Abstract
Magnesium-based matrix composites' attention has recently increased significantly in various engineering applications due to their high strength-to-weight ratio, good solidification, and good mechanical properties. During the fabrication process, oxidation and porosity was the main drawback and led to reduced composites' mechanical properties. Based on this, the AZ31B grade magnesium alloy composite was prepared with different weight fractions (0, 3, 5, 7, and 9 wt%) of zirconia nanoparticles (ZrO2) through a liquid state stir cast process under an inert argon atmosphere. The effect of inert atmosphere-operated ZrO2 on the microstructural and mechanical properties of AZ31 alloy nanocomposites was studied. The surface morphology of the developed composite showed homogenous particle distribution with a porous free structure. As a result, low porosity level (less than 1%) and enriched mechanical properties of composite and composite contained 5 wt% ZrO2 facilitate maximum yield, tensile, and impact strength of 208±2 MPa, 276±1.5 MPa, and 5.8±0.5J, respectively. However, the higher content of ZrO2 in AZ31B alloy offered a high hardness value of 74±1HV. The optimum results composite sample 3 (AZ31B/5 wt% ZrO2) is recommended for automotive roof frame application.
Similar content being viewed by others
Data Availability
All the data required are available within the manuscript.
References
R. Venkatesh, S. Sivachandran, Magnesium alloy machining and its methodology: a systematic review and analyses, in AIP Conference Proceedings, vol 2473(1) (2022). https://doi.org/10.1063/5.0096398.
M.K. Kulekci, Magnesium and its alloys applications in automotive industry. Int. J. Adv. Manuf. Technol 39, 851–865 (2008). https://doi.org/10.1007/s00170-007-1279-2
Y. Ali, D. Qiu, B. Jiang, F. Pan, M.X. Zhang, Current research progress in grain refinement of cast magnesium alloys: a review article. J. Alloys Compd. 619, 639–651 (2015). https://doi.org/10.1016/j.jallcom.2014.09.061
M. Haghshenas, M. Gupta, Magnesium nanocomposites: an overview on time-dependent plastic (creep) deformation. Def. Technol. 15(2), 123–131 (2018). https://doi.org/10.1016/2018-08-008
N. Sivashankar, R. Viswanathan, K. Periasamy, R. Venkatesh, S. Chandrakumar, ’Multi-objective optimization of performance characteristics in drilling of Mg AZ61 using twist end mill drill tool. Mater. Today: Proc. 37(2), 214–219 (2021). https://doi.org/10.1016/j.matpr.2020.05.033
R. Venkatesh, S. Manivannan, P. Sakthivel, V. Vijayan, S. Jidesh, The investigation on newly developed of hydrophobic coating on cast AZ91D magnesium alloy under 3.5 wt% NaCl solutions. J InorgOrganometPolym Mater 32(4), 1246–1258 (2022). https://doi.org/10.1007/s10904-021-02174-z
B.L. Mordike, T. Ebert, Magnesium: properties, applications, and potential. Mater. Sci. Eng. A 302, 37–45 (2001). https://doi.org/10.1016/S0921-5093(00)01351-4
S. Jayabharathy, P. Mathiazhagan, Investigation of mechanical and wear behaviour of AZ91 magnesium matrix hybrid composite with TiO2/graphene. Mater. Today: Proc. 27(3), 2394–2397 (2019). https://doi.org/10.1016/j.matpr.2019.09.142
R. Arunachalam, P.K. Krishnan, R. Muraliraja, A review on the production of metal matrix composites through stir casting–Furnace design, properties, challenges, and research opportunities. J. Manuf. Process 42, 213–245 (2019). https://doi.org/10.1016/j.jmapro.2019.04.017
I. Balasuramanian, R. Maheswaran, V. Manikandan, N. Patil, M.A. Raja, R.M. Singari, Mechanical characterization and machining of squeeze cast AZ91D/SiC magnesium based metal matrix composites. Procedia Eng. 20, 97–105 (2018). https://doi.org/10.1016/2018-02-014
