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A study on flowability, strength and drying shrinkage properties of one-part AAM cured at ambient temperature

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Abstract

Alkali-activated materials are conventionally produced by a two-part mixing in which alkalis are used as aqueous solutions that create applicability problems. To overcome the problem, one-part alkali-activated materials (AAM) are being studied. In this study, the influence of aluminosilicate precursors, sodium hydroxide (NaOH), alkaline activators (AA) ratio (Na2SiO3: NaOH), and production method on flowability, compressive and flexural strength, and drying shrinkage properties of one-part AAM was studied. Ground granulated blast-furnace slag (GGBFS) increased the strength but negatively influenced the flowability and drying shrinkage of the AAM. Fly ash improved the flowability and decreased the drying shrinkage but the material had much lower reactivity at ambient temperature to improve the strength. AA ratio improved the flowability but reduced the strength. High-concentrated NaOH decreased the flowability and strength of the material. One-part AAM had much lower strength compared to conventional and two-part AAM. This is attributed to a lack of better reaction between aluminosilicate precursors and AA in the one-part mixture.

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References

  1. Duxson P, Provis JL, Grant VD (2007) The role of inorganic polymer technology in the development of ‘green concrete.’ Cem Concr Res 37:1590–1597. https://doi.org/10.1016/j.cemconres.2007.08.018

    Article  Google Scholar 

  2. Provis JL, Duxson P, Kavalerova E, Krivenko PV, Pan Z, Puertas F, van Deventer JSJ (2014) Historical aspects and overview. In: Provis JL, van Deventer JSJ (eds) Alkali-activated materials: state-of-the-art report, Rilem, T.C. 224-AAM, Springer, Dordrecht, pp 11–57. https://doi.org/10.1007/978-94-007-7672-2_2

  3. Duxson P, Fernández-Jiménez A, Provis JL, Lukey GC, Palomo A, Van Deventer JSJ (2007) Geopolymer technology: the current state of the art. J Mater Sci 42:2917–2933. https://doi.org/10.1007/s10853-006-0637-z

    Article  Google Scholar 

  4. Van Deventer JSJ, Provis JL, Duxson P, Brice DG (2010) Chemical research and climate change as drivers in the commercial adoption of alkali activated materials. Waste Biomass Valoriz 1:145–155. https://doi.org/10.1007/s12649-010-9015-9

    Article  Google Scholar 

  5. Fernández-Jiménez A, Palomo JG, Puertas F (1999) Alkali-activated slag mortars: mechanical strength behaviour. Cem Concr Res 29:1313–1321. https://doi.org/10.1016/S0008-8846(99)00154-4

    Article  Google Scholar 

  6. Davidovits J (1991) Geopolymers—inorganic polymeric new materials. J Therm Anal 37:1633–1656. https://doi.org/10.1007/BF01912193

    Article  Google Scholar 

  7. Glukhovsky VD, Pashkov IA, Yavorsky GA (1957) New building material in Russian, Bulletin of Technical Information, GlavKievStroy, Kiev

  8. Davidovits J (1984) Synthetic mineral polymer compound of the silicoaluminates family and preparation process. U.S. Patent 4,472,199

  9. Luukkonen T, Abdollahnejad Z, Yliniemi J, Kinnunen P, Illikainen M (2018) One-part alkali-activated materials: a review. Cem Concr Res 103:21–34. https://doi.org/10.1016/j.cemconres.2017.10.001

    Article  Google Scholar 

  10. Fang G, Ho WK, Tu W, Zhang M (2018) Workability and mechanical properties of alkali-activated fly ash-slag concrete cured at ambient temperature. Constr Build Mater 172:476–487. https://doi.org/10.1016/j.conbuildmat.2018.04.008

    Article  Google Scholar 

  11. Rangan B, Wallah S, Sumajouw D, Hardjito D (2006) Heat-cured low-calcium fly ash-based geopolymer concrete. Indian Concrete J 80(6):47–52

