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Microstructure and Abrasive Wear Properties of WC/Fe Matrix Composites Under Different Preform Wall Thicknesses

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Abstract

In this paper, preforms with three-dimensional structures and different thicknesses were constructed by 3D printing technology, and WC particle reinforced high-chromium cast iron (HCCI) composites was prepared by infiltration casting method. The microstructure of the WC/Fe matrix composites was investigated using scanning electron microscopy (SEM), energy spectroscopy (EDS), X-ray diffraction (XRD) and electron backscattered diffraction (EBSD). The effects of different preform wall thickness on the hardness and three-body abrasive wear properties of the composites were tested. The results showed that with the increase in the wall thickness of the three-dimensional preform from 2.5 to 10 mm, the volume of the composite zone formed by the dissolution diffusion reaction of WC and HCCI gradually increased from 31.8 to 41.2%. The microstructure was composed of composite zone, matrix and WC particles partially dissolved. The hardness of the composite zone increased at first and then decreased, while the wear weight loss of the composite showed an opposite trend. Compared with the wall thickness of 2.5 mm, the minimum wear weight loss of the composite was 0.2821 g for a wall thickness of 7.5 mm, and the wear resistance was improved by 12.8%. The hardness and wear resistance of WC/Fe matrix composites at different wall thicknesses were mainly related to the diffusion of the preform and the formation of the composite zone.

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References

  1. S. Zhao, S. Xu, L. Yang et al., WC-Fe metal-matrix composite coatings fabricated by laser wire cladding. J Mater Process Technol (2022). https://doi.org/10.1016/j.jmatprotec.2021.117438

    Article  Google Scholar 

  2. D. Duman, H. Gokce, H. Cimenoglu, Synthesis, microstructure, and mechanical properties of WC-TiC-Co ceramic composites. J. Eur. Ceram. Soc. 32(7), 1427–1433 (2012). https://doi.org/10.1016/j.jeurceramsoc.2011.06.013

    Article  CAS  Google Scholar 

  3. B. Qiu, S.M. Xing, Q. Dong, Fabrication and wear behavior of ZTA particles reinforced iron matrix composite produced by flow mixing and pressure compositing. Wear 428, 167–177 (2019). https://doi.org/10.1016/j.wear.2019.03.013

    Article  CAS  Google Scholar 

  4. X. Cai, Y. Xu, L. Zhong et al., Fracture toughness of WC-Fe cermet in W-WC-Fe composite by nanoindentation. J. Alloy. Compd. 728, 788–796 (2017). https://doi.org/10.1016/j.jallcom.2017.09.070

    Article  CAS  Google Scholar 

  5. T. Zhang, Q. Shan, Z. Li et al., Effects of TiC and residual austenite synergistic strengthening mechanism on impact-abrasive wear behavior of bainite steel. Wear (2021). https://doi.org/10.1016/j.wear.2021.204088

    Article  Google Scholar 

  6. F. Akhtar, S.J. Guo, Microstructure, mechanical and fretting wear properties of TiC-stainless steel composites. Mater. Charact. 59(1), 84–90 (2008). https://doi.org/10.1016/j.matchar.2006.10.021

    Article  CAS  Google Scholar 

  7. C.S. Ramesh, C.K. Srinivas, B.H. Channabasappa, Abrasive wear behaviour of laser sintered iron–SiC composites. Wear 267(11), 1777–1783 (2009). https://doi.org/10.1016/j.wear.2008.12.026

    Article  CAS  Google Scholar 

  8. H. Tan, Z. Luo, Y. Li et al., Effect of strengthening particles on the dry sliding wear behavior of Al2O3–M7C3/Fe metal matrix composite coatings produced by laser cladding. Wear 324–325, 36–44 (2015). https://doi.org/10.1016/j.wear.2014.11.023

    Article  CAS  Google Scholar 

  9. K. Kambakas, P. Tsakiropoulos, Solidification of high-Cr white cast iron–WC particle reinforced composites. Mater. Sci. Eng., A 413–414, 538–544 (2005). https://doi.org/10.1016/j.msea.2005.08.215

    Article  CAS  Google Scholar 

  10. Y. Yin, Y. Zhao, K. En Koey et al., In-situ synthesized age-hardenable high-entropy composites with superior wear resistance. Compos Part B: Eng (2022). https://doi.org/10.1016/j.compositesb.2022.109795

