Skip to main content
Log in

Unveiling optimal performance of SBS-modified asphalt mixture: crucial impact of elevated storage temperature and duration of binders

  • Technical Paper
  • Published:
Innovative Infrastructure Solutions Aims and scope Submit manuscript

Abstract

SBS-modified binders (SBS-MB) are susceptible to degradation when exposed to temperatures above 200 °C during manufacturing, transport and installation due to minimal oxygen. Without proper controls, this can lead to a substantial decline in binder properties, negatively affecting pavement quality. Therefore, a humble effort has been made in this study to recognize the role of elevated temperature and storage duration of modified binders on the properties of the prepared mixes. Studies were carried out by storing 4.5 wt% SBS-modified bitumen in a sealed tin container at 150 °C, 180 °C and 210 °C separately, for 1, 3, 7 and 14 days. After the stipulated storage time, the rheological properties of the SBS-modified binders were measured. Results highlighted that the aforementioned storage condition of binders played a key role in the observed property erosion of the modified mix. It had been found that in storage at 150 °C up to 14 days, the properties of the modified binder and corresponding mix remain unaffected. Notably, consequential erosion in asphalt mix performance was observed through Marshall stability, moisture susceptibility, tensile strength and stiffness modulus value when using mixes prepared with SBS-MBs stored at 180 °C and 210 °C. The severity of erosion corresponded to the duration of binder storage days. Storing the binder at temperatures of 180 °C for 3, 7 and 14 days resulted in 8.9%, 11.7% and 13% more abrasion loss, respectively, compared to fresh (unstored) SBS-MB. Moreover, within only 1 day of storage at 210 °C, a significant 20% reduction in the mixes' dynamic stability (DS) value was observed. The FM results clearly indicate that storing SBS-MBs at elevated temperatures (≥ 180 °C) will lead to the disintegration of the polymer network, thereby eroding the properties.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10
Fig. 11

Similar content being viewed by others

References

  1. Lu X, Isacsson U (2000) Modification of road bitumens with thermoplastic polymers. Polym Test 20:77–86. https://doi.org/10.1016/S0142-9418(00)00004-0

    Article  Google Scholar 

  2. Airey GD (2003) Rheological properties of styrene butadiene styrene polymer modified road bitumens. Fuel 82:1709–1719. https://doi.org/10.1016/S0016-2361(03)00146-7

    Article  Google Scholar 

  3. Alkaissi A (2018) Effect of high temperature and traffic loading on rutting performance of flexible pavement. J King Saud Univ Eng Sci. https://doi.org/10.1016/j.jksues.2018.04.005

    Article  Google Scholar 

  4. Lu X et al (2013) Performance evaluation of polymer modified bitumens on a heavily trafficked test road. Int J Pave Res Technol 7(6):381–388

    Google Scholar 

  5. Kodippily S, Tighe SL, Henning T (2016) Evaluating pavement performance through smart monitoring–effects of soil moisture, temperature and traffic. Road Mater Pavement Des 19(1):71–86. https://doi.org/10.1080/14680629.2016.1235507

    Article  Google Scholar 

  6. Lu X, Isacsson U, Xiaohu L (1998) Chemical and rheological evaluation of ageing properties of SBS polymer modified bitumens. Fuel 77:961–972. https://doi.org/10.1016/s0016-2361(97)00283-4

    Article  Google Scholar 

  7. Kumar P, Garg R (2011) Rheology of waste plastic fibre-modified bitumen. Int J Pavement Eng 12(5):449–459

    Article  Google Scholar 

  8. Ziari H, Goli A, Farahani H (2016) Application of rheological characteristics of modified bitumen to predict the fatigue life of asphalt mixtures. Pet Sci Technol 34(6):505–511. https://doi.org/10.1080/10916466.2013.773039,2016

    Article  Google Scholar 

  9. Chen JS, Liao MC, Lin CH (2003) Determination of polymer content in modified bitumen. Mater Struct Constr 36:594–598. https://doi.org/10.1617/13870

    Article  Google Scholar 

  10. Zhang Q et al (2014) Evaluation of the properties of bitumen modified by SBS copolymers with different styrene-butadiene structure. J Appl Polym Sci 131:1–7. https://doi.org/10.1002/app.40398

    Article  Google Scholar 

  11. Al-Hadidy AI, Yi-qiu T (2011) Effect of Styrene–Butadiene–Styrene on the properties of asphalt and stone-matrix-asphalt mixture. J Mater Civ Eng 23(4):504–510. https://doi.org/10.1061/(ASCE)MT.1943-5533.0000185

    Article  Google Scholar 

  12. Kok B, Yilmaz M (2009) The effects of using lime and styrene–butadiene–styrene on moisture sensitivity resistance of hot mix asphalt. Constr Build Mater 23:1999–2006