    Google Scholar 

  12. Wallah S, Rangan B (2006) Low-calcium fly ash-based geopolymer concrete: long term properties. Research Report G. C., Faculty of Engineering, Curtin University of Technology, Perth, Australia. https://www.researchgate.net/publication/265277484_Low-calcium_fly_ash-based_geopolymer_concrete_long_term_properties

  13. Fernández-Jiménez A, Palomo A, López-Hombrados C (2006) Some engineering properties of alkali activated fly ash concrete. ACI Mater J 103(2):106–12

    Google Scholar 

  14. Tajunnisa Y, Sugimoto M, Sato T, Shigeishi M (2017) A study on factors affecting geopolymerization of low calcium fly ash. Int J GEOMATE 13:100–107. https://doi.org/10.21660/2017.36.84153

    Article  Google Scholar 

  15. Tajunnisa Y, Sugimoto M, Uchinuno T, Sato T, Toda Y, Hamasaki A, Yoshinaga T, Shida K, Shigeishi M (2017) Effect of GGBFS and micro-silica on mechanical properties shrinkage and microstructure of alkali-activated fly ash mortar. Int J GEOMATE 13:87–94. https://doi.org/10.21660/2017.39.11341

    Article  Google Scholar 

  16. Kurtoglu AE, Alzeebaree R, Aljumaili O, Nis A, Gulsan E, Humur G, Cevik A (2018) Mechanical and durability properties of fly ash and slag based geopolymer concrete. Adv Concrete Constr 6(4):345–362. https://doi.org/10.12989/acc.2018.6.4.345

    Article  Google Scholar 

  17. Mizuno H, Iyoda T (2019) Shrinkage characteristics of ground granulated blast furnace slag high content cement. Integrated Vision—Caspeele, Taerwe & Frangopol (eds) © 2019 Taylor & Francis Group, London, ISBN 978-1-138-62633-1

  18. Phoo-ngernkham T, Maegawa A, Mishima N, Hatanaka S, Chindaprasirt P (2015) Effects of sodium hydroxide and sodium silicate solutions on compressive and shear bond strengths of FA–GBFS geopolymer. Constr Build Mater 91:1–8

    Article  Google Scholar 

  19. Taghvayi H, Behfarnia K, Khalili M (2018) The effect of alkali concentration and sodium silicate modulus on the properties of alkali-activated slag concrete. J Adv Concr Technol 16:293–305. https://doi.org/10.3151/jact.16.293

    Article  Google Scholar 

  20. Pundiene I, Pranckeviciene I, Zhu Ch (2020) Effect of molarity and temperature of alkaline activator solution on the rheological properties and structure formation of alkali-activated refractory materials. Glass Ceram 77:51–56. https://doi.org/10.1007/s10717-020-00236-1

    Article  Google Scholar 

  21. Mustata Al Bakri AM, Kamarudin H, Bnhussain M, Rafiza AR, Zarina Y (2012) Effect of Na2SiO3/NaOH ratios and NaOH molarities on compressive strength of fly-ash-based geopolymer. ACI Mater J 109(5):503–508

    Google Scholar 

  22. Hamzah HN, Abdullah MMAB, Yong H, Rozainy Z, Nor A, Zailani WW (2016) Correlation of the Na2SiO3 to NaOH ratios and solid to liquid ratios to the kedah’s soil strength. MATEC Web Confer 78:01071. https://doi.org/10.1051/matecconf/20167801071

    Article  Google Scholar 

  23. Rasuli MI (2022) A study on the influence of sodium silicate concentration and SiO2: Na2O ratio on the properties of low-calcium fly ash-based alkali-activated materials cured at ambient condition. Adv Mater Sci Eng 2022:7. https://doi.org/10.1155/2022/7762507