    Article  Google Scholar 

  11. L. Niu, M. Hojamberdiev, Y. Xu, Preparation of in situ-formed WC/Fe composite on gray cast iron substrate by a centrifugal casting process. J. Mater. Process. Technol. 210(14), 1986–1990 (2010). https://doi.org/10.1016/j.jmatprotec.2010.07.013

    Article  CAS  Google Scholar 

  12. C.X. Liu, J.L. Sun, C. Wang et al., Fracture behaviour, microstructure, and performance of various layered-structured Al2O3-TiC-WC-Co composites. Ceram. Int. 47(14), 19766–19773 (2021). https://doi.org/10.1016/j.ceramint.2021.03.315

    Article  CAS  Google Scholar 

  13. A.B. Moreira, L.M.M. Ribeiro, P. Lacerda et al., Preparation and microstructural characterization of a high-Cr white cast iron reinforced with WC particles. Materials (Basel) (2020). https://doi.org/10.3390/ma13112596

    Article  PubMed  PubMed Central  Google Scholar 

  14. K. Zhai, S. Chen, C. Wang et al., Microstructure and properties of WC-CoCuFeNi composites fabricated by spark plasma sintering. Int J Refract Met Hard Mater (2022). https://doi.org/10.1016/j.ijrmhm.2022.105808

    Article  Google Scholar 

  15. J.P. Song, C.Z. Huang, B. Zou et al., Microstructure and mechanical properties of TiB2-WC-TiC-Ni composite tool materials. Adv Mater Eng Mater 457–458, 1191 (2012)

    Google Scholar 

  16. T. Wang, L. Zhu, H. Song et al., Effect of WC-17Co content on microstructure and properties of IN718 composites prepared by laser cladding. Opt Laser Technol (2022). https://doi.org/10.1016/j.optlastec.2021.107780

    Article  Google Scholar 

  17. J. Wang, H. Meng, H. Yu et al., Wear characteristics of spheroidal graphite roll WC-8Co coating produced by electro-spark deposition. Rare Met. 29(2), 174–179 (2010). https://doi.org/10.1007/s12598-010-0030-6

    Article  CAS  Google Scholar 

  18. Q. Shan, R. Ge, Z. Li et al., Wear properties of high-manganese steel strengthened with nano-sized V2C precipitates. Wear (2021). https://doi.org/10.1016/j.wear.2021.203922

    Article  Google Scholar 

  19. D.B. Miracle, Metal matrix composites - From science to technological significance. Compos. Sci. Technol. 65(15–16), 2526–2540 (2005). https://doi.org/10.1016/j.compscitech.2005.05.027

    Article  CAS  Google Scholar 

  20. M. Fattahi, M.S. Asl, S.A. Delbari et al., Role of nano-WC addition on microstructural, mechanical and thermal characteristics of TiC-SiCw composite. Int J Refract Met Hard Mater (2020). https://doi.org/10.1016/j.ijrmhm.2020.105248

    Article  Google Scholar 

  21. Y. Wang, S. Tan, D. Jiang, The effect of porous carbon preform and the infiltration process on the properties of reaction-formed SiC. Carbon 42(8–9), 1833–1839 (2004). https://doi.org/10.1016/j.carbon.2004.03.018

    Article  CAS  Google Scholar 

  22. J. Zhang, Y. Sui, Y. Jiang et al., Effect of honeycomb structure parameters on the mechanical properties of ZTAp/HCCI composites. Mater Res Express (2022). https://doi.org/10.1088/2053-1591/ac6ccf

    Article  Google Scholar 

  23. Z. Zhang, Y. Chen, L. Zuo et al., The effect of volume fraction of WC particles on wear behavior of in-situ WC/Fe composites by spark plasma sintering. Int. J. Refract Metal Hard Mater. 69, 196–208 (2017). https://doi.org/10.1016/j.ijrmhm.2017.08.009

    Article  CAS  Google Scholar 

  24. Z. Li, B. Teng, B. Yao et al., Microstructure and mechanical properties of WC reinforced 18Ni300 composites produced by selective laser melting. Mater Charact (2021). https://doi.org/10.1016/j.matchar.2021.111406

    Article  Google Scholar 

  25. Q.B. Nguyen, Z. Zhu, F.L. Ng et al., High mechanical strengths and ductility of stainless steel 304L fabricated using selective laser melting. J. Mater. Sci. Technol. 35(2), 388–394 (2019). https://doi.org/10.1016/j.jmst.2018.10.013