B. Ratna Sunil, G. Pradeep Kumar Reddy, H. Patle, R. Dumpala, Magnesium based surface metal matrix composites by friction stir processing. J. Magnes. Alloys 4, 52–61 (2016). https://doi.org/10.1016/2016-02-001
C.-L. Zhang, X.J. Wang, X.S. Hu, K. Wu, Fabrication, microstructure and mechanical properties of Mg matrix composites reinforced by high volume fraction of sphere TC4 particles. J. Magnes. Alloys 4(4), 286–294 (2016). https://doi.org/10.1016/2016-10-003
M. Rashad, F. Pan, M. Asif, J. She, A. Ullah, Improved mechanical properties of magnesium based composites with titanium—aluminum hybrids. J. Magnes. Alloys 3(1), 1–9 (2015). https://doi.org/10.1016/2014-12-010
M.J. Shen, X.J. Wang, M.F. Zhang, B.H. Zhang, M.Y. Zheng, K. Wu, Microstructure and room temperature tensile properties of 1μm-SiCp/AZ31B magnesium matrix composite. J. Magnes. Alloys 3, 155–161 (2015). https://doi.org/10.1016/2015-03-001
D. Sameer Kumar, K.N.S. Suman, C. Tara Sasanka, K. Ravindra, P. Poddar, S.B. Venkata Siva, Microstructure, mechanical response and fractography of AZ91E/Al2O3 (P) nanocomposite fabricated by semi-solid stir casting method. J. Magnes. Alloys 5(1), 48–55 (2017). https://doi.org/10.1016/2016-11-006
X. Jia, W. Guo-hua, W.-C. Liu, Y. Zhang, W.J. Ding, Effect of rotating gas bubble stirring treatment on the microstructures of semi-solid AZ91-2Ca alloy. J. Magnes. Alloys 1, 217–223 (2013). https://doi.org/10.1016/j.jma.2013.08.002
D. Kumar, R.K. Phanden, L. Thakur, A review on environment-friendly and lightweight magnesium-based metal matrix composites and alloys. Mater. Today Proc. 38(1), 359–364 (2021). https://doi.org/10.1016/j.matpr.2020.07.424
J. Chandradass, T. Thirugnanasambandham, P.B. Sethupathi, "Liquid state stir cast processing and characteristics study of AZ91D/SiCp composites. Mater. Today Proc. 45(7), 6507–6511 (2021). https://doi.org/10.1016/j.matpr.2020.11.450
B. Selvam, P. Marimuthu, R. Narayanasamy, V. Senthilkumar, K.S. Tun, M. Gupta, Effect of temperature and strain rate on compressive response of extruded magnesium nano-composite. J. Magnes. Alloys 3(3), 224–230 (2015). https://doi.org/10.1016/j.jma.2015.07.002
S.T. Selvamani, S. Premkumar, M. Vigneshwar, P. Hariprasath, K. Planikumar, Influence of carbon nanotubes on mechanical, metallurgical and tribological behaviour of magnesium nanocomposites. J. Magnes. Alloys 5(3), 326–335 (2017). https://doi.org/10.1016/j.jma.2017.08.006
S. Banerjee, S. Poria, G. Sutradhar, P. Sahoo, Dry sliding tribological behaviour of AZ31-WC nano-composites. J. Magnes. Alloys 7(2), 315–327 (2019). https://doi.org/10.1016/j.jma.2018.11.005
G.B. Veeresh Kumar, R. Pramod, C.G. Sekhar, G.P. Kumar, T. Bhanumurthy, Investigation of physical, mechanical and tribological properties of Al6061–ZrO2 nano-composites. Heliyon 5, e02858 (2019). https://doi.org/10.1016/j.heliyon.2019.e02858
B. Thakur, S. Barve, P. Pesode, Investigation on mechanical properties of AZ31B magnesium alloy manufactured by stir casting process. J. Mech. Behav. 138, 105641 (2023). https://doi.org/10.1016/j.jmbbm.2022.105641
T. SathisKumar, S. Shalini, M. Ramu, M. Govindaraju, Characterization of AZ31/ZrO2 composites produced via stir casting. Mater. Res. Express. 6(11), 1165d1 (2019). https://doi.org/10.1088/2053-1591/ab4eae
P. Emadi, B. Andilab, C. Ravindran, Processing and properties of magnesium-based composites reinforced with low levels of Al2O3. Int. Metalcast. 16, 1680–1692 (2022). https://doi.org/10.1007/s40962-021-00738-w
J. Bian, B. Yu, J. Hao, H. Zhu, P. Jin, L. Zheng, R. Li, Research on the effect of Sr and Zr on microstructure and properties of Mg–4Zn alloy. Int. Metalcast. 15, 1483–1498 (2021). https://doi.org/10.1007/s40962-021-00576-w
