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Corrosion Resistance of Montmorillonite-Modified Dense Concretes

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Abstract

Corrosion of reinforcing steel bars is the leading cause of deterioration in concrete. In this paper, corrosion process of rebars is controlled using montmorillonite nano-clay particles which are partially substituted as cement in the mix designs. Mechanical and physical properties of the mixtures are measured, and steel reinforced concrete specimens are exposed to chloride solution for 6 months. Passing electric current through the reinforcement is measured under constant voltage, and potential differences between the steel bars and the concrete surfaces are measured every week. Results show that Montmorillonite particles remarkably reduce the compressive strength and increase the water absorption, but they can postpone initiating of rebars corrosion and decrease the corrosion rate. Negatively charged surface of nano-clay particles repulse OH and Cl ions and as a result the formation of iron rusts is delayed and the corrosion process is declined. Consequently, neither the compressive strength nor the water absorption is suitable as a criterion to accept a reinforced concrete under chloride attacks.

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References

  1. Ann KY, Song HW (2007) Chloride threshold level for corrosion of steel in concrete. Corros Sci 49(11):4113–4133

    Article  Google Scholar 

  2. Angst U, Elsener B, Larsen CK, Vennesland Ø (2009) Critical chloride content in reinforced concrete—a review. Cement Concrete Res 39(12):1122–1138

    Article  Google Scholar 

  3. Dousti A, Moradian M, Taheri SR, Rashetnia R, Shekarchi M (2013) Corrosion assessment of RC deck in a jetty structure damaged by chloride attack. J Perform Constr Facil 27:519–528

    Article  Google Scholar 

  4. Li JH, Zhao B, Hu J, Zhang H, Dong SG, Du RG, Li CJ (2015) Corrosion inhibition effect of D-sodium gluconate on reinforcing steel in chloride-contaminated simulated concrete pore solution. Int J Electrochem Sci 10:956–968

    Google Scholar 

  5. Martín-Pérez B, Zibara H, Hooton RD, Thomas MDA (2000) A study of the effect of chloride binding on service life predictions. Cement Concrete Res 30(8):1215–1223

    Article  Google Scholar 

  6. Cheung MMS, Cao C (2013) Application of cathodic protection for controlling macrocell corrosion in chloride contaminated RC structures. Constr Build Mater 45:199–207

    Article  Google Scholar 

  7. Huang T, Huang X, Wu P (2014) Review of recent developments of electrochemical chloride extraction on reinforced concrete in civil engineering. Int J Electrochem Sci 9:4589–4597

    Google Scholar 

  8. Hussain RR, Wasim M, Baloch MA (2015) Investigation of long term coupled effect of high temperature and constant high humidity on corrosion rehabilitated patches of reinforced concrete structures. Int J Civ Eng 13(1):69–75

    Google Scholar 

  9. Stanish KD, Hooton RD, Thomas MDA (2000) Testing the chloride penetration resistance of concrete: a literature review. Research report, Department of Civil Engineering, University of Toronto, Ontario, Canada

  10. Song HW, Lee CH, Ann KY (2008) Factors influencing chloride transport in concrete structures exposed to marine environments. Cement Concrete Comp 30(2):113–121

    Article  Google Scholar 

  11. Polder RB, Peelen WHA (2002) Characterisation of chloride transport and reinforcement corrosion in concrete under cyclic wetting and drying by electrical resistivity. Cement Concrete Comp 24(5):427–435

    Article  Google Scholar 

  12. Page CL, Short NR, Tarras AE (1981) Diffusion of chloride ions in hardened cement pastes. Cement Concrete Res 11(3):395–406

    Article  Google Scholar 

  13. Pavoine A, Harbec D, Chaussadent T, Tagnit-Hamou A, Divet L (2014) Impact of alternative cementitious material on mechanical and transfer properties of concrete. ACI Mater J 114(3):251–262

    Google Scholar 

  14. Fan Y, Zhang S, Kawashima S, Shah SP (2014) Influence of kaolinite clay on the chloride diffusion property of cement-based materials. Cement Concrete Comp 45(1):117–124

    Article  Google Scholar 

  15. Otieno M, Beushausen H, Alexander M (2014) Effect of chemical composition of slag on chloride penetration resistance of concrete. Cement Concrete Comp 46(1):56–64

