Abstract
Modern agricultural chemistry has to support farmers by providing innovative agrochemicals. In this context, the introduction of sulfur atoms into an active ingredient is still an important tool in modulating the properties of new crop-protection compounds. More than 30% of today’s agrochemicals contain at least one sulfur atom, mainly in fungicides, herbicides and insecticides. A number of recently developed sulfur-containing agrochemical candidates represent a novel class of chemical compounds with new modes of action, so we intend to highlight the emerging interest in commercially active sulfur-containing compounds. This chapter gives a comprehensive overview of selected leading sulfur-containing pesticidal chemical families namely: sulfonylureas, sulfonamides, sulfur-containing heterocyclics, thioureas, sulfides, sulfones, sulfoxides and sulfoximines. Also, the most suitable large-scale synthetic methods of the recently launched or provisionally approved sulfur-containing agrochemicals from respective chemical families have been highlighted.
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Abbreviations
- AHAS:
-
Acetohydroxyacid synthase
- GABA:
-
γ-Aminobutyric acid
- BOC:
-
t-Butyloxycarbonyl
- mCPBA:
-
meta-Chloroperoxybenzoic acid
- DBU:
-
1,8-Diazabicyclo[5.4.0]undec-7-ene
- DCC:
-
N,N’-Dicyclohexylcarbodiimide
- DHPS:
-
7,8-Dihydro-preroate synthetase
- DMAP:
-
4-Dimethylaminopyridine
- FRAC:
-
Fungicide Resistance Action Committee
- GUP:
-
General use pesticide
- HRAC:
-
Herbicide resistance Action Committee
- HPPD:
-
4-Hydroxyphenylpyruvate dioxygenase
- IRAC:
-
Insecticide Resistance Action Committee
- ISO:
-
International Standardization Organization
- LDA:
-
Lithium diisopropylamide
- MOA:
-
Mode of action
- nAchRs:
-
Nicotinic acetylcholine receptors
- PPO:
-
Protoporphyrinogen IX oxidase
- SDHI:
-
Succinate dehydrogenase inhibitor
- TEA:
-
Triethylamine
- VLCFA:
-
Very long chain fatty acid
- WSSA:
-
Weed Science Society of America
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Financial support from Natinal Key R&D Program (2017YFD0200507) and National Science Foundation of China (No. 21332004) is greatfully acknowledged.
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This article is part of the topical collection “Sulfur Chemistry”; edited by Xuefeng Jiang.
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Devendar, P., Yang, GF. Sulfur-Containing Agrochemicals. Top Curr Chem (Z) 375, 82 (2017). https://doi.org/10.1007/s41061-017-0169-9
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DOI: https://doi.org/10.1007/s41061-017-0169-9