    Article  Google Scholar 

  24. Nematollahi B, Sanjayan J, Qiu J, Yang EH (2017) Micromechanics-based investigation of a sustainable ambient temperature cured one-part strain hardening geopolymer composite. Constr Build Mater 131:552–563. https://doi.org/10.1016/j.conbuildmat.2016.11.117

    Article  Google Scholar 

  25. Hajimohammadi A, van Deventer JSJ (2017) Characterisation of one-part geopolymer binders made from fly ash. Waste Biomass Valoriz 8:225–233. https://doi.org/10.1007/s12649-016-9582-5

    Article  Google Scholar 

  26. Suwan T, Fan M (2017) Effect of manufacturing process on the mechanisms and mechanical properties of fly ash-based geopolymer in ambient curing temperature. Mater Manuf Processes 32:461–467. https://doi.org/10.1080/10426914.2016.1198013

    Article  Google Scholar 

  27. Qin Y, Qu C, Ma C, Zhou L (2022) One-part alkali-activated materials: state of the art and perspectives. Polymers 14:5046. https://doi.org/10.3390/polym14225046

    Article  Google Scholar 

  28. Teo W, Shirai K, Lim JH, Jack LB, Nikbakht E (2022) Experimental investigation on ambient-cured one-part alkali-activated binders using combined high-calcium fly ash (HCFA) and ground granulated blast furnace slag (GGBS). Materials 15:1612. https://doi.org/10.3390/ma15041612

    Article  Google Scholar 

  29. Nematollahi B, Sanjayan J, Ahmed S (2015) FU synthesis of heat and ambient cured one-part geopolymer mixes with different grades of sodium silicate. Ceram Int 41:5696–5704

    Article  Google Scholar 

  30. Ouyang S, Chen W, Zhang Z, Li X, Zhu W (2020) Experimental study of one-part geopolymer using different alkali sources. J Phys: Conf Ser 1605:012155. https://doi.org/10.1088/1742-6596/1605/1/012155

    Article  Google Scholar 

  31. Tajunnisa Y (2017) Characterization of alkali-activated materials cured at ordinary temperature for utilization of PVA fiber-reinforcement. Doctoral thesis. Kumamoto University, Kumamoto, Japan

  32. Rasuli MI, Tajunnisa Y, Yamamura A, Shigeishi M (2022) A consideration on the one-part mixing method of alkali-activated material: problems of sodium silicate solubility and quick setting. Heliyon 8(1):e08783. https://doi.org/10.1016/j.heliyon.2022.e08783

    Article  Google Scholar 

  33. Tajunnisa Y, Rasuli MI, Yamamura A, Shigeishi M (2023) Reliability prediction of alkali-activated mortar during flexural loading using Weibull analysis. Heliyon. https://doi.org/10.1016/j.heliyon.2023.e21512

    Article  Google Scholar 

Download references

Acknowledgements

This research was conducted at Kumamoto University, Japan, supported by The Hitachi Global Foundation Ref. RS-15, E-1 March 8, 2019, Kumamoto University, and Institut Teknologi Sepuluh Nopember, Surabaya, Indonesia.

Funding

This work was supported by the Hitachi Global Foundation Ref. RS-15, E-1 March 8, 2019, Kumamoto University, and Institut Teknologi Sepuluh Nopember.

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Mohammad Idris Rasuli: Conceived and designed the experiments; Analyzed and interpreted the data; Wrote the paper. Yuyun Tajunnisa: Conceived and designed the experiments; Performed the experiments; Analyzed and interpreted the data. Akifumi Yamamura: Performed the experiments; Analyzed and interpreted the data.

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Correspondence to Mohammad Idris Rasuli.

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Rasuli, M.I., Tajunnisa, Y. & Yamamura, A. A study on flowability, strength and drying shrinkage properties of one-part AAM cured at ambient temperature. J Build Rehabil 9, 30 (2024). https://doi.org/10.1007/s41024-023-00380-5

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  • DOI: https://doi.org/10.1007/s41024-023-00380-5

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