    Article  Google Scholar 

  13. Wen KG, Zhang Y et al (2002) Rheological characterization of storage-stable SBS-modified Asphalts. Polym Test 21:295–302

    Article  Google Scholar 

  14. Tayfur S, Ozen H, Aksoy A (2007) Investigation of rutting performance of asphalt mixtures containing polymer modifiers. Constr Build Mater 21:328–337

    Article  Google Scholar 

  15. Gorkem C, Sengoz B (2009) Predicting stripping and moisture-induced damage of asphalt concrete prepared with polymer-modified bitumen and hydrated lime. Constr Build Mater 23:2227–2236

    Article  Google Scholar 

  16. Aglan H, Othman A, Figueroa L et al (1993) Effect of styrene–butadiene–styrene block copolymer on fatigue crack propagation behavior of asphalt concrete mixtures. Transp Res 1417:178–186

    Google Scholar 

  17. Rek V, Vranjes N, Barjaktarovic ZM (2005) Relationship between fractal, viscoelastic, and aging properties of linear and radial styrene–butadiene–styrene polymer-modified bitumen. Mater Res Innov 9:670–691

    Google Scholar 

  18. Singh B et al (2016) Effect of polymer modification on the ageing properties of asphalt binders: chemical and morphological investigation. Constr Build Mater 205:633–641

    Article  Google Scholar 

  19. Chen F, Qian J (2000) Studies on the thermal degradation of polybutadiene. Fuel Process Technol 67:53–60

    Article  Google Scholar 

  20. Xu J et al (2007) A study on thermal oxidation mechanism of styrene-butadiene-styrene block copolymer (SBS). Polym Degrad Stab 92:1682–1691

    Article  Google Scholar 

  21. Cortizo MS, Larsen DO, Bianchetto H (2004) Effect of the thermal degradation of SBS copolymers during the ageing of modified asphalts. Polym Degrad Stab 86:275–282

    Article  Google Scholar 

  22. Mouillet V, Lamontagne J et al (2008) Infrared microscopy investigation of oxidation and phase evolution in bitumen modified with polymers. Fuel 87:1270–1280

    Article  Google Scholar 

  23. Dehouche N, Kaci M, Mokhtar KA (2012) Influence of thermo-oxidative ageing on chemical composition and physical properties of polymer modified bitumens. Constr Build Mater 26:350–356

    Article  Google Scholar 

  24. Xiao FP, Putman B, Amirkhanian S (2015) Rheological characteristics investigation of high percentage RAP binders with WMA technology at various aging states. Constr Build Mater 98:315–324

    Article  Google Scholar 

  25. Yan CQ, Xiao FP, Huang W (2018) Critical matters in using attenuated total reflectance Fourier transform infrared to characterize the polymer degradation in Styrene–Butadiene–Styrene-modified asphalt binders. Polym Test 70:289–296

    Article  Google Scholar 

  26. Xu S, Yu JY, Hu CB (2017) Laboratory evaluation of rejuvenation effect of reactive rejuvenator on aged SBS modified bitumen. Mater Struct 50:233

    Article  Google Scholar 

  27. Xu X, Yu JY, Zhang CL (2017) Effect of reactive rejuvenators on structure and properties of UV-aged SBS modified bitumen. Constr Build Mater 155:780–788

    Article  Google Scholar 

  28. Rasool T, Yao HR (2018) In-field aging process of high content SBS modified asphalt in porous pavement. Polym Degrad Stabil 155:220–229

    Article  Google Scholar 

  29. Hao J et al (2017) Developing of a SBS polymer modified bitumen to avoid low temperature cracks in the asphalt facing of a reservoir in a harsh climate region. Constr Build Mater 150:105–113

    Article  Google Scholar 

  30. Liu G et al (2014) Rheological and chemical evaluation on the ageing properties of SBS polymer modified bitumen: from the laboratory to the field. Constr Build Mater 51:244–248

    Article  Google Scholar 

  31. Gao Y, Gu F, Zhao Y (2013) Thermal oxidative aging characterization of SBS modified Asphalt. J Wuhan Univ Technol Mat Sci Ed 28:88–91

    Article  Google Scholar 

  32. Zhenzun Z, Wang J, Cong P (2020) Investigation of thermal degradation of asphalt binders during storage and transportation. Constr Build Mater 231:117196

    Article  Google Scholar 

  33. Singh S, Kumar Y, Ravindranath S (2018) Thermal degradation of SBS in asphalt binder during storage: influence of temperature, SBS concentration, polymer type and base asphalt binder. Polym Degrad Stabil 147:64–75

    Article  Google Scholar 

  34. Remtulla A et al (2009) The effect of prolonged hot storage of the elastomeric pmbs on the rutting and fatigue properties of hot mix asphalt. In: AAPA international flexible pavements conference 13th.