    Article  CAS  Google Scholar 

  26. F.F. Conde, J.D. Escobar, J.P. Oliveira et al., Austenite reversion kinetics and stability during tempering of an additively manufactured maraging 300 steel. Addit Manuf. (2019). https://doi.org/10.1016/j.addma.2019.100804

    Article  Google Scholar 

  27. J.P. Oliveira, A.J. Cavaleiro, N. Schell et al., Effects of laser processing on the transformation characteristics of NiTi: A contribute to additive manufacturing. Scripta Mater. 152, 122–126 (2018). https://doi.org/10.1016/j.scriptamat.2018.04.024

    Article  CAS  Google Scholar 

  28. K.G. Prashanth, J. Eckert, Formation of metastable cellular microstructures in selective laser melted alloys. J. Alloy. Compd. 707, 27–34 (2017). https://doi.org/10.1016/j.jallcom.2016.12.209

    Article  CAS  Google Scholar 

  29. Q. Xiao, W.L. Sun, K.X. Yang et al., Wear mechanisms and micro-evaluation on WC particles investigation of WC-Fe composite coatings fabricated by laser cladding. Surf Coatings Technol (2021). https://doi.org/10.1016/j.surfcoat.2021.127341

    Article  Google Scholar 

  30. S. Wu, Z. Liu, X. Huang et al., Process parameter optimization and EBSD analysis of Ni60A-25% WC laser cladding. Int J Refract Met Hard Mater (2021). https://doi.org/10.1016/j.ijrmhm.2021.105675

    Article  Google Scholar 

  31. Y. Li, K. Wang, H. Fu et al., Microstructure and wear resistance of in-situ TiC reinforced AlCoCrFeNi-based coatings by laser cladding. Appl Surf Sci (2022). https://doi.org/10.1016/j.apsusc.2022.152703

    Article  PubMed  Google Scholar 

  32. X. Zhang, Y. Xu, M. Wang et al., A powder-metallurgy-based strategy toward three-dimensional graphene-like network for reinforcing copper matrix composites. Nat Commun 11(1), 2775 (2020). https://doi.org/10.1038/s41467-020-16490-4

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  33. Q.-C. Guo, H. Zhou, C.-T. Wang et al., Effect of medium on friction and wear properties of compacted graphite cast iron processed by biomimetic coupling laser remelting process. Appl Surf. Sci. 255(12), 6266–6273 (2009). https://doi.org/10.1016/j.apsusc.2009.02.003

    Article  CAS  Google Scholar 

  34. J. Liu, Q. Li, M. Huo et al., Microstructure and mechanical properties of 3D-printed nano-silica reinforced alumina cores. Ceram. Int. (2022). https://doi.org/10.1016/j.ceramint.2022.06.301

    Article  Google Scholar 

  35. Y. Tian, R. Yang, Z. Gu et al., Ultrahigh cavitation erosion resistant metal-matrix composites with biomimetic hierarchical structure. Compos. Part B: Eng. (2022). https://doi.org/10.1016/j.compositesb.2022.109730

    Article  Google Scholar 

  36. W.-H. Gong, D.-H. Lu, G.-Y. He et al., Effect of volume fraction of metal matrix composites framework on compressive mechanical properties of 3D interpenetrating ZTAp/40Cr architectured composites. J. Iron. Steel Res. Int. 29(5), 859–865 (2021). https://doi.org/10.1007/s42243-021-00670-7

    Article  CAS  Google Scholar 

Download references

Acknowledgements

This work was supported by the National Natural Science Foundation of China [52071166]; Key Basic Research of Yunnan Provincial Science and Technology Department [202001AS070013].

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Authors and Affiliations

  1. Faculty of Materials Science and Engineering, Kunming University of Science and Technology, Kunming, 650093, China

    Zulai Li, Haojie Gou, Yingxing Zhang, Fei Zhang, Quan Shan & He Wei

  2. Faculty of Materials and Manufacturing, Beijing University of Technology, Beijing, 100124, China

    Zhaoyang Yan

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Li, Z., Gou, H., Zhang, Y. et al. Microstructure and Abrasive Wear Properties of WC/Fe Matrix Composites Under Different Preform Wall Thicknesses. Inter Metalcast 18, 1508–1522 (2024). https://doi.org/10.1007/s40962-023-01127-1

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