Abstract
SBS-modified binders (SBS-MB) are susceptible to degradation when exposed to temperatures above 200 °C during manufacturing, transport and installation due to minimal oxygen. Without proper controls, this can lead to a substantial decline in binder properties, negatively affecting pavement quality. Therefore, a humble effort has been made in this study to recognize the role of elevated temperature and storage duration of modified binders on the properties of the prepared mixes. Studies were carried out by storing 4.5 wt% SBS-modified bitumen in a sealed tin container at 150 °C, 180 °C and 210 °C separately, for 1, 3, 7 and 14 days. After the stipulated storage time, the rheological properties of the SBS-modified binders were measured. Results highlighted that the aforementioned storage condition of binders played a key role in the observed property erosion of the modified mix. It had been found that in storage at 150 °C up to 14 days, the properties of the modified binder and corresponding mix remain unaffected. Notably, consequential erosion in asphalt mix performance was observed through Marshall stability, moisture susceptibility, tensile strength and stiffness modulus value when using mixes prepared with SBS-MBs stored at 180 °C and 210 °C. The severity of erosion corresponded to the duration of binder storage days. Storing the binder at temperatures of 180 °C for 3, 7 and 14 days resulted in 8.9%, 11.7% and 13% more abrasion loss, respectively, compared to fresh (unstored) SBS-MB. Moreover, within only 1 day of storage at 210 °C, a significant 20% reduction in the mixes' dynamic stability (DS) value was observed. The FM results clearly indicate that storing SBS-MBs at elevated temperatures (≥ 180 °C) will lead to the disintegration of the polymer network, thereby eroding the properties.
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References
Lu X, Isacsson U (2000) Modification of road bitumens with thermoplastic polymers. Polym Test 20:77–86. https://doi.org/10.1016/S0142-9418(00)00004-0
Airey GD (2003) Rheological properties of styrene butadiene styrene polymer modified road bitumens. Fuel 82:1709–1719. https://doi.org/10.1016/S0016-2361(03)00146-7
Alkaissi A (2018) Effect of high temperature and traffic loading on rutting performance of flexible pavement. J King Saud Univ Eng Sci. https://doi.org/10.1016/j.jksues.2018.04.005
Lu X et al (2013) Performance evaluation of polymer modified bitumens on a heavily trafficked test road. Int J Pave Res Technol 7(6):381–388
Kodippily S, Tighe SL, Henning T (2016) Evaluating pavement performance through smart monitoring–effects of soil moisture, temperature and traffic. Road Mater Pavement Des 19(1):71–86. https://doi.org/10.1080/14680629.2016.1235507
Lu X, Isacsson U, Xiaohu L (1998) Chemical and rheological evaluation of ageing properties of SBS polymer modified bitumens. Fuel 77:961–972. https://doi.org/10.1016/s0016-2361(97)00283-4
Kumar P, Garg R (2011) Rheology of waste plastic fibre-modified bitumen. Int J Pavement Eng 12(5):449–459
Ziari H, Goli A, Farahani H (2016) Application of rheological characteristics of modified bitumen to predict the fatigue life of asphalt mixtures. Pet Sci Technol 34(6):505–511. https://doi.org/10.1080/10916466.2013.773039,2016
Chen JS, Liao MC, Lin CH (2003) Determination of polymer content in modified bitumen. Mater Struct Constr 36:594–598. https://doi.org/10.1617/13870
Zhang Q et al (2014) Evaluation of the properties of bitumen modified by SBS copolymers with different styrene-butadiene structure. J Appl Polym Sci 131:1–7. https://doi.org/10.1002/app.40398
Al-Hadidy AI, Yi-qiu T (2011) Effect of Styrene–Butadiene–Styrene on the properties of asphalt and stone-matrix-asphalt mixture. J Mater Civ Eng 23(4):504–510. https://doi.org/10.1061/(ASCE)MT.1943-5533.0000185