    Article  Google Scholar 

  16. Maghsoodloorad H, Allahverdi A (2016) Efflorescence formation and control in alkali-activated phosphorus slag cement. Int J Civ Eng 14(6):425–438

    Article  Google Scholar 

  17. Allahvedi A, Hashemi H (2015) Investigating the resistance of alkali-activated slag mortar exposed to magnesium sulfate attack. Int J Civ Eng 13(4):379–387

    Google Scholar 

  18. Birnin-Yauri UA, Glasser FP (1998) Friedel’s salt, Ca2Al(OH)6(Cl, OH).2H2O: its solid solutions and their role in chloride binding. Cement Concrete Res 28(12):1713–1723

    Article  Google Scholar 

  19. Suryavanshi AK, Scantlebury JD, Lyon SB (1996) Mechanism of Friedel’s salt formation in cements rich in tri-calcium aluminate. Cement Concrete Res 26(5):717–727

    Article  Google Scholar 

  20. Arya C, Xu Y (1995) Effect of cement type on chloride binding and corrosion of steel in concrete. Cement Concrete Res 25(4):893–902

    Article  Google Scholar 

  21. Csizmadia J, Balázs G, Tamás FD (2001) Chloride ion binding capacity of aluminoferrites. Cement Concrete Res 31(4):577–588

    Article  Google Scholar 

  22. Florea MVA, Brouwers HJH (2012) Chloride binding related to hydration products: part I: ordinary Portland cement. Cement Concrete Res 42(2):282–290

    Article  Google Scholar 

  23. Rahmani H, Ramazanianpour AA (2008) Effect of binary cement replacement materials on sulfuric acid resistance of dense concretes. Mag Concrete Res 60(2):145–155

    Article  Google Scholar 

  24. Niu Q, Feng N, Yang J, Zheng X (2002) Effect of superfine slag powder on cement properties. Cement Concrete Res 32(4):615–621

    Article  Google Scholar 

  25. Peronius N, Sweeting TJ (1985) On the correlation of minimum porosity with particle size distribution. Powder Technol 42(2):113–121

    Article  Google Scholar 

  26. Elmoaty AEMA (2011) Self-healing of polymer modified concrete. Alex Eng J 50(2):171–178

    Article  Google Scholar 

  27. Shalan AA (2010) Properties of latex modified mortar and concrete. MSc thesis, Alexandria, Alexandria University

  28. Rahmani H, Bazrgar H (2015) Effect of coarse cement particles on the self-healing of dense concretes. Mag Concrete Res 69(9):476–486

    Article  Google Scholar 

  29. Idriss AF, Negi SC, Jofriet JC, Hayward GI (2001) Effect of hydrogen sulphide emissions on cement mortar specimens. Can Biosyst Eng 43(1):5.23–5.28

    Google Scholar 

  30. Khedr SA, Idriss AF (1995) Resistance of silica fume concrete to corrosion-related damage. J Mater Civ Eng 7(2):102–107

    Article  Google Scholar 

  31. ASTM C 876-80 (1980) Standard test method for half-cell potentials of uncoated reinforcing steel in concrete. American Society for Testing and Materials, West Conshohocken

    Google Scholar 

  32. Douglas AS, Donald MW, Holler FJ (1992) Fundamentals of analytical chemistry, 6th edn. Saunders College Publishing, New York

    Google Scholar 

  33. Schofield RK (1947) Calculation of surface areas from measurements of negative adsorption. Nature 160(1):408–410

    Article  Google Scholar 

  34. Edwards DG, Quirk JP (1962) Repulsion of chloride by montmorillonite. J Colloid Sci 17(9):872–882

    Article  Google Scholar 

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Acknowledgments

The authors gratefully acknowledge Yasuj University for support of this study as MSc thesis.

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Correspondence to Hamid Rahmani.

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MSc thesis.

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Rahmani, H., Imani Asbagh, Y. Corrosion Resistance of Montmorillonite-Modified Dense Concretes. Int J Civ Eng 16, 137–146 (2018). https://doi.org/10.1007/s40999-016-0111-5

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  • DOI: https://doi.org/10.1007/s40999-016-0111-5

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