the Laboratory, Annual Book of ASTM Standards, ASTM International, West Conshohocken, PA, 2002

  18. ASTM C39/C39M-03 (2014) Standard Test Method for Compressive Strength of Cylindrical Concrete Specimens. Annual Book of ASTM Standards, ASTM International, West Conshohocken, PA

  19. ASTM C293 (2016) Standard Test Method for Flexural Strength of Concrete (Using Simple Beam with Center-point Loading). Annual Book of ASTM Standards

  20. ASTM, C 1202 (2019) Standard test method for electrical indication of concrete’s ability to resist chloride ion penetration. West Conshohocken, PA, United States: ASTM International

  21. Knöfel D (1975) Corrosion of building materials. Van Nostrand Reinhold, New York

    Google Scholar 

  22. Rashad AM, Gharieb M (2021) Solving the perpetual problem of imperative use heat curing for fly ash geopolymer cement by using sugar beet waste. Constr Build Mater 307:124902

    Article  CAS  Google Scholar 

  23. Gharieb M, Rashad AM (2022) Impact of sugar beet waste on strength and durability of alkali-activated slag cement. ACI Mater J. https://doi.org/10.14359/51734354

    Article  Google Scholar 

  24. Song HW, Saraswathy V (2007) Corrosion monitoring of reinforced concrete structures—a review. Int J Electrochem Sci 2:1–28

    Article  Google Scholar 

  25. Rilem TC 154-EMC (2004) Test methods for on-site corrosion rate measurement of steel reinforcement in concrete by means of the polarization resistance method. Mate Struct 37:623–643

    Article  Google Scholar 

  26. Millard SG, Law D, Bungey JH, Cairns J (2001) Environmental influences on linear polarization corrosion rate measurement in reinforced concrete. NDT 9E Int 34:409–417

    Article  CAS  Google Scholar 

  27. El-Gawad WMA, Mossalam EA, Gharieb M (2023) Enhancing corrosion resistance in reinforced concrete structures by using innovative eco-friendly composite pigments. Innov Infrastruct Solut 8(12):320

    Article  Google Scholar 

  28. Elhabak A, El-Sayed H, El-Sokkary T, Gharieb M, Abdel Aziz A (2023) The impact of local industrially produced metakaolin on both cement and concrete reinforcing steel physico-mechanical and corrosion resistance properties. Egypt J Chem 66(10):549–565

    Google Scholar 

  29. Daniyal M, Akhtar S (2020) Corrosion assessment and control techniques for reinforced concrete structures: a review. J Build Pathol Rehabil 5(1):1–20

    Article  Google Scholar 

  30. Barbir D, Dabic P, Krolo P (2013) Hydration study of ordinary portland cement in the presence of lead (II) oxide. Chem Biochem Eng 27(1):95–99

    CAS  Google Scholar 

  31. He X, Shi X (2008) Chloride permeability and microstructure of Portland cement mortars incorporating nanomaterials. Transp Res Rec 2070(1):13–21

    Article  CAS  Google Scholar 

  32. Khater HM, Ghareib M (2020) Optimization of geopolymer mortar incorporating heavy metals in producing dense hybrid composites. J Build Eng 32:101684

    Article  Google Scholar 

  33. Feng D, Xie N, Gong Ch, Leng Z, Xiao H, Li H, Shi X (2013) Portland cement paste modified by TiO2 nanoparticles: a microstructure perspective. Ind Eng Chem Res 52:11575–11582

    Article  CAS  Google Scholar 

  34. El-Sayed HA, Sherbini GM (1984) Investigation of the factors enduing early deterioration of a reinforced concrete construction. Surf Technol 23(3):291–300

    Article  CAS  Google Scholar 

  35. Neville AM, Brooks JJ (1984) Concrete Technology, 2nd edn. Longman Group UK Limited, London

    Google Scholar 

  36. HA El-Sayed, AH Ali (1993) Effects of non-chloride accelerating admixtures on reinforced concrete durability. In: International Conference on Concrete and Structures, Hong Kong, pp. 57–60

Download references

Acknowledgements

The authors are thankful to the team work of Housing and Building National Research Center (HBRC), Egypt.

Funding

The authors declare that no funds, grants, or other support were received during the preparation of this manuscript.

Author information

Authors and Affiliations

Authors

Contributions

Esraa S. Ibrahim: materials preparation, experimental execution, literature preparation, Mahmoud Gharieb: Methodology, statistical analysis, results preparation, revision of manuscript, Mohamed R. Sakr: data interpretation, revision of manuscript, Hamdy A. El-Sayed: data interpretation, revision of manuscript, language editing, Mohamed O. R. El Hariri: data interpretation, revision of manuscript.

Corresponding author

Correspondence to Esraa S. Ibrahim.

Ethics declarations

Conflict of interest

The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the paper.

Ethics approval

Not applicable.

Informed consent

Not applicable.

Consent for publication

Not applicable.

Rights and permissions

Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Ibrahim, E.S., Gharieb, M., Sakr, M.R. et al. Impact of novel chloride-binding on strength, chloride penetration and resistance to corrosion of concrete exposed to chloride-bearing environment. Innov. Infrastruct. Solut. 9, 213 (2024). https://doi.org/10.1007/s41062-024-01522-5

Download citation

  • Received:

  • Accepted:

  • Published:

  • DOI: https://doi.org/10.1007/s41062-024-01522-5

Keywords

Navigation