Kok B, Yilmaz M (2009) The effects of using lime and styrene–butadiene–styrene on moisture sensitivity resistance of hot mix asphalt. Constr Build Mater 23:1999–2006
Wen KG, Zhang Y et al (2002) Rheological characterization of storage-stable SBS-modified Asphalts. Polym Test 21:295–302
Tayfur S, Ozen H, Aksoy A (2007) Investigation of rutting performance of asphalt mixtures containing polymer modifiers. Constr Build Mater 21:328–337
Gorkem C, Sengoz B (2009) Predicting stripping and moisture-induced damage of asphalt concrete prepared with polymer-modified bitumen and hydrated lime. Constr Build Mater 23:2227–2236
Aglan H, Othman A, Figueroa L et al (1993) Effect of styrene–butadiene–styrene block copolymer on fatigue crack propagation behavior of asphalt concrete mixtures. Transp Res 1417:178–186
Rek V, Vranjes N, Barjaktarovic ZM (2005) Relationship between fractal, viscoelastic, and aging properties of linear and radial styrene–butadiene–styrene polymer-modified bitumen. Mater Res Innov 9:670–691
Singh B et al (2016) Effect of polymer modification on the ageing properties of asphalt binders: chemical and morphological investigation. Constr Build Mater 205:633–641
Chen F, Qian J (2000) Studies on the thermal degradation of polybutadiene. Fuel Process Technol 67:53–60
Xu J et al (2007) A study on thermal oxidation mechanism of styrene-butadiene-styrene block copolymer (SBS). Polym Degrad Stab 92:1682–1691
Cortizo MS, Larsen DO, Bianchetto H (2004) Effect of the thermal degradation of SBS copolymers during the ageing of modified asphalts. Polym Degrad Stab 86:275–282
Mouillet V, Lamontagne J et al (2008) Infrared microscopy investigation of oxidation and phase evolution in bitumen modified with polymers. Fuel 87:1270–1280
Dehouche N, Kaci M, Mokhtar KA (2012) Influence of thermo-oxidative ageing on chemical composition and physical properties of polymer modified bitumens. Constr Build Mater 26:350–356
Xiao FP, Putman B, Amirkhanian S (2015) Rheological characteristics investigation of high percentage RAP binders with WMA technology at various aging states. Constr Build Mater 98:315–324
Yan CQ, Xiao FP, Huang W (2018) Critical matters in using attenuated total reflectance Fourier transform infrared to characterize the polymer degradation in Styrene–Butadiene–Styrene-modified asphalt binders. Polym Test 70:289–296
Xu S, Yu JY, Hu CB (2017) Laboratory evaluation of rejuvenation effect of reactive rejuvenator on aged SBS modified bitumen. Mater Struct 50:233
Xu X, Yu JY, Zhang CL (2017) Effect of reactive rejuvenators on structure and properties of UV-aged SBS modified bitumen. Constr Build Mater 155:780–788
Rasool T, Yao HR (2018) In-field aging process of high content SBS modified asphalt in porous pavement. Polym Degrad Stabil 155:220–229
Hao J et al (2017) Developing of a SBS polymer modified bitumen to avoid low temperature cracks in the asphalt facing of a reservoir in a harsh climate region. Constr Build Mater 150:105–113
Liu G et al (2014) Rheological and chemical evaluation on the ageing properties of SBS polymer modified bitumen: from the laboratory to the field. Constr Build Mater 51:244–248
Gao Y, Gu F, Zhao Y (2013) Thermal oxidative aging characterization of SBS modified Asphalt. J Wuhan Univ Technol Mat Sci Ed 28:88–91
Zhenzun Z, Wang J, Cong P (2020) Investigation of thermal degradation of asphalt binders during storage and transportation. Constr Build Mater 231:117196
Singh S, Kumar Y, Ravindranath S (2018) Thermal degradation of SBS in asphalt binder during storage: influence of temperature, SBS concentration, polymer type and base asphalt binder. Polym Degrad Stabil 147:64–75
Remtulla A et al (2009) The effect of prolonged hot storage of the elastomeric pmbs on the rutting and fatigue properties of hot mix asphalt. In: AAPA international flexible pavements conference 13th.