  35. Austroads Technical Report: Investigations into the effects of polymer segregation and degradation in polymer modified binders, Sydney NSW, Australia, AP-T227 (2013)

  36. AAPA (Australian Asphalt Pavement Association) (2004) Code of practice Manufacture, storage, and handling of polymer modified binders. AAPA 1st edition, Australia

  37. AAPA (Australian Asphalt Pavement Association) (2013) Guide to the Heating and Storage of Binders for Sprayed Sealing and Hot Mixed Asphalt. AAPA Advisory Note 7, Australia

  38. Mouillet V, Farcas F, Besson S (2008) Ageing by UV radiation of an elastomer modified bitumen. Fuel 87(12):2408–2419. https://doi.org/10.1016/j.fuel.2008.02.008

    Article  Google Scholar 

  39. Sun L, Wang Y, Zhang Y (2014) Ageing mechanism and effective recycling ration of SBS modified asphalt. Const Build Mater 70:26–35

    Article  Google Scholar 

  40. Mandal T, Sylla R, Bahia HU (2015) Effect of cross-linking agents on the rheological properties of polymer-modified bitumen. Road Mater Pavement Des 16(1):349–361

    Article  Google Scholar 

  41. Zhang F, Yu J, Wu S (2010) Effect of aging on rheological properties of storage-stable SBS/sulfur-modified asphalts. J Hazard Mater 182(1–3):507–517

    Article  Google Scholar 

  42. Martínez-Estrada A et al (2010) Comparative study of the effect of sulfur on the morphology and rheological properties of SB-and SBS-modified asphalt. J Appl Polym Sci 115:3409–3422

    Article  Google Scholar 

  43. MORTH (2013) Specifications for Road and bridge work, ministry of road transport and highway, New Delhi, India.

  44. Asphalt Institute (2014) MS-2 asphalt mix design methods. Asphalt Institute, Lexington

    Google Scholar 

  45. ASTM D7405 (2010) Standard test method for multiple stress creep and recovery (MSCR) of asphalt binder using a dynamic shear rheometer. ASTM, West Conshohocken

    Google Scholar 

  46. ASTM D6927 (2015) Standard test method for Marshall stability and flow of asphalt mixtures. ASTM, West Conshohocken

    Google Scholar 

  47. ASTM D6931–12 (2012) Indirect tensile (IDT) strength for bituminous mixtures. ASTM, West Conshohocken

    Google Scholar 

  48. AASHTO (1989) Resistance of compacted bituminous mixture to moisture induced damage. T283, Washington, DC

    Google Scholar 

  49. ASTM D4123–82 (1995) Standard test method for indirect tension test for resilient modulus of bituminous mixtures. ASTM, West Conshohocken

    Google Scholar 

  50. ASTM D7064 (2013) Standard practice for open-graded friction course (OGFC) mix design. ASTM, West Conshohocken

    Google Scholar 

  51. AASHTO (2004) Standard method of test for hamburg wheel-track testing of compacted hot-mix asphalt (HMA). American Association of State Highway and Transportation Officials, T324, Washington

    Google Scholar 

  52. McNally T (2011) Polymer modified bitumen. Polym Modif Bitum 16:1–404. https://doi.org/10.1533/9780857093721

    Article  Google Scholar 

  53. Nciri N, KimKim NN (2017) New insights into the effects of styrene-butadiene-styrene polymer modifier on the structure, properties, and performance of asphal binder: the case of AP-5 asphalt and solvent deasphalting pitch. Mater Chem Phys 193:477–495

    Article  Google Scholar 

Download references

Acknowledgements

The authors express their gratitude to the Ministry of Human Resource Development, Government of India, for granting student scholarships.

Funding

Funding was provided by MHRD, GOI (Grant No. 18910071).

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to G. D. Ransinchung R.N.

Ethics declarations

Conflict of interest

The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.

Ethical approval

The authors remained loyal to ethical rules during the data collection process.

Informed consent

All participants provided informed consent prior to their participation.

Consent to participate

All authors have consented to participate in this study.

Consent to publish

All authors have consented to the publication of this work.

Rights and permissions

Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Islam, S.S., Ghosh, A., R.N, G.D.R. et al. Unveiling optimal performance of SBS-modified asphalt mixture: crucial impact of elevated storage temperature and duration of binders. Innov. Infrastruct. Solut. 8, 307 (2023). https://doi.org/10.1007/s41062-023-01271-x

Download citation

  • Received:

  • Accepted:

  • Published:

  • DOI: https://doi.org/10.1007/s41062-023-01271-x

Keywords

Navigation