R. Venkatesh, C. Ramesh Kannan, S. Manivannan, M. Vivekanandan, Synthesis and experimental investigations of tribological and corrosion performance of AZ61 magnesium alloy hybrid composites, J. Nanomater., Volume 2022, Article ID 6012518, 12 pages (2022). https://doi.org/10.1155/2022/6012518
A. Incesu, A. Gungor, Biocorrosion and mechanical properties of ZXM100 and ZXM120 magnesium alloys. Int. Metalcast 13, 905–914 (2019). https://doi.org/10.1007/s40962-019-00308-1
P. Ajay Kumar, P. Rohatgi, D. Weiss, 50 years of foundry-produced metal matrix composites and future opportunities. Int. Metalcast. 14, 291–317 (2019). https://doi.org/10.1007/s40962-019-00375-4
A.H. Jabbari, M. Sedighi, Investigation of electromagnetic and mechanical stirring sequence effects on production of magnesium matrix nanocomposite. Int. Metalcast. 14, 489–504 (2020). https://doi.org/10.1007/s40962-019-00374-5
E. Cevik, M. Gundogan, A. Incesu, Corrosion behavior of graphene nanoplatelet-coated TiB2 reinforced AZ91 magnesium matrix semi-ceramic hybrid composites. Hittite J. Sci. Eng. 8(1), 27–33 (2021). https://doi.org/10.17350/HJSE19030000209
C. Ramesh Kannan, R. Venkatesh, M. Vivekanandan, Synthesis and characterization of mechanical properties of AA8014 + Si3N4/ ZrO2 hybrid composites by stir casting process, J. Adv. Mater. Sci. Eng. vol. 2022, Article ID 9150442 (2022). https://doi.org/10.1155/2022/9150442
R. Karthik, K. Gopalakrishnan, R. Venkatesh, A.M. Krishnan, S. Marimuthu, Influence of stir casting parameters in mechanical strength analysis of Aluminium Metal Matrix Composites (AMMCs). Mater. Today Proc. 62(4), 1965–1968 (2022). https://doi.org/10.1016/j.matpr.2022.02.067
Funding
The authors did not receive support from any organization for the submitted work. No funding was received to assist with the preparation of this manuscript. No funding was received for conducting this study. No funds, grants, or other support were received.
Author information
Authors and Affiliations
Contributions
All authors contributed to the study's conception and design. Material preparation, data collection and analysis were performed by [SS], [KR], [RV], and [ES]. The first draft of the manuscript was written by [RV], and all authors provided language help, writing assistance and proofreading. All authors read and approved the final manuscript.
Corresponding author
Ethics declarations
Conflict of Interest
The authors have no relevant financial or non-financial interests to disclose. The authors have no competing interests to declare relevant to this article's content. All authors certify that they have no affiliations with or involvement in any organization or entity with any financial or non-financial interest in the subject matter or materials discussed in this manuscript. The authors have no financial or proprietary interests in any material discussed in this article.
Ethics approval
This is an observational study. Enhancement of magnesium alloy (AZ31B) nanocomposite by the additions of zirconia nanoparticle via stir casting technique: Physical, microstructural, and mechanical behaviour, Research Ethics Committee has confirmed that no ethical approval is required.
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.
About this article
Cite this article
Senthilkumar, S., Revathi, K., Venkatesh, R. et al. Enhancement of Magnesium Alloy (AZ31B) Nanocomposite by the Additions of Zirconia Nanoparticle Via Stir Casting Technique: Physical, Microstructural, and Mechanical Behaviour. Inter Metalcast 18, 1465–1474 (2024). https://doi.org/10.1007/s40962-023-01116-4
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s40962-023-01116-4