Austroads Technical Report: Investigations into the effects of polymer segregation and degradation in polymer modified binders, Sydney NSW, Australia, AP-T227 (2013)
AAPA (Australian Asphalt Pavement Association) (2004) Code of practice Manufacture, storage, and handling of polymer modified binders. AAPA 1st edition, Australia
AAPA (Australian Asphalt Pavement Association) (2013) Guide to the Heating and Storage of Binders for Sprayed Sealing and Hot Mixed Asphalt. AAPA Advisory Note 7, Australia
Mouillet V, Farcas F, Besson S (2008) Ageing by UV radiation of an elastomer modified bitumen. Fuel 87(12):2408–2419. https://doi.org/10.1016/j.fuel.2008.02.008
Sun L, Wang Y, Zhang Y (2014) Ageing mechanism and effective recycling ration of SBS modified asphalt. Const Build Mater 70:26–35
Mandal T, Sylla R, Bahia HU (2015) Effect of cross-linking agents on the rheological properties of polymer-modified bitumen. Road Mater Pavement Des 16(1):349–361
Zhang F, Yu J, Wu S (2010) Effect of aging on rheological properties of storage-stable SBS/sulfur-modified asphalts. J Hazard Mater 182(1–3):507–517
Martínez-Estrada A et al (2010) Comparative study of the effect of sulfur on the morphology and rheological properties of SB-and SBS-modified asphalt. J Appl Polym Sci 115:3409–3422
MORTH (2013) Specifications for Road and bridge work, ministry of road transport and highway, New Delhi, India.
Asphalt Institute (2014) MS-2 asphalt mix design methods. Asphalt Institute, Lexington
ASTM D7405 (2010) Standard test method for multiple stress creep and recovery (MSCR) of asphalt binder using a dynamic shear rheometer. ASTM, West Conshohocken
ASTM D6927 (2015) Standard test method for Marshall stability and flow of asphalt mixtures. ASTM, West Conshohocken
ASTM D6931–12 (2012) Indirect tensile (IDT) strength for bituminous mixtures. ASTM, West Conshohocken
AASHTO (1989) Resistance of compacted bituminous mixture to moisture induced damage. T283, Washington, DC
ASTM D4123–82 (1995) Standard test method for indirect tension test for resilient modulus of bituminous mixtures. ASTM, West Conshohocken
ASTM D7064 (2013) Standard practice for open-graded friction course (OGFC) mix design. ASTM, West Conshohocken
AASHTO (2004) Standard method of test for hamburg wheel-track testing of compacted hot-mix asphalt (HMA). American Association of State Highway and Transportation Officials, T324, Washington
McNally T (2011) Polymer modified bitumen. Polym Modif Bitum 16:1–404. https://doi.org/10.1533/9780857093721
Nciri N, KimKim NN (2017) New insights into the effects of styrene-butadiene-styrene polymer modifier on the structure, properties, and performance of asphal binder: the case of AP-5 asphalt and solvent deasphalting pitch. Mater Chem Phys 193:477–495
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The authors express their gratitude to the Ministry of Human Resource Development, Government of India, for granting student scholarships.
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Funding was provided by MHRD, GOI (Grant No. 18910071).
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Islam, S.S., Ghosh, A., R.N, G.D.R. et al. Unveiling optimal performance of SBS-modified asphalt mixture: crucial impact of elevated storage temperature and duration of binders. Innov. Infrastruct. Solut. 8, 307 (2023). https://doi.org/10.1007/s41062-023-01271-x
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DOI: https://doi.org/10.1007/s41062-023-01271-x